1,3-dihydro-naphtho[1,2-c]thiophene 2-oxide | 31739-49-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,3-dihydro-naphtho[1,2-c]thiophene 2-oxide
• 英文别名: 1.3-Dihydronaphtho<1.2-c>thiophen-2-oxid；Naphtho[1,2-c]thiophene, 1,3-dihydro-, 2-oxide；1,3-dihydrobenzo[g][2]benzothiole 2-oxide
• CAS: 31739-49-8
• 化学式: C₁₂H₁₀OS
• 分子量: 202.277
• InChiKey: JPCLRYZMRVNRID-UHFFFAOYSA-N

物化性质

• 沸点：
  472.8±35.0 °C(Predicted)
• 密度：
  1.36±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  36.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-苯基马来酰亚胺 、 1,3-dihydro-naphtho[1,2-c]thiophene 2-oxide 在 乙酸酐 作用下， 生成 9-phenyl-(7at,10at)-7,7a,10a,11-tetrahydro-7r,11c-episulfano-naphtho[1,2-f]isoindole-8,10-dione 、 9-phenyl-(7ac,10ac)-7,7a,10a,11-tetrahydro-7r,11c-episulfano-naphtho[1,2-f]isoindole-8,10-dione
  参考文献：
  名称：

  Synthetic route to benzo[c]thiophene and the naphtho[c]thiophenes

  摘要：

  DOI：

  10.1021/jo00824a019
• 作为产物：
  描述：

  二苯硫醚 在 bismuth oxybromide 、 氧气 作用下， 以 乙腈 为溶剂， 反应 8.0h， 生成 1,3-dihydro-naphtho[1,2-c]thiophene 2-oxide 、 二苯砜
  参考文献：
  名称：

  Generation of defect clusters for ¹O₂ production for molecular oxygen activation in photocatalysis

  摘要：

  缺陷团簇促进光催化中分子氧活化产生活性氧的产生。

  DOI：

  10.1039/c7ta08117k

文献信息

• SOLID ELECTROLYTIC CAPACITOR AND PROCESS FOR THE PRODUCTION THEREOF
  申请人：Showa Denko K K

  公开号：EP0971382A1

  公开（公告）日：2000-01-12

  A solid electrolytic capacitor includes a valve acting metal having microfine pores, a dielectric film formed on a surface of the valve acting metal, and a solid electrolyte layer provided on the dielectric film, in which at least a portion of the solid electrolyte layer is of a lamellar structure. In particular, a solid electrolytic capacitor includes an electrically conducting polymer having a specified condensed ring structure containing (1) a solid electrolyte layer containing a sulfoquinone anion having a sulfo anion group and a quinone structure and other anion, and (2) a solid electrolyte layer containing an anthracenesulfonate ion and other anion.

  固体电解电容器包括具有微细孔隙的阀门作用金属、形成于阀门作用金属表面的介电膜以及设置在介电膜上的固体电解质层，其中固体电解质层的至少一部分为片状结构。具体而言，固体电解电容器包括具有特定缩合环结构的导电聚合物，其中包含（1）含有磺醌阴离子的固体电解质层，该阴离子具有磺阴离子基团和醌结构以及其他阴离子；以及（2）含有蒽磺酸离子和其他阴离子的固体电解质层。
• FUSED HETEROPOLYCYCLIC COMPOUND, AND METHOD FOR PRODUCING CONDUCTIVE POLYMER IN WHICH SAID COMPOUND IS USED
  申请人：Showa Denko K.K.

  公开号：EP3564229A1

  公开（公告）日：2019-11-06

  The present invention relates to a fused heteropolycyclic compound represented by formulae (1) and (2), a method for producing the same, and a method for producing a conductive polymer represented by formulae (3) and (4) in which at least one compound represented by formula (2) is used (the symbols in the formulae are as described in the description). The method of the present invention is a method for producing a sulfo-group-containing polyisothianaphthene capable of reducing the use amount of an oxidant or capable of being polymerized without the use of any oxidant.

  本发明涉及一种由式(1)和(2)表示的融合杂多环化合物、一种生产该化合物的方法，以及一种生产由式(3)和(4)表示的导电聚合物的方法，其中至少使用了一种由式(2)表示的化合物（式中符号如说明中所描述）。本发明的方法是一种生产含磺基的聚异噻吩的方法，该聚异噻吩能够减少氧化剂的使用量或能够在不使用任何氧化剂的情况下聚合。
• Method for manufacturing solid electrolytic capacitor
  申请人：SHOWA DENKO K.K.

  公开号：US11183340B2

  公开（公告）日：2021-11-23

  A method of producing a solid electrolytic capacitor, including a step of forming a dielectric film on the surface of a valve-acting metal having fine pores and a step of forming a solid electrolyte layer containing a conductive polymer on the dielectric film; wherein the solid electrolyte layer containing the conductive polymer is formed without using an oxidizing agent by: (i) a method of polymerizing at least one of the compounds (A1) represented by formula (1) disclosed herein in the presence of a compound (B) having a sulfo group; (ii) a method of copolymerizing at least one compound (A2) represented by formula (2) disclosed herein; and (iii) a method of polymerizing at least one of the compounds (A1) and (A2).

  一种生产固体电解电容器的方法，包括在具有细孔的阀动金属表面上形成电介质膜的步骤和在电介质膜上形成含有导电聚合物的固体电解质层的步骤；其中含有导电聚合物的固体电解质层是在不使用氧化剂的情况下通过以下方法形成的：(i)在具有磺基的化合物(B)存在下聚合本文所公开的至少一种由式(1)表示的化合物(A1)的方法；(ii)共聚本文所公开的至少一种由式(2)表示的化合物(A2)的方法；以及(iii)聚合化合物(A1)和(A2)中的至少一种的方法。
• Method for producing polyisothianaphthene-based electroconductive polymer
  申请人：SHOWA DENKO K.K.

  公开号：US11136432B2

  公开（公告）日：2021-10-05

  The present invention relates to (i) a method of producing a conductive polymer, comprising polymerizing at least one of compounds (A1) represented by the formula (1) disclosed in the specification in the presence of a compound (B) having sulfo group; (ii) a method of producing a conductive polymer, comprising polymerizing at least one compound selected from a group consisting of at least one compound (A2) represented by the formula (2); and (iii) a method of producing a conductive polymer, comprising copolymerizing at least one compound (A1) and at least one compound selected from a group consisting of at least one compound (A2). The method of the present invention is a method for producing a one-liquid type conductive polymer in which it is possible to easily adjust the solvent affinity, the solubility, and other such aspects of performance according to the purpose.

  本发明涉及(i)生产导电聚合物的方法，包括在具有磺基的化合物(B)存在下聚合至少一种由说明书中公开的式(1)代表的化合物(A1)；(iii) 一种生产导电聚合物的方法，包括将至少一种化合物(A1)和至少一种选自至少 一种化合物(A2)的化合物共聚。本发明的方法是一种生产单液型导电聚合物的方法，在这种方法中，可以根据目的轻松调整溶剂亲和性、溶解性和其他性能方面。
• Solid electrolytic capacitor and method for producing the same
  申请人：Showa Denko K.K.

  公开号：EP1988556B1

  公开（公告）日：2010-01-13