N,N-dimethyl-N,N-diallylammonium bromide | 14764-64-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-dimethyl-N,N-diallylammonium bromide
• 英文别名: NN-diallyldimethylammonium bromide；dimethyldiallylammonium bromide；Diallyl-dimethylammoniumbromid；dimethyl diallylammonium bromide；N,N-Dimethyl-N-(prop-2-en-1-yl)prop-2-en-1-aminium bromide；dimethyl-bis(prop-2-enyl)azanium;bromide
• CAS: 14764-64-8
• 化学式: Br*C₈H₁₆N
• 分子量: 206.126
• InChiKey: YRHAJIIKYFCUTG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.56
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N,N-dimethyl-N,N-diallylammonium bromide 在 正丁基锂 、 N,N-二甲基环己胺 作用下， 以 正己烷 为溶剂， 68.0~200.1 ℃ 、399.97 Pa 条件下， 反应 24.0h， 生成 5-己烯醛
  参考文献：
  名称：

  Dollinger, Michael; Henning, Wolfgang; Kirmse, Wolfgang, Chemische Berichte, 1982, vol. 115, # 6, p. 2309 - 2325

  摘要：

  DOI：
• 作为产物：
  描述：

  Amidosulfoxylic acid, dimethyl-, methyl ester 、 3-溴丙烯 生成 N,N-dimethyl-N,N-diallylammonium bromide
  参考文献：
  名称：

  Wenschuh, Eberhard; Kuehne, Ulrich; Mikolajczyk, Marian, Zeitschrift fur Chemie, 1981, vol. 21, # 6, p. 217 - 218

  摘要：

  DOI：

文献信息

• Base catalysed rearrangements involving ylide intermediates. Part 1. The rearrangements of diallyl- and allylpropynyl-ammonium cations
  作者：Robert W. Jemison、Trevor Laird、W. David Ollis、Ian O. Sutherland

  DOI：10.1039/p19800001436

  日期：——

  The base catalysed rearrangements of diallylammonium rations and allylpropynylammonium rations are described. In most cases, the major product arises by a symmetry-allowed [3,2] sigmatropic rearrangement of the intermediate ylide. The minor products can be regarded as being derived by homolysis of the ylide into a radical pair followed by recombination.

  描述了碱催化的二烯丙基铵比和烯丙基丙烯酰铵比的重排。在大多数情况下，主要产物是由中间内环的对称允许的[3,2]σ重排产生的。次要产物可以认为是通过将叶立德均质化为自由基对，然后进行重组而得到的。
• [EN] BRANCHED AMINO ACID SURFACTANTS FOR CLEANING PRODUCTS<br/>[FR] TENSIOACTIFS D'ACIDES AMINÉS RAMIFIÉS POUR PRODUITS DE NETTOYAGE
  申请人：ADVANSIX RESINS & CHEMICALS LLC

  公开号：WO2022015606A1

  公开（公告）日：2022-01-20

  The present disclosure pertains to branched surfactants for use in the formulation of detergents, foaming agents, emulsifiers, and degreasers. Some aspects of the invention include formulations suitable for cleaning and/or condition fabrics including upholstery. Some formulations are suitable for in home or commercial dry cleaning. Some of the formulations may be suitable for cleaning hard surfaces including plastic surfaces.

  本发明涉及用于制备洗涤剂、起泡剂、乳化剂和脱脂剂的分支型表面活性剂。本发明的一些方面包括适用于清洁和/或调理织物（包括室内装饰物）的配方。一些配方适用于家庭或商业干洗。其中一些配方可能适用于清洁塑料表面等硬表面。
• [EN] PROCESS FOR PREPARING PHARMACEUTICAL GRADE FERRIC CITRATE<br/>[FR] PROCÉDÉ DE PRÉPARATION DE CITRATE FERRIQUE DE QUALITÉ PHARMACEUTIQUE
  申请人：ACTAVIS GROUP PTC EHF

  公开号：WO2016162888A1

  公开（公告）日：2016-10-13

  The invention relates to a method for preparing pharmaceutical grade ferric citrate that has a BET active surface area of < 16 m2/g and a dissolution rate of 4 to 9 mg/cm2/min. The invention further provides pharmaceutical grade ferric citrate that is characterized by a BET active surface area of < 16 m2/g and a dissolution rate of 4 to 9 mg/cm2/min.

  本发明涉及一种制备药品级柠檬酸铁的方法，其BET活性表面积小于16 m2/g，溶解速率为4至9 mg/cm2/min。本发明还提供了药品级柠檬酸铁，其特征是BET活性表面积小于16 m2/g，溶解速率为4至9 mg/cm2/min。
• Composite polymer electrolyte composition
  申请人：Ogata Naoya

  公开号：US20060057465A1

  公开（公告）日：2006-03-16

  A totally solid polymer electrolyte composition with high ionic conductivity and enhanced mechanical properties is provided. This electrolyte composition is produced by polymerizing a monomer composition comprising a molten quaternary ammonium salt having a polymerizable functional group introduced therein and a charge transfer ion source in the presence of a polymeric reinforcing material. The polymeric reinforcing material can be formed into a composite of polymer blend morphology by dissolving the monomer composition and the reinforcing material in an appropriate organic solvent and polymerizing the solution. Alternatively, the composite can be obtained by impregnating, a porous sheet or film as the reinforcing material with the monomer composition and effecting polymerization. An electrolyte for lithium ion battery can be obtained by selecting a lithium salt as the charge transfer ion source; an electrolyte for fuel cell by selecting a proton donor; and an electrolyte for dye sensitized solar cell by selecting a redox ion pair. A polymer electrolyte composition not containing the charge transfer ion source is also useful as an electrolyte for electrolytic capacitor.

  提供了一种具有高离子导电性和增强机械性能的完全固态聚合物电解质组合物。该电解质组合物是通过在聚合物增强材料的存在下聚合包含具有聚合功能基团的熔融季铵盐和电荷转移离子源的单体组成物而制备的。聚合物增强材料可以通过在适当的有机溶剂中溶解单体组成物和增强材料并聚合溶液来形成聚合物混合物形态的复合材料。或者，可以通过用单体组成物浸渍多孔片或膜作为增强材料并进行聚合来获得复合材料。通过选择锂盐作为电荷转移离子源可以获得用于锂离子电池的电解质；通过选择质子供体可以获得用于燃料电池的电解质；通过选择氧化还原离子对可以获得用于染料敏化太阳能电池的电解质。不含电荷转移离子源的聚合物电解质组合物也可用作电解电容器的电解质。
• Personal care compositions comprising certain dye-polymer complexes
  申请人：Song Zhiqiang

  公开号：US20090060849A1

  公开（公告）日：2009-03-05

  The present invention relates to personal care compositions comprising certain dye-polymer complexes. Additionally, methods for coloration of personal care compositions using said dye-polymer complexes are disclosed.

  本发明涉及含有某些染料-聚合物复合物的个人护理组合物。此外，还公开了使用所述染料-聚合物复合物对个人护理组合物进行着色的方法。