tris(2-benzothiazolylmethyl)amine | 75472-28-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: tris(2-benzothiazolylmethyl)amine
• 英文别名: 1,3-Benzothiazol-2-yl-N,N-bis(1,3-benzothiazol-2-ylmethyl)methanamine；1-(1,3-benzothiazol-2-yl)-N,N-bis(1,3-benzothiazol-2-ylmethyl)methanamine
• CAS: 75472-28-5
• 化学式: C₂₄H₁₈N₄S₃
• 分子量: 458.632
• InChiKey: RYQOCRNXHKYKNY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  31
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  127
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  cobalt(II) bromide hexahydrate 、 tris(2-benzothiazolylmethyl)amine 在 triethylorthoformate 作用下， 以 乙醇 、 二氯甲烷 为溶剂， 生成 [Co(tris(2-benzothiazolylmethyl)amine)Br]2CoBr4
  参考文献：
  名称：

  Complexes of substituted benzothiazoles 3. Cobalt (II) complexes of the ‘tripod’ ligand tris(2-benzothiazolymethyl)amine

  摘要：

  DOI：

  10.1016/s0020-1693(00)88913-6
• 作为产物：
  描述：

  次氮基三乙酸 、 2-氨基苯硫醇 以 乙二醇 为溶剂， 以44%的产率得到tris(2-benzothiazolylmethyl)amine
  参考文献：
  名称：

  [EN] METAL COMPLEXES FOR PROMOTING GROWTH IN A PHOTOSYNTHETIC ORGANISM
  [FR] COMPLEXES MÉTALLIQUES POUR FAVORISER LA CROISSANCE DANS UN ORGANISME PHOTOSYNTHÉTIQUE

  摘要：

  一种促进光合生物生长的方法，包括将光合生物处理为金属配合物或其前体，其中金属配合物包括从锌（Zn）、钴（Co）、铜（Cu）、镍（Ni）和铁（Fe）中选择的金属，以及一个双齿或三齿配体。还描述了金属配合物及其配体。

  公开号：

  WO2020089630A1

文献信息

• Benzimidazole and Related Ligands for Cu-Catalyzed Azide−Alkyne Cycloaddition
  作者：Valentin O. Rodionov、Stanislav I. Presolski、Sean Gardinier、Yeon-Hee Lim、M. G. Finn

  DOI：10.1021/ja072678l

  日期：2007.10.1

  Tris(2-benzimidazolylmethyl)amines have been found to be superior accelerating ligands for the copper(I)-catalyzed azide-alkyne cycloaddition reaction. Candidates bearing different benzimidazole N-substituents as well as benzothiazole and pyridyl ligand arms were evaluated by absolute rate measurements under relatively dilute conditions by aliquot quenching kinetics and by relative rate measurements

  已发现三（2-苯并咪唑基甲基）胺是铜（I）催化的叠氮化物-炔环加成反应的优异加速配体。带有不同苯并咪唑 N 取代基以及苯并噻唑和吡啶基配体臂的候选物通过在相对稀释条件下通过等分淬火动力学进行的绝对速率测量和在浓缩条件下通过反应量热法进行的相对速率测量进行评估。具有侧链烷基羧酸盐臂的苯并咪唑基配体被证明在后一种情况下是有利的。该催化剂系统显示出包含不止一种活性物质，对 pH 值和缓冲盐的变化提供复杂的响应，并在高浓度配位配体的存在下保持高催化速率。
• [EN] LIGANDS FOR COPPER-CATALYZED AZIDE-ALKYNE CYCLOADDITION REACTIONS<br/>[FR] LIGANDS POUR DES RÉACTIONS DE CYCLO-ADDITION AZIDE-ALKYNE CATALYSÉS AU CUIVRE
  申请人：SCRIPPS RESEARCH INST

  公开号：WO2009038685A1

  公开（公告）日：2009-03-26

  Ligands useful for promoting copper-catalyzed azide-alkyne cycloaddition reactions comprise a compound represented by structural Formula (I) as described in the specification, wherein in Formula (I) Z1 is a nitrogen-containing heterocyclic group or a group represented by the formula : Y1-(CH2)c-Y2-(CH2)d-Y3-CH2-N(CH2Z4)(CH2Z5), where Y1 is -E1-C(O)O-, -E1-C(O)NH-, -E1-, or a covalent bond; Y2 is a covalent bond, -CH=CH-, or a 1,4-(1,2,3-triazolyl) group; Y3 is -OC(O)-E2-, -NHC(O)-E2-, -E2-, or a covalent bond; each of E1 and E2 is a benzimidazolyl group attached at the 1 and 2 positions; each of c and d is independently 1, 2, 3, 4, or 5; each of Z2, Z3, Z4 and Z5 is a nitrogen-containing heterocyclic group including a substituent X1 and optionally including a substituent (CH2)n-R1, and Y1, Y2, Y3, X1, R1, c, d and n are each as defined in the specification.

  有助于促进铜催化的酰胺-炔基环加成反应的配体包括一种由结构式（I）表示的化合物，如说明书中所述，在式（I）中，Z1是含氮杂环基团或由式子表示的基团：Y1-（CH2）c-Y2-（CH2）d-Y3-CH2-N（CH2Z4）（CH2Z5），其中Y1是-E1-C（O）O-，-E1-C（O）NH-，-E1-或共价键；Y2是共价键，-CH=CH-或1,4-（1,2,3-三唑基）基团；Y3是-OC（O）-E2-，-NHC（O）-E2-，-E2-或共价键；E1和E2中的每一个都是连接在1和2位置的苯并咪唑基团；每个c和d都是独立的1、2、3、4或5；每个Z2、Z3、Z4和Z5都是含氮杂环基团，包括取代基X1，且可选地包括取代基（CH2）n-R1，Y1、Y2、Y3、X1、R1、c、d和n的定义均如说明书中所定义。
• Method for producing phenol condensate
  申请人：——

  公开号：US20040267057A1

  公开（公告）日：2004-12-30

  Provided is a method for producing a phenol condensate by oxidative condensation of a phenol compound not having a substituted group on at least one ortho-position, in the presence of a specific complex (II) and oxygen, wherein a condensate coupled at para-position of the phenol can be produced in an excellent yield, L-M (X) n (II) wherein L represents a ligand having 2 to 4 nitrogen atoms as donor atoms, M represents copper ion, nickel ion, cobalt ion, iron ion, manganese ion, chromium ion or vanadyl ion, X represents a counter ion, n is a number of Xs.

  提供一种方法，通过在特定复合物（II）和氧的存在下，对至少一个邻位没有取代基的酚化合物进行氧化缩合，从而可以产生一个在酚的对位耦合的缩合物，其产率优异，公式为L-M（X）n（II），其中L代表具有2至4个氮原子作为供体原子的配体，M代表铜离子，镍离子，钴离子，铁离子，锰离子，铬离子或钒离子，X代表计数离子，n是X的数量。
• RESIN COMPOSITION AND PROCESS FOR PRODUCING THE SAME
  申请人：Japan as represented by Secretary of Agency of Industrial Science and Technology

  公开号：EP1114836A1

  公开（公告）日：2001-07-11

  A curable resin composition, which comprises a resin formed, in the presence of a transition metal complex, by polymerizing an oxidative-polymerizable compound that contains a phenol-compound-containing vegetable oil. A method for producing a curable resin composition comprising a resin formed, in the presence of a catalyst, by polymerizing an oxidative-polymerizable compound that contains a phenol-compound-containing vegetable oil, wherein the catalyst is a transition metal complex. The curable resin composition is useful as a raw material for a urushi-like coating, a friction material, a brake lining material, a brake pad material, a material for forming a coating film, a compound for a recording material, a raw material for an ink, a raw material for a coating, a raw material for a adhesive, a raw material for an epoxy resin, a raw material for a photoresist or antioxidant, and a starting material for a functional polymer.

  一种可固化树脂组合物，它包括在过渡金属络合物存在下，通过聚合含有含酚化合物的植物油的可氧化聚合化合物而形成的树脂。一种生产可固化树脂组合物的方法，该树脂组合物包括在催化剂存在下，通过聚合含有含酚化合物植物油的可氧化聚合化合物而形成的树脂，其中催化剂为过渡金属络合物。这种可固化树脂组合物可用作乌拉石般的涂层的原料、摩擦材料、制动衬片材料、制动片材料、形成涂膜的材料、记录材料的化合物、油墨的原料、涂层的原料、粘合剂的原料、环氧树脂的原料、光刻胶或抗氧化剂的原料以及功能聚合物的起始原料。
• METHOD FOR PRODUCING AROMATIC COMPOUND POLYMER
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1767560A1

  公开（公告）日：2007-03-28

  A method for producing an aromatic compound polymer comprising oxidatively polymerizing one or more of aromatic compound(s) having two or more hydrogen atoms directly connected to aromatic ring(s), in the presence of an oxidizing agent, wherein the method employs a catalyst composed of a transition metal complex or a catalyst prepared from a transition metal complex and an activating agent, and said catalyst has a parameter P defined by the following formula (A) of 0.50 or more, and a parameter Eo defined by the following formula (B) of 0.50 [V] or more: P=Af/Ai (wherein Ai represents an absorbance at an absorption maximum belonging in an absorption band located at the longest wavelength side in an absorption spectrum obtained for a solution containing the catalyst, in a ultraviolet to near-infrared wavelength region from 200 nm to 800 nm, and Af represents an absorbance at the same wavelength applied to the Ai, in an absorption spectrum in the above wavelength region obtained for a solution prepared by adding 3 equivalent of water per mole of the metal contained in the catalyst to the solution), and Eo=Epa+Epc/2V (wherein, Epa represents a peak potential at the oxidation side of an oxidation-reduction potential derived from the transition metal contained in the catalyst, at a potential of 0.50 [V] or more based on oxidation-reduction potential of ferrocene/ferrocenium ion measured with a cyclic voltammetry for the solution containing the catalyst, and Epc represents a peak potential at the reduction side corresponding to Epa by the same measurement).

  一种生产芳香族化合物聚合物的方法，包括在氧化剂存在下，氧化聚合一种或多种具有两个或两个以上氢原子直接连接到芳香环上的芳香族化合物，其中该方法采用由过渡金属络合物组成的催化剂或由过渡金属络合物和活化剂制备的催化剂，所述催化剂的参数P由下式(A)定义为0.50或以上，参数Eo由下式(B)定义为0.50[V]或以上：P=Af/Ai (其中，Ai 表示在含有催化剂的溶液的吸收光谱中，在 200 纳米至 800 纳米的紫外至近红外波长区域内，属于最长波长侧的吸收带的吸收最大值处的吸光度；Af 表示在通过向溶液中加入每摩尔催化剂所含金属 3 当量的水而制备的溶液的吸收光谱中，在上述波长区域内，与 Ai 相同波长处的吸光度），以及 Eo=Epa+Epc/2V (其中，Epa 代表由催化剂所含过渡金属衍生的氧化还原电位的氧化侧峰值电位，电位值为 0.50 [V] 或更高，该电位值基于对含有催化剂的溶液用循环伏安法测得的二茂铁/二茂铁离子的氧化还原电位；Epc 代表与 Epa 相对应的还原侧峰值电位，该测量值与 Epa 相同）。