2-(Diethylamino)ethanol;ethenoxyethene

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2-(Diethylamino)ethanol;ethenoxyethene
• 化学式: C10H21NO2
• 分子量: 187.28
• InChiKey: OEXQAHZQRSEXFW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.61
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  32.7
• 氢给体数：
  1
• 氢受体数：
  3

文献信息

• Phenyl-and pyridyl-piperidines with tnf activity
  申请人：——

  公开号：US20040127517A1

  公开（公告）日：2004-07-01

  The present invention relates to compounds of formula (I): 1 in which X represents N or CH; R 1 represents a hydrogen or halogen atom or a CF 3 group; R 2 and R 3 independently represent a hydrogen atom or a methyl group; n is 0 or 1; A represents a condensed heterocyclic group of formula (w) 2 where W completes an aromatic or saturated 6-membered ring system comprising one or two nitrogen atoms or else an aromatic or saturated 5-membered ring system comprising a nitrogen, oxygen or sulfur atom which are optionally substituted, and to their N-oxides and to their salts or solvates, to the pharmaceutical compositions and the medicaments comprising them and to a process for their preparation.

  本发明涉及以下式(I)的化合物： 其中X代表N或CH；R1代表氢或卤素原子或CF3基团；R2和R3独立地代表氢原子或甲基基团；n为0或1；A代表具有以下式(w)2的缩合杂环基团，其中W完成一个含有一个或两个氮原子的芳香或饱和的6元环系统，或者一个含有一个氮、氧或硫原子的芳香或饱和的5元环系统，这些原子可以被取代，以及它们的N-氧化物、盐或溶剂化合物，以及包含它们的药物组合物和药物，以及它们的制备方法。
• PHOTOCURABLE COMPOSITION
  申请人：Fukui Hiroji

  公开号：US20110097669A1

  公开（公告）日：2011-04-28

  The present invention provides a photocurable composition which contains a photobase generator capable of generating a satisfactory amount of a base in a high quantum yield when irradiated even with a small quantity of light for a short time, and contains a curable compound that is rapidly cured by the generated base such that the composition is cured into a cured product. The photocurable composition comprises: a photobase generator (A) which is a salt of a carboxylic acid (a1-1) represented by the following formula (1-1) with a basic compound (a2), and a curable compound (B) which has, in one molecule thereof, at least two functional groups selected from among epoxy group, (meth)acryloyl group, isocyanato group, acid anhydride group, and alkoxysilyl group, where R1 to R7 in the above formula (1-1) each are hydrogen or an organic group, R1 to R7 may be the same or different, and two of R1 to R7 may be bonded to each other to form a ring structure.

  本发明提供了一种光固化组合物，其包含一种光碱发生剂，当短时间内用少量光照射时，能够生成足量碱，并且具有高量子产率，同时含有一种可固化化合物，该化合物能够被生成的碱迅速固化，从而使组合物固化成为固化产物。该光固化组合物包括：光碱发生剂（A），其是由下式（1-1）所表示的羧酸盐（a1-1）与碱性化合物（a2）形成的，以及一种可固化化合物（B），该化合物在一个分子中具有至少两种官能团，所述官能团选自环氧基团、（甲基）丙烯酰基团、异氰酸酯基团、酸酐基团和烷氧基硅基团，其中上述式（1-1）中的R1至R7分别为氢或有机基团，R1至R7可以相同或不同，其中两个R1至R7可以相互连接形成环结构。
• PROCESSES FOR PRODUCING THERMOPLASTIC RESINS, CROSSLINKED RESINS AND CROSSLINKED RESIN COMPOSITE MATERIALS
  申请人：ZEON CORPORATION

  公开号：EP1535941A1

  公开（公告）日：2005-06-01

  The invention relates to a process for the production of post-crosslinkable thermoplastic resins by bulk-polymerizing a polymerizable composition (A) comprising (I) a monomer fluid containing a cyclic olefin (α) having two or more metathetical ring-opening reaction sites in the molecule in an amount 10 wt% or above based on the total amount of the monomers or a monomer fluid containing a norbornene monomer and a crosslinking agent, (II) a metathetical polymerization catalyst, and (III) a chain transfer agent; thermoplastic resins obtained by this process; and a process for producing crosslinked resins or crosslinked resin composite materials which comprises laminating such a thermoplastic resin with a substrate at need and then crosslinking the thermoplastic resin. According to the invention, thermoplastic resins which are free from odor due to residual monomers and excellent in storage stability can be efficiently obtained by a simple process of bulk-polymerizing the composition (A). The process is not only easy and simple but also applicable to continuous production, thus being industrially advantageous. The crosslinked resins and crosslinked resin composite materials obtained according to the invention are excellent in electrical insulation properties, mechanical strengths, heat resistance, dielectric characteristics and so on, thus being useful as electrical materials or the like.

  本发明涉及一种通过批量聚合可聚合组合物（A）来生产可后交联热塑性树脂的工艺，该组合物（A）包含（I）单体流体，该单体流体含有分子中具有两个或两个以上元开环反应位点的环烯烃（α），其含量为单体总量的 10 wt%或以上，或含有降冰片烯单体和交联剂的单体流体、(II) 元聚合催化剂，以及 (III) 链转移剂；通过该工艺获得的热塑性树脂；以及生产交联树脂或交联树脂复合材料的工艺，该工艺包括在需要时将这种热塑性树脂与基材层压，然后使热塑性树脂交联。根据本发明，通过组合物（A）的简单批量聚合工艺，可以有效地获得无残留单体气味且储存稳定性极佳的热塑性树脂。该工艺不仅简单易行，而且适用于连续生产，因此具有工业优势。根据本发明获得的交联树脂和交联树脂复合材料具有优异的电绝缘性能、机械强度、耐热性、介电特性等，因此可用作电气材料或类似材料。
• POLYMERIZABLE COMPOSITION, THERMOPLASTIC RESIN COMPOSITION, CROSSLINKED RESIN, AND CROSSLINKED RESIN COMPOSITE MATERIALS
  申请人：ZEON CORPORATION

  公开号：EP1589054A1

  公开（公告）日：2005-10-26

  A polymerizable composition which comprises (i) a cycloolefin monomer, (ii) a metathesis polymerization catalyst, (iii) a chain transfer agent, (iv) a radical crosslinking agent, and (v) a compound (α) selected from the group consisting of compounds having alkoxyphenol structures wherein each aromatic ring has one or more substituents, compounds having aryloxyphenol structures, and compounds having catechol structures wherein each aromatic ring has two or more substituents; a thermoplastic resin composition which comprises (1) a cycloolefin thermoplastic resin, (2) a radical crosslinking agent, and (3) a compound (α) ; a process for the production thereof; a crosslinked resin obtained by crosslinking the thermoplastic resin composition; and crosslinked resin composite materials produced by laminating a substrate with the thermoplastic resin composition and crosslinking the thermoplastic resin composition. The invention provides a polymerizable composition useful as raw material in the production of a thermoplastic resin composition excellent in storage stability and fluidity in heat lamination; a thermoplastic resin composition and a process for the production thereof; a crosslinked resin obtained by crosslinking the thermoplastic resin composition; and crosslinked resin composite materials exhibiting excellent interlayer adhesion.

  一种可聚合组合物，它包括(i)环烯烃单体，(ii)偏聚催化剂，(iii)链转移剂，(iv)自由基交联剂，和(v)选自以下组别的化合物(α)：具有烷氧基苯酚结构的化合物，其中每个芳香环有一个或多个取代基；具有芳氧基苯酚结构的化合物；以及具有邻苯二酚结构的化合物，其中每个芳香环有两个或多个取代基；一种热塑性树脂组合物，它包括：(1) 环烯烃热塑性树脂；(2) 自由基交联剂；(3) 化合物 (α)；其生产工艺；通过交联该热塑性树脂组合物而获得的交联树脂；以及通过将基材与该热塑性树脂组合物层压并交联该热塑性树脂组合物而生产的交联树脂复合材料。本发明提供了一种可聚合组合物，可作为生产热塑性树脂组合物的原料，该组合物具有优异的储存稳定性和热层压流动性；一种热塑性树脂组合物及其生产工艺；一种通过交联该热塑性树脂组合物而获得的交联树脂；以及具有优异层间粘合性的交联树脂复合材料。
• PROCESS FOR PRODUCING CYCLOOLEFIN RESIN FILM AND PROCESS FOR PRODUCING CYCLOOLEFIN POLYMER SHEET OR FILM
  申请人：ZEON CORPORATION

  公开号：EP1589055A1

  公开（公告）日：2005-10-26

  A process (1) for producing a cycloolefin resin film comprising the steps of: the step (I) of mixing a cycloolefin monomer and a metathesis polymerization catalyst to prepare a polymerizable composition (A); the step (II) of coating or impregnating the supporting body with the polymerizable composition (A) at once after the step(I), and the step (III) of polymerizing the polymerizable composition (A) by bulk polymerization; and a process (2) for producing a cycloolefin polymer sheet or film with the thickness of 1 mm or less comprising polymerizing a reactive solution containing a ruthenium complex catalyst, having a hetero atom-containing carbene compound as a ligand, and a cycloolefin monomer by ring-opening metathesis bulk polymerization, wherein the polymerization of the cycloolefin monomer is completed by heating the reactive solution to 100°C or higher at the heating rate of 20°C/min or more. Thus, a cycloolefin resin film having excellent adhesion to other materials and a cycloolefin polymer sheet of film having a thickness of 1 mm or smaller can be efficiently produced.

  一种生产环烯烃树脂薄膜的工艺（1），包括以下步骤：步骤(I)混合环烯烃单体和偏聚催化剂，制备可聚合组合物(A)； 步骤(II)在步骤(I)后立即用可聚合组合物(A)涂覆或浸渍支撑体，以及 步骤(III)通过批量聚合使可聚合组合物(A)聚合；以及一种生产厚度为 1 毫米或以下的环烯烃聚合物片材或薄膜的工艺 (2)，该工艺包括通过开环偏合成批量聚合将含有钌络合物催化剂的反应溶液和环烯烃单体聚合，钌络合物催化剂具有含杂原子的碳烯化合物作为配体，其中环烯烃单体的聚合是通过以 20°C/min 或更高的加热速率将反应溶液加热至 100°C 或更高来完成的。因此，可以有效地生产出与其他材料具有良好粘附性的环烯烃树脂薄膜和厚度为 1 毫米或更小的环烯烃聚合物薄膜片材。