5-氯-5-甲基癸烷 | 75458-21-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 中文名称: 5-氯-5-甲基癸烷
• 英文名称: 5-chloro-5-methyl-decane
• 英文别名: 5-Chlor-5-methyl-decan；5-Chloro-5-methyldecane
• CAS: 75458-21-8
• 化学式: C₁₁H₂₃Cl
• 分子量: 190.757
• InChiKey: GXNMWIOLHVTXBK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  5-氯-5-甲基癸烷 、 Dimethylzinc 在 四氯化钛 作用下， 生成 5,5-Dimethyldecan
  参考文献：
  名称：

  Reetz, Manfred T.; Westermann, Juergen; Steinbach, Rainer, Angewandte Chemie, 1980, vol. 92, # 11, p. 931 - 933

  摘要：

  DOI：
• 作为产物：
  描述：

  5-甲基癸烷-5-醇 在 盐酸 作用下， 生成 5-氯-5-甲基癸烷
  参考文献：
  名称：

  Whitmore; Williams, Journal of the American Chemical Society, 1933, vol. 55, p. 408

  摘要：

  DOI：

文献信息

• PARTICLE SIZE DISTRIBUTION CONTROL THROUGH INTERNAL DONOR IN ZIEGLER-NATTA CATALYST
  申请人：Indian Oil Corporation Limited

  公开号：EP2966099A1

  公开（公告）日：2016-01-13

  The present invention describes a process for controlling particle size of a catalyst composition. The process comprising the steps of contacting an internal donor with an organomagnesium precursor solution to form an intermediate solution and treating the intermediate solution with a transition metal compound to form a catalyst composition, wherein particle size of the catalyst composition is controlled by controlling a contact time of the internal donor with the precursor solution during formation of the intermediate solution.

  本发明描述了一种控制催化剂组合物粒度的工艺。该工艺包括以下步骤：将内部供体与有机镁前驱体溶液接触以形成中间溶液，以及用过渡金属化合物处理中间溶液以形成催化剂组合物，其中催化剂组合物的粒度是通过在中间溶液形成过程中控制内部供体与前驱体溶液的接触时间来控制的。
• IMPROVED ZIEGLER-NATTA CATALYST SYNTHESIS AND PROCESS THEREOF
  申请人：Indian Oil Corporation Limited

  公开号：EP3162819A1

  公开（公告）日：2017-05-03

  The present invention describes a process of preparing a catalyst for olefin polymerization comprising: (i) treating a magnesium metal with an organohalide along with an internal donor to obtain a reaction mixture having solid component (A); (ii) treating the reaction mixture having solid component (A) with an acyl halide to obtain a reaction mixture having solid component (B); and (iii) treating the reaction mixture having solid component (B) of step (ii) with a transition metal compound to obtain the catalyst. The present invention also relates to a process for preparation of a catalyst system from said catalyst and preparation of a polyolefins from the catalyst system.

  本发明描述了一种制备烯烃聚合催化剂的工艺，包括：(i) 将金属镁与有机卤化物和内部供体一起处理，得到具有固体组分（A）的反应混合物；(ii) 将具有固体组分（A）的反应混合物与酰基卤化物一起处理，得到具有固体组分（B）的反应混合物；(iii) 将步骤(ii)中具有固体组分（B）的反应混合物与过渡金属化合物一起处理，得到催化剂。本发明还涉及用上述催化剂制备催化剂体系和用催化剂体系制备聚烯烃的工艺。
• PROCESSES FOR THE PREPARATION OF AN OLEFIN POLYMERIZATION CATALYST BASED ON TREATING SOLID ORGANOMAGNESIUM COMPOUNDS WITH TITANIUM MOIETIES
  申请人：INDIAN OIL CORPORATION Ltd.

  公开号：EP3653631A1

  公开（公告）日：2020-05-20

  The present invention relates to a process for preparation of a catalyst composition and the catalyst composition as obtained by said process. The present invention relates to a process for preparation of a catalyst system and to said catalyst system. Finally, the present invention relates to a process of polymerizing and/or copolymerizing olefins.

  本发明涉及一种催化剂组合物的制备工艺和通过所述工艺获得的催化剂组合物。本发明涉及一种催化剂体系的制备工艺和所述催化剂体系。最后，本发明涉及一种聚合和/或共聚烯烃的工艺。
• Organometallic compound in solid form, process for preparing the same and use thereof
  申请人：INDIAN OIL CORPORATION LIMITED

  公开号：US10100136B2

  公开（公告）日：2018-10-16

  The present invention provides a solid organomagnesium precursor having formula Mg(OR′)X}.aMgX2}.bMg(OR′)2}.cR′OH}, wherein R′ is selected from a hydrocarbon group, X is selected from a halide group, and a:b:c is in range of 0.01-0.5:0.01-0.5:0.01-5 and process for preparing the same, said process comprising contacting a magnesium source with a solvating agent, an organohalide and an alcohol to obtain the solid organomagnesium precursor. The present invention also provides a process for preparing a catalyst system using the organomagnesium precursor and its use thereof for polymerization of olefins.

  本发明提供了一种固体有机镁前体，其式为Mg(OR′)X}.aMgX2}.bMg(OR′)2}.cR′OH}，其中R′选自烃基，X选自卤化物基团，a:b:c的范围为0.01-0.5∶0.01-0.5∶0.01-5以及制备该物质的工艺，所述工艺包括将镁源与溶解剂、有机卤化物和醇接触以获得固体有机镁前体。本发明还提供了一种使用有机镁前体制备催化剂体系的工艺及其在烯烃聚合中的应用。
• REETS M. T.; WESTERMANN J.; STEINBACH R., ANGEW. CHEM., 1980, 92, NO 11, 931-933
  作者：REETS M. T.、 WESTERMANN J.、 STEINBACH R.

  DOI：——

  日期：——