1-Propenyl-2-naphthol | 57241-38-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-Propenyl-2-naphthol
• 英文别名: 1-Isopropenyl-[2]naphthol；1-Isopropenyl-2-naphthol；1-Prop-1-en-2-ylnaphthalen-2-ol
• CAS: 57241-38-0
• 化学式: C₁₃H₁₂O
• 分子量: 184.238
• InChiKey: YFPBPKPVBZAQFY-UHFFFAOYSA-N

物化性质

• 熔点：
  98-101 °C
• 沸点：
  333.3±11.0 °C(Predicted)
• 密度：
  1.097±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-Propenyl-2-naphthol 在 palladium on activated charcoal 、 溶剂黄146 作用下， 生成 1-isopropyl-2-naphthol
  参考文献：
  名称：

  Takeda; Osaka, Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1955, vol. 75, p. 210

  摘要：

  DOI：
• 作为产物：
  描述：

  乙酸-2-萘酯 在 三氯化铝 作用下， 生成 1-Propenyl-2-naphthol
  参考文献：
  名称：

  关于萘衍生物的“出环”克莱森重排

  摘要：

  当将（E）-和（Z）-1-丙烯基萘-2-基-烯丙基醚（（E / Z）-5）的混合物加热到182°时，只有（E）-异构体会重排以给出'环'积（E / Z）-16，（Z）-5保持不变。在较高的温度（Z）-5下，产生2-甲基萘[2,1- b ]呋喃（15）作为主要产物。β-氯代烯丙基衍生物的混合物（E / Z）-6表现类似。这些发现使我们怀疑“环外”产物16和18是由起始醚（E）-5和（E）-6的直接[1，5 s ]烯丙基迁移形成的。对（E）-和（Z）-5以及独立合成的（E）-和（Z）-1-烯丙基-1-丙烯基-1 H-萘-2-酮（（E）-和（Z）-17表示，但是，醚（E）-5和（E）-6经历两次[3 s，3 s ]重排（即Claisen然后是Cope重排）和氢迁移以产生“环外”产物（E / Z）-16和（E / Z）-18（方案9）。

  DOI：

  10.1002/hlca.19750580235

文献信息

• MONOMER, POLYMER, RESIST COMPOSITION, AND PATTERNING PROCESS
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20140045123A1

  公开（公告）日：2014-02-13

  A polymer comprising recurring units derived from a (meth)acrylate monomer of tertiary ester type having branched alkyl on alicycle is used to form a resist composition. When subjected to exposure, PEB and organic solvent development, the resist composition is improved in dissolution contrast.

  一种聚合物，包括由具有支链烷基的萜酸酯单体衍生的重复单元，用于形成抗蚀组合物。在经过曝光、PEB和有机溶剂显影处理后，抗蚀组合物在溶解对比度方面得到改善。
• Fluorine-Containing Compound, Fluorine-Containing Polymer, Negative-Type Resist Composition, and Patterning Process Using Same
  申请人：ISONO Yoshimi

  公开号：US20120226070A1

  公开（公告）日：2012-09-06

  A fluorine-containing unsaturated carboxylic acid represented by formula (1), wherein R 1 represents a polymerizable double-bond containing group, R 3 represents a fluorine atom or fluorine-containing alkyl group, and W represents a bivalent linking group. This compound can provide a fluorine-containing polymer compound that has a weight-average molecular weight of 1,000-1,000,000 and contains a repeating unit represented by formula (2), wherein R 3 and W are defined as above, each of R 4 , R 5 and R 6 independently represents a hydrogen atom, fluorine atom or monovalent organic group, at least two of R 4 , R 5 and R 6 may be combined to form a ring. This polymer compound can provide a chemically amplified resist composition that is transparent to KrF or ArF excimer laser light and has a high resolution and is capable of forming a pattern having a rectangular section with no swelling.

  化学式（1）所表示的含氟不饱和羧酸，其中R1代表可聚合的双键含基团，R3代表氟原子或含氟烷基团，W代表二价连接基团。该化合物可提供一种分子量为1,000-1,000,000且含有化学式（2）所表示的重复单元的含氟聚合物化合物，其中R3和W如上所定义，R4、R5和R6中的每一个独立地代表氢原子、氟原子或一价有机基团，R4、R5和R6中至少有两个可以结合形成环。该聚合物化合物可提供一种化学增强型光刻胶组合物，该组合物对KrF或ArF准分子激光光线透明，具有高分辨率，并能够形成具有矩形截面且无膨胀的图案。
• Sml2-promoted aryl radical cyclization. A new synthetic entry into heterocycles
  作者：Junji Inanaga、Osamu Ujikawa、Masaru Yamaguchi

  DOI：10.1016/s0040-4039(00)74317-6

  日期：1991.4

  Benzofuran, naphthofuran, and indole frameworks were expediently constructed at ambient temperature from arene bromides with ortho O- and N-substituents containing double or triple bonds via radical cyclization process promoted by Sml2.
• FLUORINE-CONTAINING POLYMER AND ANTI-STATIC AGENT WHEREIN SAME IS USED
  申请人：Central Glass Company, Limited

  公开号：EP2289954B1

  公开（公告）日：2013-01-16
• Fluorine-Containing Polymer and Anti-Static Agent Wherein Same is Used
  申请人：Terui Yoshiharu

  公开号：US20110065857A1

  公开（公告）日：2011-03-17

  There is provided a fluorine-containing polymer having a repeating unit of the general formula (2) and produced by homopolymerization or copolymerization with an other polymerizable double bond-containing monomer. In the formula, W represents a linking group; R 1 each independently represents a perfluoroalkyl group; Q represents a unit structure formed by cleavage of a double bond of a polymerizable double bond-containing group; and M + represents a hydrogen cation, a metal ion or a quaternary ammonium ion. There is also provided an antistatic agent using the above fluorine-containing polymer such that the antistatic agent can impart antistatic performance to an article stably over a long time and show excellent transparency.