N,N'-bis-[1]naphthylmethylen-ethylenediamine | 113926-82-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N,N'-bis-[1]naphthylmethylen-ethylenediamine
• 英文别名: N,N'-bis-[1]naphthylmethylen-ethylenediamine；N,N'-Bis-[1]naphthylmethylen-aethylendiamin
• CAS: 113926-82-2
• 化学式: C₂₄H₂₀N₂
• 分子量: 336.436
• InChiKey: HEDFJWUXBLLAKT-RPCRKUJJSA-N

物化性质

• 沸点：
  542.5±33.0 °C(Predicted)
• 密度：
  1.07±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.53
• 重原子数：
  26.0
• 可旋转键数：
  5.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  24.72
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  N,N'-bis-[1]naphthylmethylen-ethylenediamine 在 甲烷磺酸 、 四乙基对甲苯磺酸铵 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以62%的产率得到2,3-bis(1-naphthyl)piperazine
  参考文献：
  名称：

  Electroorganic chemistry. 129. Electroreductive synthesis of chiral piperazines and enantioselective addition of diethylzinc to aldehydes in the presence of the chiral piperazines

  摘要：

  Electroreduction of diimines, prepared from 1,2-diamines and aromatic aldehydes, in acidic media gave intramolecularly coupled products, 2,3-diarylpiperazines, stereoselectively. Chiral tri- and tetrasubstituted piperazines were synthesized effectively from chiral 1,2-diamines by the same electroreductive method. Chiral piperazines, prepared from 1(R),2(R)-diaminocyclohexane were effective chiral ligands of catalysts for the enantioselective addition of diethylzinc to aldehydes.

  DOI：

  10.1021/jo00009a026
• 作为产物：
  描述：

  1-萘甲醛 、 乙二胺 生成 N,N'-bis-[1]naphthylmethylen-ethylenediamine
  参考文献：
  名称：

  Addition of Hydrogen Cyanide to Aromatic Schiff Bases

  摘要：

  DOI：

  10.1021/jo01094a021

文献信息

• Late transition metal catalysts for olefin polymerization and oligomerization
  申请人：Cherkasov Kuzunich Vladimir

  公开号：US20060047094A1

  公开（公告）日：2006-03-02

  This invention relates to a transition metal compound represented by the formula LMX wherein M is a Group 3 to 11 metal L is a bulky bidentate or tridentate neutral ligand that is bonded to M by two or three heteroatoms and at least one heteroatom is nitrogen; X is a substituted or unsubstituted catecholate ligand provided that the substituted catecholate ligand does not contain a 1,2-diketone functionality.

  本发明涉及一种由式LMX所表示的过渡金属化合物，其中M是第3到11族金属，L是一种笨重的双或三齿中性配体，通过两个或三个杂原子与M结合，至少一个杂原子是氮；X是一种取代或未取代的邻二酚配体，但取代的邻二酚配体不含1,2-二酮官能团。
• Eckstein; Lukasiewicz, Bulletin de l'Academie Polonaise des Sciences, Serie des Sciences Chimiques, 1959, vol. 7, p. 789,790,795
  作者：Eckstein、Lukasiewicz

  DOI：——

  日期：——
• LATE TRANSITION METAL CATALYSTS FOR OLEFIN POLYMERIZATION AND OLIGOMERIZATION
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：EP1521758B1

  公开（公告）日：2006-05-24
• US7247687B2
  申请人：——

  公开号：US7247687B2

  公开（公告）日：2007-07-24
• Electroorganic chemistry. 129. Electroreductive synthesis of chiral piperazines and enantioselective addition of diethylzinc to aldehydes in the presence of the chiral piperazines
  作者：Tatsuya Shono、Naoki Kise、Eiji Shirakawa、Hideshi Matsumoto、Eiichi Okazaki

  DOI：10.1021/jo00009a026

  日期：1991.4

  Electroreduction of diimines, prepared from 1,2-diamines and aromatic aldehydes, in acidic media gave intramolecularly coupled products, 2,3-diarylpiperazines, stereoselectively. Chiral tri- and tetrasubstituted piperazines were synthesized effectively from chiral 1,2-diamines by the same electroreductive method. Chiral piperazines, prepared from 1(R),2(R)-diaminocyclohexane were effective chiral ligands of catalysts for the enantioselective addition of diethylzinc to aldehydes.