3-[6-[5-[3-[4,8-Dimethyl-6-[[3-(6-methyl-4,8-dipropoxythieno[2,3-f][1]benzothiol-2-yl)-5-octyl-4,6-dioxothieno[3,4-c]pyrrol-1-yl]methyl]thieno[2,3-f][1]benzothiol-2-yl]-5-octyl-4,6-dioxothieno[3,4-c]pyrrol-1-yl]thiophen-2-yl]-4,8-dimethylthieno[2,3-f][1]benzothiol-2-yl]-1-methyl-5-octylthieno[3,4-c]pyrrole-4,6-dione

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: 3-[6-[5-[3-[4,8-Dimethyl-6-[[3-(6-methyl-4,8-dipropoxythieno[2,3-f][1]benzothiol-2-yl)-5-octyl-4,6-dioxothieno[3,4-c]pyrrol-1-yl]methyl]thieno[2,3-f][1]benzothiol-2-yl]-5-octyl-4,6-dioxothieno[3,4-c]pyrrol-1-yl]thiophen-2-yl]-4,8-dimethylthieno[2,3-f][1]benzothiol-2-yl]-1-methyl-5-octylthieno[3,4-c]pyrrole-4,6-dione
• 英文别名: 3-[6-[5-[3-[4,8-dimethyl-6-[[3-(6-methyl-4,8-dipropoxythieno[2,3-f][1]benzothiol-2-yl)-5-octyl-4,6-dioxothieno[3,4-c]pyrrol-1-yl]methyl]thieno[2,3-f][1]benzothiol-2-yl]-5-octyl-4,6-dioxothieno[3,4-c]pyrrol-1-yl]thiophen-2-yl]-4,8-dimethylthieno[2,3-f][1]benzothiol-2-yl]-1-methyl-5-octylthieno[3,4-c]pyrrole-4,6-dione
• 化学式: C₈₉H₉₃N₃O₈S₁₀
• 分子量: 1653.4
• InChiKey: UGRAQSMQEMFESH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  28.4
• 重原子数：
  110
• 可旋转键数：
  34
• 环数：
  16.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  413
• 氢给体数：
  0
• 氢受体数：
  18

文献信息

• PI-ELECTRON CONJUGATED BLOCK COPOLYMER AND PHOTOELECTRIC CONVERSION ELEMENT
  申请人：Inagaki Takuya

  公开号：US20140084220A1

  公开（公告）日：2014-03-27

  Provided is a conjugated block copolymer that is capable of morphology control and that can achieve superior conversion efficiency. A π-electron conjugated block copolymer contiguously or non-contiguously bonding polymer block (A) involving a monomer unit having in a portion of a chemical structure at least one heteroaryl skeleton selected from a thiophene, a fluorine, a carbazole, a dibenzosilole and a dibenzogermole; and a polymer block (B) involving a monomer unit similarly having at least one heteroaryl skeleton; wherein the polymer block (A) comprises a homopolymer block of a monomer unit having a substituent R nA that is an alkoxy group or an alkyl group having 1-18 carbon atoms, and the polymer block (B) comprises a copolymer block of at least two different each other types of monomer units having substituent R nB selected from an alkoxy group or an alkyl group having 1-18 carbon atoms, which may be substituted with an alkoxy group, a halogen atom, a hydroxyl group, an amino group, a thiole group, a silyl group, an ester group, an aryl group, hetero aryl group.

  提供的是一种共轭嵌段共聚物，能够控制形态并实现更高的转化效率。该共轭嵌段共聚物由连续或非连续键合的聚合物块（A）和聚合物块（B）组成，聚合物块（A）包括至少在化学结构的一部分中具有来自噻吩、氟、咔唑、二苯基硅烷和二苯基锗烷中至少一个杂环骨架的单体单元，其中聚合物块（A）包括单体单元的同源聚合物块，该单体单元具有取代基RnA，该取代基为具有1-18个碳原子的烷氧基或烷基，并且聚合物块（B）包括至少两种不同类型的单体单元的共聚物块，该单体单元具有取代基RnB，该取代基为具有1-18个碳原子的烷氧基或烷基，可以用烷氧基、卤素原子、羟基、氨基、硫醇基、硅基、酯基、芳基、杂芳基进行取代。