7-Oxabicyclo[4.1.0]heptane, oxiranyl-

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 英文名称: 7-Oxabicyclo[4.1.0]heptane, oxiranyl-
• 英文别名: 2-methyloxirane;7-oxabicyclo[4.1.0]heptane
• 化学式: C9H16O2
• 分子量: 156.22
• InChiKey: AVROMNDRDNRBOK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.73
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.1
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Carbon dioxide-philic compounds and methods of synthesis thereof
  申请人：——

  公开号：US20040158013A1

  公开（公告）日：2004-08-12

  A method of synthesizing a CO 2 -philic analog of a CO 2 -phobic compound, includes the step of: reacting the CO 2 -phobic compound with a CO 2 -philic compound selected from the group of a polyether substituted with at least one side group including preferably a Lewis base, a polycarbonate, a polycarbonate substituted with at least one side group including preferably a Lewis base, a vinyl polymer substituted with at least one side group including preferably a Lewis base a poly(ether-ester) or a poly(ether-ester) substituted with at least one side group including preferably a Lewis base, to create the CO 2 -philic analog. A method of synthesizing a CO 2 -phile includes the step of copolymerizing at least two monomers, wherein a polymer formed from homopolymerization of one of the monomers has a T g of less than approximately 250 K and a steric factor less than approximately 1.8, at least one of the monomers contains a group that results in a pendant group from the CO 2 -phile backbone that contains a Lewis base group, and the resultant CO 2 -phile does not contain both hydrogen bond donors and acceptors.

  一种合成 CO 2 -的亲水类似物的方法 2 -疏水性化合物的亲 CO2 类似物的合成方法，包括以下步骤：将 CO 2 -疏水性化合物与 CO 2 -亲水性化合物，该亲水性化合物选自以下组别：被至少一个侧基（最好包括路易斯碱）取代的聚醚、聚碳酸酯、被至少一个侧基（最好包括路易斯碱）取代的聚碳酸酯、被至少一个侧基（最好包括路易斯碱）取代的乙烯基聚合物、聚醚酯或被至少一个侧基（最好包括路易斯碱）取代的聚（醚酯）。 2 -亲水类似物。一种合成 CO 2 -亲和物的合成方法包括至少两种单体共聚的步骤，其中一种单体均聚形成的聚合物的 T g 小于约 250 K，立体因子小于约 1.8，其中至少一种单体含有一个基团，该基团导致来自 CO 2 -亲和基骨架上的悬垂基团，而该基团含有路易斯碱基，由此产生的 CO 2 -亲和物不同时含有氢键供体和受体。
• CARBON DIOXIDE-PHILIC COMPOUNDS AND METHODS OF SYNTHESIS THEREOF
  申请人：UNIVERSITY OF PITTSBURGH

  公开号：EP1220851B1

  公开（公告）日：2004-08-18
• EP1220851A4
  申请人：——

  公开号：EP1220851A4

  公开（公告）日：2003-01-08
• US6686438B1
  申请人：——

  公开号：US6686438B1

  公开（公告）日：2004-02-03
• [EN] CARBON DIOXIDE-PHILIC COMPOUNDS AND METHODS OF SYNTHESIS THEREOF<br/>[FR] COMPOSES CO2-PHILES ET PROCEDES DE SYNTHESE ASSOCIES
  申请人：UNIV PITTSBURGH

  公开号：WO2001021616A1

  公开（公告）日：2001-03-29

  A method of synthesizing a CO2-philic analog of a CO2-phobic compound, includes the step of: reacting the CO2-phobic compound with a CO2-philic compound selected from the group of a polyether substituted with at least one side group including preferably a Lewis base, a polycarbonate, a polycarbonate substituted with at least one side group including preferably a Lewis base, a vinyl polymer substituted with at least one side group including preferably a Lewis base a poly(ether-ester) or a poly(ether-ester) substituted with at least one side group including preferably a Lewis base, to create the CO2-philic analog. A method of synthesizing a CO2-phile includes the step of copolymerizing at least two monomers, wherein a polymer formed from homopolymerization of one of the monomers has a Tg of less than approximately 250 K and a steric factor less than approximately 1.8, at least one of the monomers contains a group that results in a pendant group from the CO2-phile backbone that contains a Lewis base group, and the resultant CO2-phile does not contain both hydrogen bond donors and acceptors.