2-mesityl-6-(mesitylamino)-5-nitro-1H-benzo[de]isoquinoline-1,3(2H)-dione | 1446685-93-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-mesityl-6-(mesitylamino)-5-nitro-1H-benzo[de]isoquinoline-1,3(2H)-dione
• 英文别名: 5-Nitro-6-(2,4,6-trimethylanilino)-2-(2,4,6-trimethylphenyl)benzo[de]isoquinoline-1,3-dione；5-nitro-6-(2,4,6-trimethylanilino)-2-(2,4,6-trimethylphenyl)benzo[de]isoquinoline-1,3-dione
• CAS: 1446685-93-3
• 化学式: C₃₀H₂₇N₃O₄
• 分子量: 493.562
• InChiKey: LMZIOPDSTPRPBA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.8
• 重原子数：
  37
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  95.2
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  4-溴-1,8-萘二甲酸酐 、 2,4,6-三甲基苯胺 在 丙酸 作用下， 反应 48.0h， 以89%的产率得到2-mesityl-6-(mesitylamino)-5-nitro-1H-benzo[de]isoquinoline-1,3(2H)-dione
  参考文献：
  名称：

  4-Amino-3-nitro naphthalimides—Structures and spectral properties

  摘要：

  4-Aryl(alkyl)amino-3-nitro-1,8-naphthalimides show substituent and solvent dependent absorbances. The substituent steric volume and character strongly influence the charge transfer within the system. Arylamino-substituted derivatives are strongly NH acidic and their spectra are highly sensitive to even a weak base such as DMF. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jphotochem.2012.10.004

文献信息

• 4-Amino-3-nitro naphthalimides—Structures and spectral properties
  作者：Stanimir Stoyanov、Petar Petrov、Malinka Stoyanova、Miroslav Dangalov、Boris Shivachev、Rosica Nikolova、Ivan Petkov

  DOI：10.1016/j.jphotochem.2012.10.004

  日期：2012.12

  4-Aryl(alkyl)amino-3-nitro-1,8-naphthalimides show substituent and solvent dependent absorbances. The substituent steric volume and character strongly influence the charge transfer within the system. Arylamino-substituted derivatives are strongly NH acidic and their spectra are highly sensitive to even a weak base such as DMF. (C) 2012 Elsevier B.V. All rights reserved.