1,5-di(p-tolyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane | 75606-15-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,5-di(p-tolyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane
• 英文别名: 1,5-Di-p-tolyl-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane；1,5-bis(4-methylphenyl)-3,7-diphenyl-1,5,3,7-diazadiphosphocane
• CAS: 75606-15-4
• 化学式: C₃₀H₃₂N₂P₂
• 分子量: 482.545
• InChiKey: ZMCCTXJIEJYRSL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  34
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,5-di(p-tolyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane 在 copper(l) iodide 作用下， 以 吡啶 为溶剂， 以71%的产率得到{N,N-1,5-di(p-tolyl)-3,7-diphenyl-1,5,3,7-diazadiphosphacyclooctane}pyridine cuprous iodide
  参考文献：
  名称：

  Complexes of 1,3,5-triphenyl-1,3,5-diazaphosphorinane with Pt(II), Co(II), Ni(II), AND Cu(I) salts

  摘要：

  1,3,5-Triphenyl-1,3,5-diazaphosphorinanes form 2:1 complexes with Pt(II), Co(II), Ni(II), and Cu(I). P-31 NMR spectroscopy indicated that Pt, Co, and Ni are coordinated at the phosphorus atoms, while Cu(I) is coordinated at the nitrogen atoms.

  DOI：

  10.1007/bf00959661
• 作为产物：
  描述：

  N-(((l4-boraneyl)(phenyl)((p-tolylamino)methyl)-l5-phosphaneyl)methyl)-N,4-dimethylaniline 以 乙醇 为溶剂， 以30%的产率得到1,5-di(p-tolyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane
  参考文献：
  名称：

  Reaction of 1,3,5-diazaphosphorinanes with borane

  摘要：

  DOI：

  10.1007/bf00957164

文献信息

• [Ni(P^Ph₂N^C6H4X₂)₂]²⁺Complexes as Electrocatalysts for H₂Production: Effect of Substituents, Acids, and Water on Catalytic Rates
  作者：Uriah J. Kilgore、John A. S. Roberts、Douglas H. Pool、Aaron M. Appel、Michael P. Stewart、M. Rakowski DuBois、William G. Dougherty、W. Scott Kassel、R. Morris Bullock、Daniel L. DuBois

  DOI：10.1021/ja109755f

  日期：2011.4.20

  as overpotentials are decreased. Catalytic studies using acids with a range of pK(a) values reveal that turnover frequencies do not correlate with substrate acid pK(a) values but are highly dependent on the acid structure, with this effect being related to substrate size. Addition of water is shown to dramatically increase catalytic rates for all catalysts. With [Ni(P(Ph)(2)N(C6H4CH2P(O)(OEt)2)(2))(2)](BF(4))(2)

  一系列单核镍(II)双(二膦)配合物[Ni(P(Ph)(2)N(C6H4X)(2))(2)](BF(4))(2) (P(Ph)( 2)N(C6H4X)(2) = 1,5-di(para-X-phenyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane；X = OMe, Me, CH(2 )P(O)(OEt)(2)、Br 和 CF(3)) 已被合成和表征。X 射线衍射研究表明 [Ni(P(Ph)(2)N(C6H4Me)(2))(2)](BF(4))(2) 和 [Ni(P(Ph)(2)N (C6H4OMe)(2))(2)](BF(4))(2) 是具有扭曲方形平面几何形状的四坐标。每个配合物的 Ni(II/I) 和 Ni(I/0) 氧化还原对在乙腈中是电化学可逆的，随着 X 给电子特性的增加，其阴极电位越来越高。这些配合物中的每一种都是在 Ni(II/I)
• New Gold(I) Complexes with 1,5-Diaza-3,7-Diphosphacyclooctanes: Synthesis and Structures
  作者：Yu. S. Spiridonova、I. D. Strelnik、E. I. Musina、E. Hey-Hawkins、I. A. Litvinov、A. A. Karasik

  DOI：10.1134/s107032842007009x

  日期：2020.7

  and trinuclear gold(I) complexes are synthesized by the reactions of gold(I) chloride or tetrahydrothiophenegold(I) chloride with 1,5-di(p-tolyl)-3,7-diphenyl-1,5,3,7-diazadiphosphacyclooctane taken in various ratios. The structures of the synthesized compounds are confirmed by NMR spectroscopy, elemental analysis, and X-ray diffraction analysis (CIF files ССDC nos. 1974032 (I) and 1974031 (II)). Unlike

  摘要通过氯化金（I）或氯化四氢噻吩金（I）与1,5-二（对甲苯基）-3,7-二苯基-1,5,3的反应合成了新的双核和三核金（I）配合物，7-二氮杂二磷环辛烷以各种比例服用。合成的化合物的结构通过NMR光谱法，元素分析和X-射线衍射分析（CIF文件，编号DC 1974032（I）和1974031（II））确认。与含P-吡啶基的1,5-二氮杂3,7-二磷环辛烷不同，P-苯基取代的配体在三核金（I）配合物的形成过程中不会发生环扩展的重排。
• Nickel(II) Dihydrogen and Hydride Complexes as the Intermediates of H ₂ Heterolytic Splitting by Nickel Diazadiphosphacyclooctane Complexes
  作者：Nikolay V. Kireev、Alexey S. Kiryutin、Alexander A. Pavlov、Alexandra V. Yurkovskaya、Elvira I. Musina、Andrey A. Karasik、Elena S. Shubina、Konstantin L. Ivanov、Natalia V. Belkova

  DOI：10.1002/ejic.202100489

  日期：2021.11.8

  Reversible binding of H2 is shown for nickel complexes yielding the products of dihydrogen heterolytic splitting [NiH(PR12NR22)(PR12NR22H)]2+ (P2N2=1,5-diaza-3,7-diphosphacyclooctane) whose intermediacy in the reaction has been only anticipated so far. With the help of NMR spectroscopy and parahydrogen induced polarization, the formation of [Ni(η2−H2)(PR12NR22)2]2+ complex was detected for the first time

  镍复合物显示出H 2 的可逆结合，产生二氢异裂产物 [NiH(P R1 2 N R2 2 )(P R1 2 N R2 2 H)] 2+ (P 2 N 2 =1,5-二氮杂-3,7-二磷酸环辛烷），其在反应中的中介作用目前仅被预期。在核磁共振谱和仲氢激发极化的帮助下，[Ni(η 2 -H 2 )(P R1 2 N R2 2 ) 2 ] 2+ 的形成R 1 =Ph，R 2 =Ph 2 CH ，首次检测到复合物。
• Alkylation of aminomethyl derivatives of primary phosphines
  作者：O. A. Erastov、G. N. Nikonov、B. A. Arbuzov

  DOI：10.1007/bf00953167

  日期：1983.6
• Karasik, A. A.; Bobrov, S. V.; Nikonov, G. N., Russian Journal of Coordination Chemistry, 1995, vol. 21, p. 551 - 561
  作者：Karasik, A. A.、Bobrov, S. V.、Nikonov, G. N.、Pisarevskii, A. P.、Litvinov, I. A.、et al.

  DOI：——

  日期：——