N~2~,N~7~-Bis(3-methylphenyl)-N~2~,N~7~-diphenyl-9H-fluorene-2,7-diamine | 142517-32-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N~2~,N~7~-Bis(3-methylphenyl)-N~2~,N~7~-diphenyl-9H-fluorene-2,7-diamine
• 英文别名: 2-N,7-N-bis(3-methylphenyl)-2-N,7-N-diphenyl-9H-fluorene-2,7-diamine
• CAS: 142517-32-6
• 化学式: C₃₉H₃₂N₂
• 分子量: 528.7
• InChiKey: NLQCCLTXAOCRGV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.8
• 重原子数：
  41
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• POLYMER COMPOUND CONTAINING NITROGEN-CONTAINING HETEROCYCLIC STRUCTURE, AND COMPOSITION, SOLUTION, THIN FILM AND POLYMER LIGHT-EMITTING ELEMENT EACH CONTAINING SAME
  申请人：Ishii Yusuke

  公开号：US20110210322A1

  公开（公告）日：2011-09-01

  A polymer compound having a repeating unit represented by formula (1-0): wherein in formula (1-0), ring A 01 and ring A 02 are the same or different and each represents an aromatic hydrocarbon ring that is optionally substituted; and X 10 and X 20 are the same or different and each represents a hydrogen atom or a substituent, provided that at least one of X 10 and X 20 is a group represented by formula (2-0): wherein in formula (2-0), Z 10 , Z 20 and Z 30 are the same or different and each represents —N═ or —CH═, provided that at least two of Z 10 , Z 20 and Z 30 are —N═; L 0 represents an arylene group or a single bond; and Ar 10 and Ar 20 are the same or different and each represents an aryl group, provided that the total carbon number of the groups represented by Ar 10 , Ar 20 and L 0 is 24 or more.

  具有由公式（1-0）表示的重复单元的聚合物化合物：其中，在公式（1-0）中，环A01和环A02相同或不同，每个环都表示可以选择取代的芳香族碳氢环；X10和X20相同或不同，每个都表示氢原子或取代基，但至少其中一个是由公式（2-0）表示的基团：其中，在公式（2-0）中，Z10、Z20和Z30相同或不同，每个都表示—N═或—CH═，但至少有两个是—N═；L0表示芳撑基团或单键；Ar10和Ar20相同或不同，每个都表示芳基团，但由Ar10、Ar20和L0表示的基团的总碳数为24或更多。
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Soga Masayuki

  公开号：US20120199825A1

  公开（公告）日：2012-08-09

  An organic electroluminescent device comprising an anode, a cathode, a light emitting layer that is disposed between the anode and the cathode and contains a first light emitting layer material containing a phosphorescent compound and a second light emitting layer material containing a charge transporting polymer compound (that is, a light emitting layer containing a first light emitting layer material and a second light emitting layer material), and a hole transporting layer that is disposed between the anode and the light emitting layer so as to be adjacent to the light emitting layer and is composed of a hole transporting polymer compound, wherein the lowest excitation triplet energy T1 e (eV) of the first light emitting layer material, the lowest excitation triplet energy T1 h (eV) of the second light emitting layer material and the lowest excitation triplet energy T1 t (eV) of the hole transporting polymer compound satisfy the following formulae (A) and (B): T 1 e ≦T 1 h (A) T 1 t −T 1 e ≦0.10  (B). An organic electroluminescent device comprising an anode and a cathode, and a hole transporting layer and a light emitting layer disposed between the anode and the cathode, wherein the hole transporting layer contains 1) a mixture of 2,2′-bipyridine and/or 2,2′-bipyridine derivative and a non-2,2′-bipyridinediyl group-containing hole transporting polymer compound, 2) a 2,2′-bipyridinediyl group-containing polymer compound having a constitutional unit composed of an unsubstituted or substituted 2,2′-bipyridinediyl group, and at least one constitutional unit selected from the group consisting of constitutional units composed of a divalent aromatic amine residue and constitutional units composed of an unsubstituted or substituted arylene group, or a combination thereof.

  一种有机电致发光器件，包括阳极、阴极、位于阳极和阴极之间且含有第一发光层材料和第二发光层材料的发光层（即含有第一发光层材料和第二发光层材料的发光层），其中第一发光层材料含有磷光化合物，第二发光层材料含有电荷传输聚合物化合物，以及位于阳极和发光层之间以与发光层相邻的方式设置的孔传输层，由孔传输聚合物化合物组成，其中第一发光层材料的最低激发三重态能量T1e（eV）、第二发光层材料的最低激发三重态能量T1h（eV）和孔传输聚合物化合物的最低激发三重态能量T1t（eV）满足以下公式（A）和（B）：T1e≦T1h（A）T1t−T1e≦0.10（B）。一种有机电致发光器件，包括阳极和阴极、孔传输层和发光层，位于阳极和阴极之间，其中孔传输层包含1）2,2′-联吡啶和/或2,2′-联吡啶衍生物的混合物和不含2,2′-联吡啶基团的孔传输聚合物化合物，2）具有由未取代或取代的2,2′-联吡啶基团组成的构成单元和至少选自由双价芳香胺残基和由未取代或取代的芳基烃基组成的构成单元之一的构成单元的2,2′-联吡啶基团含量聚合物化合物，或其组合。
• ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2492988A1

  公开（公告）日：2012-08-29

  An organic electroluminescent device comprising an anode, a cathode, a light emitting layer that is disposed between the anode and the cathode and contains a first light emitting layer material containing a phosphorescent compound and a second light emitting layer material containing a charge transporting polymer compound (that is, a light emitting layer containing a first light emitting layer material and a second light emitting layer material), and a hole transporting layer that is disposed between the anode and the light emitting layer so as to be adjacent to the light emitting layer and is composed of a hole transporting polymer compound, wherein the lowest excitation triplet energy T1e (eV) of the first light emitting layer material, the lowest excitation triplet energy T1h (eV) of the second light emitting layer material and the lowest excitation triplet energy T1t (eV) of the hole transporting polymer compound satisfy the following formulae (A) and (B): An organic electroluminescent device comprising an anode and a cathode, and a hole transporting layer and a light emitting layer disposed between the anode and the cathode, wherein the hole transporting layer contains 1) a mixture of 2,2'-bipyridine and/or 2,2'-bipyridine derivative and a non-2,2'-bipyridinediyl group-containing hole transporting polymer compound, 2) a 2,2'-bipyridinediyl group-containing polymer compound having a constitutional unit composed of an unsubstituted or substituted 2,2'-bipyridinediyl group, and at least one constitutional unit selected from the group consisting of constitutional units composed of a divalent aromatic amine residue and constitutional units composed of an unsubstituted or substituted arylene group, or a combination thereof.

  一种有机电致发光器件，包括阳极、阴极、位于阳极和阴极之间并包含含有磷光化合物的第一发光层材料和含有电荷传输聚合物化合物的第二发光层材料的发光层（即包含第一发光层材料和第二发光层材料的发光层）、以及一个空穴传输层，该层设置在阳极和发光层之间，与发光层相邻，由空穴传输高分子化合物组成，其中第一发光层材料的最低激发三重能 T1e（eV）、第二发光层材料的最低激发三重能 T1h（eV）和空穴传输高分子化合物的最低激发三重能 T1t（eV）满足下式（A）和（B）： 一种有机电致发光器件，包括阳极和阴极，以及设置在阳极和阴极之间的空穴传输层和发光层，其中空穴传输层包含 1) 2,2'-联吡啶和/或 2,2'-联吡啶衍生物与非 2,2'-联吡啶二基含空穴传输聚合物化合物的混合物，2) 2、2)一种含 2,2'-联吡啶二基的聚合物化合物，具有一个由未取代或取代的 2,2'-联吡啶二基组成的构型单元，以及至少一个选自由二价芳香族胺残基组成的构型单元和由未取代或取代的芳烯基组成的构型单元组成的组的构型单元，或它们的组合。
• COMPOSITION AND LUMINESCENT ELEMENT OBTAINED USING SAME
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2518111A1

  公开（公告）日：2012-10-31

  A composition comprising (1) a first crosslinkable polymer compound having an aromatic conjugated repeating unit and a crosslinkable group and having at least one of a light emitting property and charge transportability, and (2) a second crosslinkable polymer compound having an aromatic conjugated repeating unit and a crosslinkable group at least one of which is different from the aromatic conjugated repeating unit in the first crosslinkable polymer compound and the crosslinkable group in the first crosslinkable polymer compound, and having at least one of a light emitting property and charge transportability, wherein at least one of the first crosslinkable polymer compound and the second crosslinkable polymer compound has a crosslinkable group represented by the following formula (Z-3) or (Z-4): in the formulae, RC represents a hydrogen atom, or a substituent such as an unsubstituted or substituted alkyl group or the like, the plurality of RC moieties may be the same or different.

  一种组合物，包含(1)具有芳香共轭重复单元和可交联基团且具有发光特性和电荷传输性中至少一种特性的第一可交联聚合物化合物，以及(2)具有芳香共轭重复单元和可交联基团（其中至少一个不同于第一可交联聚合物化合物中的芳香共轭重复单元和第一可交联聚合物化合物中的可交联基团）且具有发光特性和电荷传输性中至少一种特性的第二可交联聚合物化合物、其中第一可交联聚合物化合物和第二可交联聚合物化合物中的至少一个具有下式（Z-3）或（Z-4）所代表的可交联基团： 式中，RC 代表氢原子或取代基，如未取代或取代的烷基等，多个 RC 基团可以相同或不同。
• HOLE TRANSPORT COMPOSITIONS AND RELATED DEVICES AND METHODS (I)
  申请人：Plextronics, Inc.

  公开号：EP2588527A2

  公开（公告）日：2013-05-08