(E)-2-(2-(2,4-dinitrophenyl)hydrazono)-1,2-diphenylethanone | 7499-58-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: (E)-2-(2-(2,4-dinitrophenyl)hydrazono)-1,2-diphenylethanone
• 英文别名: Benzil-2,4-dinitrophenylhydrazon；(2E)-2-[(2,4-dinitrophenyl)hydrazinylidene]-1,2-diphenylethanone
• CAS: 7499-58-3
• 化学式: C₂₀H₁₄N₄O₅
• 分子量: 390.355
• InChiKey: ODXUDQOXIGERFQ-ZBJSNUHESA-N

物化性质

• 熔点：
  184-185 °C
• 沸点：
  565.7±60.0 °C(Predicted)
• 密度：
  1.36±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  29
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  133
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  (E)-2-(2-(2,4-dinitrophenyl)hydrazono)-1,2-diphenylethanone 、 邻苯二胺 、 copper dichloride 以 乙醇 为溶剂， 反应 4.0h， 以69%的产率得到
  参考文献：
  名称：

  Synthesis, XRD and spectroscopic characterization of pharmacologically active Cu(II) and Zn(II) complexes

  摘要：

  The present contribution accounts for the synthesis and structural elucidation of a newly synthesised copper and zinc containing schiff base compounds obtained by the condensation of 1, 2-diphenylethane1, 2-dione and dinitrophenyl hydrazine as main ligand and benzene-1,2-diamine as co-ligand respectively. The synthesised compounds were characterized by several techniques, including elemental analysis, molar conductance and electronic, FT-IR, XRD, mass and H-1 NMR spectral studies. The analytical and molar conductance values indicated that the complexes have square planar and tetrahedral geometry respectively. X-ray powder diffraction illustrates that they are crystalline in nature. The copper and zinc complexes were screened for their antimicrobial potential against some bacterial and fungi strains and the assay indicate that these complexes are good antimicrobial agents against these tested pathogens. (C) 2017 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2017.03.053
• 作为产物：
  描述：

  联苯甲酰 、 2,4-二硝基苯肼 在 盐酸 作用下， 以 乙醇 、 水 为溶剂， 以67%的产率得到(E)-2-(2-(2,4-dinitrophenyl)hydrazono)-1,2-diphenylethanone
  参考文献：
  名称：

  Synthesis, XRD and spectroscopic characterization of pharmacologically active Cu(II) and Zn(II) complexes

  摘要：

  The present contribution accounts for the synthesis and structural elucidation of a newly synthesised copper and zinc containing schiff base compounds obtained by the condensation of 1, 2-diphenylethane1, 2-dione and dinitrophenyl hydrazine as main ligand and benzene-1,2-diamine as co-ligand respectively. The synthesised compounds were characterized by several techniques, including elemental analysis, molar conductance and electronic, FT-IR, XRD, mass and H-1 NMR spectral studies. The analytical and molar conductance values indicated that the complexes have square planar and tetrahedral geometry respectively. X-ray powder diffraction illustrates that they are crystalline in nature. The copper and zinc complexes were screened for their antimicrobial potential against some bacterial and fungi strains and the assay indicate that these complexes are good antimicrobial agents against these tested pathogens. (C) 2017 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2017.03.053

文献信息

• Synthesis, XRD and spectroscopic characterization of pharmacologically active Cu(II) and Zn(II) complexes
  作者：Parveez Gull、Athar Adil Hashmi

  DOI：10.1016/j.molstruc.2017.03.053

  日期：2017.7

  The present contribution accounts for the synthesis and structural elucidation of a newly synthesised copper and zinc containing schiff base compounds obtained by the condensation of 1, 2-diphenylethane1, 2-dione and dinitrophenyl hydrazine as main ligand and benzene-1,2-diamine as co-ligand respectively. The synthesised compounds were characterized by several techniques, including elemental analysis, molar conductance and electronic, FT-IR, XRD, mass and H-1 NMR spectral studies. The analytical and molar conductance values indicated that the complexes have square planar and tetrahedral geometry respectively. X-ray powder diffraction illustrates that they are crystalline in nature. The copper and zinc complexes were screened for their antimicrobial potential against some bacterial and fungi strains and the assay indicate that these complexes are good antimicrobial agents against these tested pathogens. (C) 2017 Elsevier B.V. All rights reserved.