申请人:Asahi Glass Company, Limited
公开号:EP1813631A1
公开(公告)日:2007-08-01
A process for producing a urethane resin having a low viscosity and usable as a wide range of pressure-sensitive adhesives ranging from a strong-tack region to a slight-tack region, and a pressure-sensitive adhesive are provided.
The process for producing a urethane resin comprises reacting a polyol with a polyisocyanate compound in such a proportion that isocyanate groups are in excess to thereby obtain an isocyanate-group-terminated prepolymer, thereafter reacting the isocyanate-group-terminated prepolymer with a chain extender, and reacting the resultant polymer with a chain terminator, wherein the chain extender has three or more functional groups reactive with an isocyanate group, wherein one of the functional groups is a primary amino group or a secondary amino group, another is a primary hydroxyl group, and the remaining functional group(s) are a secondary hydroxyl group or a tertiary hydroxyl group. The pressure-sensitive adhesive comprises the urethane resin obtained.
本发明提供了一种生产具有低粘度并可用作从强粘性区域到轻微粘性区域的各种压敏粘合剂的聚氨酯树脂的工艺和一种压敏粘合剂。
生产聚氨酯树脂的工艺包括:以异氰酸酯基团过量的比例使多元醇与多异氰酸酯化合物反应,从而得到异氰酸酯基团封端的预聚物,然后使异氰酸酯基团封端的预聚物与扩链剂反应,并使得到的聚合物与链终止剂反应、其中,扩链剂具有三个或三个以上与异氰酸酯基反应的官能团,其中一个官能团为伯氨基或仲氨基,另一个官能团为伯羟基,其余官能团为仲羟基或叔羟基。压敏胶包括所获得的聚氨酯树脂。