N,N-dibromo-2-propanamine | 55877-59-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-dibromo-2-propanamine
• 英文别名: N,N-Dibromoisopropylamin；N,N-Dibromisopropylamin；N,N-dibromopropan-2-amine
• CAS: 55877-59-3
• 化学式: C₃H₇Br₂N
• 分子量: 216.903
• InChiKey: BISNEJKLAGHOSE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N,N-dibromo-2-propanamine 在 氢氧化钾 作用下， 生成 2-propanimine
  参考文献：
  名称：

  Reactions of N , N -dichloroalkylamines with solid base as studied by FTIR combined with DFT calculations

  摘要：

  Products of vacuum gas-solid reactions of N,N-dichloroalkylamines with KOH have been identified by FTIR spectroscopy and DFT calculations. It has been found that the reactions consist of elimination of two Cl atoms accompanied with migration of an H atom, a ring carbon or a methyl group from the alpha -carbon to the N atom and unstable imines with a C=N double bond are formed. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(00)00822-x
• 作为产物：
  描述：

  N,N-Dichloro-2-propanamine 在 copper(ll) bromide 作用下， 生成 N,N-dibromo-2-propanamine
  参考文献：
  名称：

  Zawalski,R.; Kovacic,P., Synthetic Communications, 1978, vol. 8, p. 549 - 562

  摘要：

  DOI：

文献信息

• ZAWALSKI R.; KOVACIC P., SYNTH. COMMUN., 1978, 8, NO 8, 549-562
  作者：ZAWALSKI R.、 KOVACIC P.

  DOI：——

  日期：——
• Reactions of N , N -dichloroalkylamines with solid base as studied by FTIR combined with DFT calculations
  作者：T. Egawa、M. Ito、S. Konaka

  DOI：10.1016/s0022-2860(00)00822-x

  日期：2001.1

  Products of vacuum gas-solid reactions of N,N-dichloroalkylamines with KOH have been identified by FTIR spectroscopy and DFT calculations. It has been found that the reactions consist of elimination of two Cl atoms accompanied with migration of an H atom, a ring carbon or a methyl group from the alpha -carbon to the N atom and unstable imines with a C=N double bond are formed. (C) 2001 Elsevier Science B.V. All rights reserved.
• Zawalski,R.; Kovacic,P., Synthetic Communications, 1978, vol. 8, p. 549 - 562
  作者：Zawalski,R.、Kovacic,P.

  DOI：——

  日期：——