tetra-N-benzyl-bibenzyl-α,α'-diyldiamine | 105541-15-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: tetra-N-benzyl-bibenzyl-α,α'-diyldiamine
• 英文别名: N1,N1,N2,N2-Tetrabenzyl-1,2-diphenylethane-1,2-diamine；N,N,N',N'-tetrabenzyl-1,2-diphenylethane-1,2-diamine
• CAS: 105541-15-9
• 化学式: C₄₂H₄₀N₂
• 分子量: 572.793
• InChiKey: DJDGBZNTWKCNRP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.3
• 重原子数：
  44
• 可旋转键数：
  13
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1H-1,2,3-benzotriazol-1-yl-N,N-dibenzyl-phenylmethaneamine 在 samarium diiodide 作用下， 以 四氢呋喃 为溶剂， 生成 tetra-N-benzyl-bibenzyl-α,α'-diyldiamine
  参考文献：
  名称：

  EPR Studies on the SmI₂-Promoted Coupling of N-(N‘,N‘-Dialkylaminoalkyl)benzotriazoles

  摘要：

  [GRAPHICS]Radicals generated in the Sml(2)-promoted coupling of N-(N',N'-dialkylaminoalkyl)benzotriazoles 1 have been detected using the EPR spin-trapping technique, Single electron transfer (SET) between 1 and Sml(2) is discussed as a mechanism for the formation of the radicals.

  DOI：

  10.1021/ol9902733

文献信息

• Synthesis of vicinal diamines by SmI2-promoted reduction of N-(N′,N′-Dialkylaminoalkyl)benzotriazoles
  作者：José M. Aurrecoechea、Alvaro Fernández-Acebes

  DOI：10.1016/s0040-4039(00)61280-7

  日期：1992.8

  N-(N′,N′-Dialkylaminoalkyl)benzotriazoles, derived from aldehydes and secondary amines, react with one equivalent of samarium iodide (SmI2), under mild conditions to afford tertiary vicinal diamines, as a result of C-C coupling between two dialkylaminoalkyl moieties.

  由醛和仲胺衍生的N-（N'，N'-二烷基氨基烷基）苯并三唑在温和的条件下与一当量的碘化sa（SmI 2）反应生成叔邻二胺，这是由于两个二烷基氨基烷基之间的CC偶联部分。
• The chemistry of benzotriazole. A novel method for the synthesis of symmetrical vicinal tertiary and secondary diamines
  作者：Alan R. Katritzky、Weiqiang Fan、Cong Fu

  DOI：10.1021/jo00297a042

  日期：1990.5
• KATRITZKY, ALAN R.;FAN, WEI-QIANG;FU, CONG, J. ORG. CHEM., 55,(1990) N0, C. 3209-3213
  作者：KATRITZKY, ALAN R.、FAN, WEI-QIANG、FU, CONG

  DOI：——

  日期：——
• EPR Studies on the SmI₂-Promoted Coupling of <i>N</i>-(<i>N</i>‘,<i>N</i>‘-Dialkylaminoalkyl)benzotriazoles
  作者：Alan R. Katritzky、Hai-Ying He、Guofang Qiu、Peter J. Bratt、Sidney H. Parrish、Alexander Angerhofer

  DOI：10.1021/ol9902733

  日期：1999.12.1

  [GRAPHICS]Radicals generated in the Sml(2)-promoted coupling of N-(N',N'-dialkylaminoalkyl)benzotriazoles 1 have been detected using the EPR spin-trapping technique, Single electron transfer (SET) between 1 and Sml(2) is discussed as a mechanism for the formation of the radicals.