1,3,3,5-tetrachloropentane | 24616-07-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 1,3,3,5-tetrachloropentane
• 英文别名: 1,3,3,5-tetrachloro-pentane；1,3,3,5-Tetrachlor-pentan；1,3,3,5-Tetrachlorpentan；1,4,4,7-Tetrachlorheptan
• CAS: 24616-07-7
• 化学式: C₅H₈Cl₄
• 分子量: 209.931
• InChiKey: AVFZURCSBSQCSO-UHFFFAOYSA-N

物化性质

• 熔点：
  32.5-34 °C
• 沸点：
  100-107 °C(Press: 10 Torr)
• 密度：
  1.340±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,3,3,5-tetrachloropentane 在 hexacarbonyl molybdenum 作用下， 以 various solvent(s) 为溶剂， 反应 3.0h， 生成 1,3,5-Trichlor-2-penten
  参考文献：
  名称：

  Dehydrochlorination of polychloroalkanes and 1,1-diaryl-2,2-dichloroethanes by the action of Mo(CO)6

  摘要：

  DOI：

  10.1007/bf00961108
• 作为产物：
  描述：

  乙烯 、 1,1,1,3-四氯丙烷 在 五羰基铁 作用下， 以 异丙醇 为溶剂， 生成 1,3,3,5-tetrachloropentane
  参考文献：
  名称：

  Telomerization of ethylene with 1,1,1,3-tetrachloropropane in the presence of iron pentacarbonyl and isopropyl alcohol

  摘要：

  DOI：

  10.1007/bf00853665

文献信息

• Process for producing monoadducts of olefins and telogens reactive therewith
  申请人：MONSANTO COMPANY

  公开号：EP0131561A1

  公开（公告）日：1985-01-16

  A process is disclosed for producing a monoadduct of a taxogen and a telogen reactive therewith. The taxogen and telogen are reacted in the presence of both a promoter and a source of metallic iron that is capable of being an activator for the reaction. The promoter comprises a phosphorus (V) compound containing a phosphoryl group.

  本发明公开了一种生产单加成物的工艺，这种单加成物包括一种分类原和一种与之反应的伸缩原。在有促进剂和可作为反应活化剂的金属铁源存在的情况下，可使分类原和毛细管原发生反应。促进剂包括含磷基的磷（V）化合物。
• CHLOROALKENE PRODUCTION METHOD ACCOMPANIED WITH DEHYDROCHLORINATION REACTION
  申请人：Tokuyama Corporation

  公开号：EP3293170A1

  公开（公告）日：2018-03-14

  A chloroalkene production method comprising the steps of: carrying out the dehydrochlorination reaction of a chloroalkane in the presence of a Lewis acid catalyst containing a metal chloride to produce a chloroalkene; removing a metal component derived from the catalyst from the obtained reaction solution; and distilling the reaction solution to obtain the purified chloroalkene.

  一种氯代烃生产方法，包括以下步骤 在含有金属氯化物的路易斯酸催化剂存在下，进行氯代烷烃的脱氢氯化反应，生成氯代烯烃； 从得到的反应溶液中去除催化剂中的金属成分；以及 蒸馏反应溶液，得到纯化的氯代烃。
• METHOD FOR PRODUCING HIGHER-ORDER CHLOROALKANE
  申请人：Tokuyama Corporation

  公开号：EP3330242A1

  公开（公告）日：2018-06-06

  To provide a high-order chloroalkane production method in which a chloroalkane is subjected to a dehydrochlorination reaction in the presence of a Lewis acid catalyst composed of a metal chloride, the obtained chloroalkene is subjected to a chlorine reaction and the obtained reaction solution is purified by distillation, after a metal component derived from the catalyst is removed from the reaction solution, the reaction solution is distilled, thereby making it possible to reduce the amount of a deposit on the inner walls of equipment and pipes and to carry out distillation stably and continuously for a long time.

  提供一种高阶氯代烷烃生产方法，在该方法中，氯代烷烃在由金属氯化物组成的路易斯酸催化剂存在下进行脱氢氯化反应，得到的氯代烷烃进行氯反应，并通过蒸馏提纯得到的反应溶液，在从反应溶液中除去从催化剂中提取的金属成分后，对反应溶液进行蒸馏，从而可以减少设备和管道内壁上的沉积物量，并可长期稳定、连续地进行蒸馏。
• Process for preparing a chlorinated alkene
  申请人：SPOLEK PRO CHEMICKOU A HUTNI VYROBU A.S.

  公开号：US10189759B2

  公开（公告）日：2019-01-29

  Disclosed is a process for preparing a chlorinated alkene, comprising contacting a chlorinated alkane with a catalyst in a dehydrochlorination zone to produce a liquid reaction mixture comprising the chlorinated alkane and the chlorinated alkene, and extracting chlorinated alkene from the reaction mixture, wherein the concentration of the chlorinated alkene in the reaction mixture present in the dehydrochlorination zone is controlled such that the molar ratio of chlorinated alkene:chlorinated alkane is from 1:99 to 50:50.

  公开了一种制备氯化烯的工艺，包括在脱氢氯化区将氯化烷烃与催化剂接触，生成由氯化烷烃和氯化烯组成的液态反应混合物，并从反应混合物中提取氯化烯，其中控制存在于脱氢氯化区的反应混合物中氯化烯的浓度，使氯化烯与氯化烷烃的摩尔比为1:99至50:50。
• Process for producing a chlorinated C3-6 alkane
  申请人：SPOLEK PRO CHEMICKOU A HUTNI VYROBU A.S.

  公开号：US10294179B2

  公开（公告）日：2019-05-21

  Disclosed is a process for producing a chlorinated C3-6 alkane comprising providing a reaction mixture comprising an alkene and carbon tetrachloride in a principal alkylation zone to produce chlorinated C3-6 alkane in the reaction mixture, and extracting a portion of the reaction mixture from the principal alkylation zone, wherein: a) the concentration of the chlorinated C3-6 alkane in the reaction mixture in the principal alkylation zone is maintained at a level such that the molar ratio of chlorinated C3-6 alkane:carbon tetrachloride in the reaction mixture extracted from the alkylation zone does not exceed 95:5 when the principal alkylation zone is in continuous operation; and/or b) the reaction mixture extracted from the principal alkylation zone additionally comprises alkene and the reaction mixture is subjected to a dealkenation step in which at least about 50% or more by weight of the alkene present in the reaction mixture is extracted therefrom and at least about 50% of the extracted alkene is fed back into the reaction mixture provided in the principal alkylation zone; and/or c) the reaction mixture present in the principal alkylation zone and extracted from the principal alkylation zone additionally comprises a catalyst, and the reaction mixture extracted from the principal alkylation zone is subjected to an aqueous treatment step in which the reaction mixture is contacted with an aqueous medium in an aqueous treatment zone, a biphasic mixture is formed and an organic phase comprising catalyst is extracted from the biphasic mixture.

  公开了一种生产氯化 C3-6 烷烃的工艺，包括在主烷基化区提供由烯和四氯化碳组成的反应混合物，以在反应混合物中生产氯化 C3-6 烷烃，以及从主烷基化区提取部分反应混合物，其中： a) 主烷基化区反应混合物中氯化 C3-6 烷烃的浓度保持在一定水平，当主烷基化区连续运行时，从烷基化区提取的反应混合物中氯化 C3-6 烷烃与四氯化碳的摩尔比不超过 95:5；和/或 b) 从主烷基化区提取的反应混合物还包括烯，该反应混合物进行脱烷基化步骤，其中从反应混合物中提取至少约 50%或更多重量的烯，并将至少约 50%提取的烯送回主烷基化区提供的反应混合物中；和/或 c) 存在于主烷基化区并从主烷基化区萃取的反应混合物还包括催化剂，从主烷基化区萃取的反应混合物经过水处理步骤，其中反应混合物在水处理区与水介质接触，形成双相混合物，并从双相混合物中萃取包含催化剂的有机相。