carbonofluoridic acid 2-chloro-ethyl ester | 462-28-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: carbonofluoridic acid 2-chloro-ethyl ester
• 英文别名: fluorocarbonic acid-(2-chloro-ethyl ester)；Fluorokohlensaeure-(2-chlor-aethylester)；1-Chlor-2-fluorcarbonyloxy-aethan；<2-Chlor-aethyl>-fluoroformat；Carbonofluoridic acid, 2-chloroethyl ester；2-chloroethyl carbonofluoridate
• CAS: 462-28-2
• 化学式: C₃H₄ClFO₂
• mdl: MFCD19232861
• 分子量: 126.515
• InChiKey: NKDGAVDXXGNMGR-UHFFFAOYSA-N

物化性质

• 沸点：
  133.8±42.0 °C(Predicted)
• 密度：
  1.286±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  7
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.666
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  carbonofluoridic acid 2-chloro-ethyl ester 在 四氢呋喃 、 三氟化硼 作用下， 生成 1-氯-1-氟乙烷 、 氟氯乙烷
  参考文献：
  名称：

  The Chemistry of Carbonyl Chloride Fluoride. I. The Ring Opening of Cyclic Ethers with Carbonyl Chloride Fluoride

  摘要：

  DOI：

  10.1021/jo01016a077
• 作为产物：
  描述：

  氯甲酸氯乙酯 在 potassium fluoride 、 硝基苯 作用下， 生成 carbonofluoridic acid 2-chloro-ethyl ester
  参考文献：
  名称：

  Cross-Cultural Perspectives: Implications for Attachment Theory and Family Therapy

  摘要：

  Cross‐cultural perspectives have always been useful for understanding behavior. They clarify the distinction between aspects that are essentially part of the human condition and those that are the most responsive to variation. The interesting article by Rothbaum and his colleagues is in that tradition, contrasting the cultural values and family patterns in Japanese society with those of Western cultures, including our own, and suggesting that these differences shape the nature and course of attachment. It stimulates questions about what we have taken for granted in our theories and in our evaluations of dysfunctional behavior.

  DOI：

  10.1111/j.1545-5300.2002.41316.x

文献信息

• New catalytic alkylation of in situ generated perfluoro-alkyloxy-anions and perfluoro-carbanions
  作者：Marco Galimberti、Giovanni Fontana、Giuseppe Resnati、Walter Navarrini

  DOI：10.1016/j.jfluchem.2005.09.005

  日期：2005.12

  Alkyl fluoroformates RHOC(O)F are a new family of excellent alkylating agents. Perfluoroacyl fluorides, selected perfluoroketones and fluoroolefins can be alkylated to hydrofluoroethers RF–O–RH and hydrofluoroalkanes RF–RH, respectively. Potassium fluoride and cesium fluorides catalysts in glymes at 50–100 °C are the preferred experimental conditions.

  烷基氟甲酸酯R H OC（O）F是一种新型的优异烷基化剂。全氟氟化物，选择perfluoroketones和氟烯烃可被烷基化，以氢氟醚- [R ˚F -O-R ħ和氢氟烷烃- [R ˚F -R ħ，分别。甘氨酸中的氟化钾和氟化铯催化剂在50–100°C是优选的实验条件。