Zn(CNS)2 | 125892-27-5

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: Zn(CNS)2
• CAS: 125892-27-5
• 化学式: CNS*Zn
• 分子量: 123.474
• InChiKey: RRMXYKHVPJSEIM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.66
• 重原子数：
  4.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  22.3
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  Zn(CNS)2 、 硫氰酸酯 以 硝酸 为溶剂， 生成 zinc(II) thiocyanate
  参考文献：
  名称：

  An ultrasonic absorption study of the complex formation of zinc(II) thiocyanate in aqueous solution

  摘要：

  A new method of analysis for the ultrasonic absorption of systems involving multiple coupled equilibria is described. The method consists of calculating the relaxation frequencies and amplitudes under a postulated reaction mechanism using trial values of the rate constants and volume changes and of comparing the computed absorption α/f2 (absorption coefficient over frequency squared) directly with the experimental one. Application of this method to the ultrasonic absorption study of aqueous zinc(II)-thiocyanate solutions reveals that the relaxation absorption is ascribed to the successive complex formation equilibria Zn(SCN)3−nn−1 +SCN−(kn⇄k−n)Zn(SCN)2−nn, n=1–4. The rate constants and volume changes of the above reactions are determined. The method proves to be especially effective when the absorption spectra are associated with multiple coupled equilibria and accordingly too broad to be separated to discrete relaxation processes by the usual method of analysis.

  DOI：

  10.1063/1.449023
• 作为产物：
  描述：

  锌 、 硫氰酸酯 以 硝酸 为溶剂， 生成 Zn(CNS)2
  参考文献：
  名称：

  An ultrasonic absorption study of the complex formation of zinc(II) thiocyanate in aqueous solution

  摘要：

  A new method of analysis for the ultrasonic absorption of systems involving multiple coupled equilibria is described. The method consists of calculating the relaxation frequencies and amplitudes under a postulated reaction mechanism using trial values of the rate constants and volume changes and of comparing the computed absorption α/f2 (absorption coefficient over frequency squared) directly with the experimental one. Application of this method to the ultrasonic absorption study of aqueous zinc(II)-thiocyanate solutions reveals that the relaxation absorption is ascribed to the successive complex formation equilibria Zn(SCN)3−nn−1 +SCN−(kn⇄k−n)Zn(SCN)2−nn, n=1–4. The rate constants and volume changes of the above reactions are determined. The method proves to be especially effective when the absorption spectra are associated with multiple coupled equilibria and accordingly too broad to be separated to discrete relaxation processes by the usual method of analysis.

  DOI：

  10.1063/1.449023
• 作为试剂：
  描述：

  乙烯酮 、 丙酮 在 Zn(CNS)2 作用下， 生成 3,3-二甲基丙烯酸
  参考文献：
  名称：

  Preparation of beta-lactones

  摘要：

  公开号：

  US02450118A1

文献信息

• An ultrasonic absorption study of the complex formation of zinc(II) thiocyanate in aqueous solution
  作者：Kiyoshi Tamura

  DOI：10.1063/1.449023

  日期：1985.11

  A new method of analysis for the ultrasonic absorption of systems involving multiple coupled equilibria is described. The method consists of calculating the relaxation frequencies and amplitudes under a postulated reaction mechanism using trial values of the rate constants and volume changes and of comparing the computed absorption α/f2 (absorption coefficient over frequency squared) directly with the experimental one. Application of this method to the ultrasonic absorption study of aqueous zinc(II)-thiocyanate solutions reveals that the relaxation absorption is ascribed to the successive complex formation equilibria Zn(SCN)3−nn−1 +SCN−(kn⇄k−n)Zn(SCN)2−nn, n=1–4. The rate constants and volume changes of the above reactions are determined. The method proves to be especially effective when the absorption spectra are associated with multiple coupled equilibria and accordingly too broad to be separated to discrete relaxation processes by the usual method of analysis.