Perinaphthenone hydrazone | 6968-74-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 非那烯类
• 英文名称: Perinaphthenone hydrazone
• 英文别名: Phenalenon-Hydrazon；phenalen-1-one-hydrazone；Phenalen-1-on-hydrazon；Phenalen-1-ylidenehydrazine
• CAS: 6968-74-7
• 化学式: C₁₃H₁₀N₂
• 分子量: 194.236
• InChiKey: HPLDEWYDQJJTIC-UHFFFAOYSA-N

物化性质

• 熔点：
  125-130 °C (decomp)
• 沸点：
  403.6±48.0 °C(Predicted)
• 密度：
  1.23±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.4
• 氢给体数：
  1
• 氢受体数：
  2

安全信息

• 海关编码：
  2928000090

反应信息

• 作为反应物：
  描述：

  Perinaphthenone hydrazone 在 lead(IV) acetate 、 1,1,2,3-四甲基胍 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以83%的产率得到1-Diazoperinaphthene
  参考文献：
  名称：

  Advantageous Syntheses of Diazo Compounds by Oxidation of Hydrazones with Lead Tetraacetate in Basic Environments

  摘要：

  Varied sensitive diazo compounds 3 are produced efficiently and safely in 3-6 g quantities by oxidation (eq 1) of hydrazones 1 at -78 degrees C with lead tetraacetate (2) in triethylamine/chloroform, N-methylmorpholine/dimethylformamide, tetramethylguanidine (8)/dimethylformamide, and tetramethylguanidine/methylene chloride, respectively, upon use of appropriate workup and handling techniques. New and improved nonhazardous procedures have been developed for preparing and handling hydrazones 1 from aldehydes and ketones in reactions with excess hydrazine.

  DOI：

  10.1021/jo00120a013
• 作为产物：
  描述：

  1H-非那烯 在 chromium(VI) oxide 、 一水合肼 、 乙二醇 、 溶剂黄146 作用下， 生成 Perinaphthenone hydrazone
  参考文献：
  名称：

  Lock; Gergely, Chemische Berichte, 1944, vol. 77/79, p. 461,464

  摘要：

  DOI：

文献信息

• Huenig,S.; Wolff,E., Justus Liebigs Annalen der Chemie, 1970, vol. 732, p. 7 - 25
  作者：Huenig,S.、Wolff,E.

  DOI：——

  日期：——
• Advantageous Syntheses of Diazo Compounds by Oxidation of Hydrazones with Lead Tetraacetate in Basic Environments
  作者：Terrence L. Holton、Harold Schechter

  DOI：10.1021/jo00120a013

  日期：1995.7

  Varied sensitive diazo compounds 3 are produced efficiently and safely in 3-6 g quantities by oxidation (eq 1) of hydrazones 1 at -78 degrees C with lead tetraacetate (2) in triethylamine/chloroform, N-methylmorpholine/dimethylformamide, tetramethylguanidine (8)/dimethylformamide, and tetramethylguanidine/methylene chloride, respectively, upon use of appropriate workup and handling techniques. New and improved nonhazardous procedures have been developed for preparing and handling hydrazones 1 from aldehydes and ketones in reactions with excess hydrazine.
• Lock; Gergely, Chemische Berichte, 1944, vol. 77/79, p. 461,464
  作者：Lock、Gergely

  DOI：——

  日期：——