N²,N⁴-didecyl-1,3,5-triazine-2,4,6-triamine | 858972-52-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: N²,N⁴-didecyl-1,3,5-triazine-2,4,6-triamine
• 英文别名: 2,4-di(n-decylamino)-6-amino-1,3,5-triazine；N2,N4-bis(decyl)melamine；2-N,4-N-didecyl-1,3,5-triazine-2,4,6-triamine
• CAS: 858972-52-8
• 化学式: C₂₃H₄₆N₆
• 分子量: 406.658
• InChiKey: GCPLQKXGZFIDOV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.3
• 重原子数：
  29
• 可旋转键数：
  20
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  88.8
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N²,N⁴-didecyl-1,3,5-triazine-2,4,6-triamine 、 光黃素 以 氘代氯仿 为溶剂， 生成 7,8,10-trimethylbenzo[g]pteridine-2,4(3H,10H)-dione compound with N2,N4-didecyl-1,3,5-triazine-2,4,6-triamine (1:1)
  参考文献：
  名称：

  Non-covalently dendronized flavins as organocatalysts for aerobic reduction of olefins

  摘要：

  A variety of association complexes of synthetic flavin with diaminopyridine and melamine receptors are described in terms of synthesis, association properties, and catalytic activities for aerobic hydrogenation of olefins. The 1:1 association complex of lumiflavin 1 with 2,6-bis(acylamino)pyridine receptor bearing 3,4,5-trialkoxybenzyl ether dendron unit 2 acts as an efficient supramolecular organocatalyst for the aerobic reduction of styrene at ambient temperature under atmospheric air pressure. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.07.082
• 作为产物：
  描述：

  1-氨基癸烷 在 ammonium hydroxide 、 potassium carbonate 作用下， 以 1,4-二氧六环 、 水 、 丙酮 为溶剂， 反应 39.0h， 生成 N²,N⁴-didecyl-1,3,5-triazine-2,4,6-triamine
  参考文献：
  名称：

  Non-covalently dendronized flavins as organocatalysts for aerobic reduction of olefins

  摘要：

  A variety of association complexes of synthetic flavin with diaminopyridine and melamine receptors are described in terms of synthesis, association properties, and catalytic activities for aerobic hydrogenation of olefins. The 1:1 association complex of lumiflavin 1 with 2,6-bis(acylamino)pyridine receptor bearing 3,4,5-trialkoxybenzyl ether dendron unit 2 acts as an efficient supramolecular organocatalyst for the aerobic reduction of styrene at ambient temperature under atmospheric air pressure. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.07.082

文献信息

• Hierarchical organization of a robust porphyrin cage self-assembled by hydrogen bonds
  作者：Sunaina Singh、Amit Aggarwal、Christopher Farley、Brian A. Hageman、James D. Batteas、Charles Michael Drain

  DOI：10.1039/c1cc11553g

  日期：——

  appended with four rigid hydrogen bonding motifs on the meso positions were synthesized and self-assembled into a cofacial cage with four complementary bis(decyl)melamine units in dry solvents. The hydrocarbon chains on the melamine mediate the formation of nanofilms on surfaces as the solvent slowly evaporates.

  在中间位置附加有四个刚性氢键基序的卟啉被合成并自组装成具有四个互补双（癸基）三聚氰胺单元在干燥溶剂中的共面笼。随着溶剂缓慢蒸发，三聚氰胺上的烃链介导了表面纳米膜的形成。
• Coordination-polymeric triethanolamineperchlorato(triflato)metal inner complexes as additives for synthetic polymers
  申请人：Wehner Wolfgang

  公开号：US20090105387A1

  公开（公告）日：2009-04-23

  Stabilizer system for chlorinated polymers, especially PVC, comprising at least one coordination-polymeric triethanolamineperchlorato(triflato)metal inner complex comprising the monomer unit of the formula (A) The stabilizer system may additionally comprise substituted cyanoacetylureas or/and 6-aminouracils or/and 3-aminocrotonic esters or/and hydantoins or/and monomeric or polymeric dihydropyridines or alkaline earth metal hydroxides or/and hydrotalcites or/and dawsonites or/and zeolites or/and glycidyl compounds or/and cyanamides or/and cyanoguanidines or/and melamines. In addition, phosphites or/and sterically hindered amines or/and NOR-HALS compounds may be present.

  氯化聚合物的稳定剂体系，特别是PVC，包括至少一种配位聚合三乙醇胺高氯酸盐（三氟乙酸盐）金属内部络合物，该络合物包括式（A）的单体单位。稳定剂系统还可以包括取代的氰乙酰脲或/和6-氨基尿嘧啶或/和3-氨基巴豆酸酯或/和恒化酮或/和单体或聚合二氢吡啶或碱土金属氢氧化物或/和水滑石或/和道森石或/和沸石或/和环氧丙烷化合物或/和氰胺或/和氰基脲或/和三聚氰胺。此外，磷酸酯或/和立体阻隔胺或/和NOR-HALS化合物也可能存在。
• COORDINATION-POLYMERIC TRIETHANOLAMINEPERCHLORATO(TRIFLATO)METAL INNER COMPLEXES AS ADDITIVES FOR SYNTHETIC POLYMERS
  申请人：Wehner Wolfgang

  公开号：US20090131564A1

  公开（公告）日：2009-05-21

  Stabilizer system for chlorinated polymers, especially PVC, comprising at least one coordination-polymeric triethanolamineperchlorato(triflato)metal inner complex comprising the monomer unit of the formula (A) The stabilizer system may additionally comprise substituted cyanoacetylureas or/and 6-aminouracils or/and 3-aminocrotonic esters or/and hydantoins or/and monomeric or polymeric dihydropyridines or alkaline earth metal hydroxides or/and hydrotalcites or/and dawsonites or/and zeolites or/and glycidyl compounds or/and cyanamides or/and cyanoguanidines or/and melamines. In addition, phosphites or/and sterically hindered amines or/and NOR-HALS compounds may be present.

  氯化聚合物，尤其是PVC的稳定剂系统，包括至少一个配位聚合三乙醇胺高氯酸盐（三氟甲烷磺酸盐）金属内部配合物，其中包括公式（A）的单体单位。稳定剂系统还可以包括取代的氰乙酰脲或/和6-氨基尿嘧啶或/和3-氨基巴豆酸酯或/和咪唑二酮或/和单体或聚合二氢吡啶或碱土金属氢氧化物或/和水滑石或/和达氏石或/和沸石或/和环氧丙烷化合物或/和氰胺或/和氰基脲或/和三聚氰胺。此外，还可以存在亚磷酸酯或/和立体阻碍胺或/和NOR-HALS化合物。
• US7741390B2
  申请人：——

  公开号：US7741390B2

  公开（公告）日：2010-06-22
• Non-covalently dendronized flavins as organocatalysts for aerobic reduction of olefins
  作者：Yasushi Imada、Yudai Kugimiya、Shotaro Iwata、Naruyoshi Komiya、Takeshi Naota

  DOI：10.1016/j.tet.2013.07.082

  日期：2013.10

  A variety of association complexes of synthetic flavin with diaminopyridine and melamine receptors are described in terms of synthesis, association properties, and catalytic activities for aerobic hydrogenation of olefins. The 1:1 association complex of lumiflavin 1 with 2,6-bis(acylamino)pyridine receptor bearing 3,4,5-trialkoxybenzyl ether dendron unit 2 acts as an efficient supramolecular organocatalyst for the aerobic reduction of styrene at ambient temperature under atmospheric air pressure. (C) 2013 Elsevier Ltd. All rights reserved.