2-methacryloyloxyethyl perfluorooctanoate | 14814-77-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: 2-methacryloyloxyethyl perfluorooctanoate
• 英文别名: 2-(2-Methylprop-2-enoyloxy)ethyl 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoate；2-(2-methylprop-2-enoyloxy)ethyl 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoate
• CAS: 14814-77-8
• 化学式: C₁₄H₉F₁₅O₄
• 分子量: 526.199
• InChiKey: ICIPSDRNJYEKLL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  33
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  19

反应信息

• 作为产物：
  描述：

  全氟辛酸 在 氯化亚砜 、 N,N-二甲基甲酰胺 作用下， 反应 13.0h， 生成 2-methacryloyloxyethyl perfluorooctanoate
  参考文献：
  名称：

  Synthesis and characterization of a novel fluorine-containing polymer emulsion with core/shell structure

  摘要：

  A novel fluorine-containing polymer emulsion 4 with core/shell structure was synthesized in water phase by a two-stage emulsion polymerization technique using monomer 3 (i.e., 2-methacryloyloxyethyl perfluorooctanoate (MAEF)) reacting with the monomers such as butyl acrylate (BA), acrylic acid (AA) and styrene (ST). The monomer 3 was synthesized from the intermediate 2 (pentadecafluoro-octanoyl chloride) reacting with P-hydroxyethyl methacrylate (REMA). Polymer film were prepared by coating emulsion 4 directly on a cleaned glass plate and allowed to dry at room temperature. Moreover, the characteristics of polymer film such as hydrophobicity, chemical resistance, surface composition, thermal stability, emulsion particle morphology, as well as the film-forming property were also studied. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2005.12.002

文献信息

• Synthesis and characterization of a novel fluorine-containing polymer emulsion with core/shell structure
  作者：Jinzhang Gao、Xuemei Wang、Yunxia Wei、Wu Yang

  DOI：10.1016/j.jfluchem.2005.12.002

  日期：2006.2

  A novel fluorine-containing polymer emulsion 4 with core/shell structure was synthesized in water phase by a two-stage emulsion polymerization technique using monomer 3 (i.e., 2-methacryloyloxyethyl perfluorooctanoate (MAEF)) reacting with the monomers such as butyl acrylate (BA), acrylic acid (AA) and styrene (ST). The monomer 3 was synthesized from the intermediate 2 (pentadecafluoro-octanoyl chloride) reacting with P-hydroxyethyl methacrylate (REMA). Polymer film were prepared by coating emulsion 4 directly on a cleaned glass plate and allowed to dry at room temperature. Moreover, the characteristics of polymer film such as hydrophobicity, chemical resistance, surface composition, thermal stability, emulsion particle morphology, as well as the film-forming property were also studied. (c) 2006 Elsevier B.V. All rights reserved.