| 15157-32-1

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 其他非金属卤化物
• CAS: 15157-32-1
• 化学式: FHN
• 分子量: 35.0051
• InChiKey: KKWGFADFRBKTES-VMNATFBRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.2
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  hydrazoic acid 、 四氟化碳 生成
  参考文献：
  名称：

  Spectrally resolved fluorescence in the HNF (DNF) Ã2A′ - X̃2 A″ band system

  摘要：

  Selectively detected fluorescence excitation spectra have been employed to find and assign Q-type subband heads in the HNF A2A'-X2A''2(1/0)3(1/0) and 2(2/0)3(1/0) bands, which are obscured because of the near equality of the omega2' and omega3' vibrational frequencies by the stronger 2(2/0) and 2(3/0) bands, respectively. A number of previously unobserved heads in the corresponding DNF band system are also reported. Dispersed fluorescence spectra were also taken for excitation of a variety of HNF and DNFA2A' vibrational levels, and the energies of vibrational levels in their ground X2A'' electronic states were derived. These energies were fit to determine vibrational constants. The following values (in cm-1) were derived for the harmonic constants omega0/1'', omega0/2'', and omega0/3'': 3167(6), 1455(2), 1036(7) for HNF and 2339(4), 1084(3), 1013(6) for DNF.

  DOI：

  10.1016/0009-2614(93)89165-e

文献信息

• Spectrally resolved fluorescence in the HNF (DNF) Ã2A′ - X̃2 A″ band system
  作者：Jing Chen、Paul J. Dagdigian

  DOI：10.1016/0009-2614(93)89165-e

  日期：1993.10

  Selectively detected fluorescence excitation spectra have been employed to find and assign Q-type subband heads in the HNF A2A'-X2A''2(1/0)3(1/0) and 2(2/0)3(1/0) bands, which are obscured because of the near equality of the omega2' and omega3' vibrational frequencies by the stronger 2(2/0) and 2(3/0) bands, respectively. A number of previously unobserved heads in the corresponding DNF band system are also reported. Dispersed fluorescence spectra were also taken for excitation of a variety of HNF and DNFA2A' vibrational levels, and the energies of vibrational levels in their ground X2A'' electronic states were derived. These energies were fit to determine vibrational constants. The following values (in cm-1) were derived for the harmonic constants omega0/1'', omega0/2'', and omega0/3'': 3167(6), 1455(2), 1036(7) for HNF and 2339(4), 1084(3), 1013(6) for DNF.