5,12-Dioxatetracyclo[7.5.0.04,13.06,11]tetradecane

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 英文名称: 5,12-Dioxatetracyclo[7.5.0.04,13.06,11]tetradecane
• 英文别名: 5,12-dioxatetracyclo[7.5.0.04,13.06,11]tetradecane
• 化学式: C₁₂H₁₈O₂
• 分子量: 194.27
• InChiKey: ZHPVUQZMNBRGEL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• EPOXY COMPOUND, CURABLE COMPOSITION, CURED PRODUCT, METHOD OF PRODUCING EPOXY COMPOUND, AND REACTIVE DILUENT
  申请人：JXTG NIPPON OIL & ENERGY CORPORATION

  公开号：US20190071409A1

  公开（公告）日：2019-03-07

  The present invention discloses a monoepoxy compound represented by the following Formula (1), a curable composition containing the same, a cured product therefrom, a method of producing the monoepoxy compound, and a reactive diluent containing the monoepoxy compound. The monoepoxy compound represented by the Formula (1) is useful in that it is capable of reducing the viscosity of a curable composition containing the monoepoxy compound, while preventing a reduction in the heat resistance of the curable composition as well as a reduction in the weight of the curable composition upon curing. (In the Formula (1), R 1 to R 6 are each independently selected from the group consisting of a hydrogen atom, an alkyl group, and an alkoxy group.)

  本发明揭示了一种由以下式（1）表示的单环氧化合物，包含该化合物的可固化组合物，由此固化产物，制备单环氧化合物的方法以及含有单环氧化合物的反应性稀释剂。式（1）表示的单环氧化合物有用之处在于，它能够减少含有单环氧化合物的可固化组合物的粘度，同时防止可固化组合物的耐热性和固化后的重量降低。（在式（1）中，R1至R6各自独立地选自氢原子、烷基和烷氧基组成的群）
• EPOXY COMPOUND, CURABLE COMPOSITION CONTAINING THE SAME, AND CURED PRODUCT OBTAINED BY CURING CURABLE COMPOSITION
  申请人：JXTG NIPPON OIL & ENERGY CORPORATION

  公开号：US20190161494A1

  公开（公告）日：2019-05-30

  The present invention discloses a composition comprising at least one or more stereoisomers of a compound represented by the following Formula (1), wherein, in a gas chromatogram obtained by analyzing the composition by gas chromatography, the ratio of the area of the maximum peak with respect to the total area of peaks derived from the stereoisomers is 60% or more; and wherein the maximum peak is present within the range of retention time of from 27.6 to 28.0 minutes. The present invention also discloses: a curable composition comprising the above described composition, and one selected from the group consisting of a thermal cationic polymerization initiator, an acid anhydride-based curing agent and a curing accelerator, and a photo-cationic polymerization initiator; as well as a cured product therefrom. The above described curable composition is useful in that it allows for the production of a cured product having a high heat resistance. (In the Formula (1), R 1 to R 18 are each independently selected from the group consisting of a hydrogen atom, an alkyl group and an alkoxy group.)

  本发明公开了一种组合物，包括由以下式（1）表示的化合物的至少一种立体异构体，其中，在通过气相色谱分析组合物获得的气相色谱图中，立体异构体所得峰的总面积比之下最大峰的面积比为60％或更高；而且最大峰存在于保留时间范围为27.6至28.0分钟之间。本发明还公开了：包括上述组合物和选自热固性阳离子聚合引发剂、酸酐基固化剂和固化促进剂以及光引发的阳离子聚合引发剂的固化组合物；以及由此固化产生的固化产品。上述固化组合物的用处在于它允许生产具有高耐热性的固化产品。（在式（1）中，R1到R18各自独立地选自氢原子、烷基和烷氧基的群体。）
• PHOTOSENSITIVE RESIN COMPOSITION, CURED PRODUCT THEREOF, AND OPTICAL COMPONENT
  申请人：Daicel Corporation

  公开号：EP2826799A1

  公开（公告）日：2015-01-21

  Provided is a photosensitive resin composition that is, after being applied to an adherend surface, rapidly cured by photoirradiation to form a cured product having excellent light-shielding ability and adhesiveness (preferably, further having excellent reflow heat resistance). The photosensitive resin composition includes components (A), (C), and (D) and preferably further includes a component (B) as follows: (A) a cationically polymerizable compound at least including a compound containing an alicyclic epoxy group and devoid of ester bonds; (B) a hydroxyl-containing compound having a molecular weight of 500 or more; (C) a photo-cationic polymerization initiator; and (D) a light-shielding material.

  本发明提供了一种光敏树脂组合物，该组合物在涂覆到粘合剂表面后，可通过光照射快速固化，从而形成具有优异遮光能力和粘合性（最好还具有优异的耐回流热性）的固化产品。光敏树脂组合物包括组分（A）、（C）和（D），最好还包括如下组分（B）： (A) 阳离子可聚合化合物，至少包括含有脂环族环氧基团且不含酯键的化合物； (B) 分子量大于或等于 500 的含羟基化合物； (C) 光阳离子聚合引发剂；及 (D) 遮光材料。
• CURABLE COMPOSITION AND CURED OBJECT OBTAINED BY CURING SAME
  申请人：JXTG Nippon Oil & Energy Corporation

  公开号：EP3434709A1

  公开（公告）日：2019-01-30

  The present invention discloses a curable composition comprising: an epoxy compound represented by the following Formula (1); and one selected from the group consisting of: a thermal cationic polymerization initiator, an acid anhydride-based curing agent and a curing accelerator, and a photo-cationic polymerization initiator as well as the cured product therefrom. The above described curable composition is useful in that it allows for the production of a cured product having a high heat resistance. (In the Formula (1), A represents CR17R18; B represents CR19R20; R1 to R20 each independently represents a substituent selected from the group consisting of a hydrogen atom, an alkyl group and an alkoxy group; and n represents 0 or 1, with the proviso that when n is 0, m represents 1, and when n is 1, m represents 0.)

  本发明公开了一种可固化组合物，该组合物包括：由下式（1）表示的环氧化合物；和选自以下组别的一种：热阳离子聚合引发剂、酸酐基固化剂和固化促进剂、光阳离子聚合引发剂以及由此产生的固化产品。上述固化组合物的作用在于可以生产出具有高耐热性的固化产品。 (在式(1)中，A 代表 CR17R18；B 代表 CR19R20；R1 至 R20 各自独立地代表选自氢原子、烷基和烷氧基组成的组的取代基；n 代表 0 或 1，但条件是当 n 为 0 时，m 代表 1，而当 n 为 1 时，m 代表 0)。
• EPOXY COMPOUND, CURABLE COMPOSITION CONTAINING THIS, AND CURED PRODUCT OF CURABLE COMPOSITION
  申请人：JXTG Nippon Oil & Energy Corporation

  公开号：EP3470449A1

  公开（公告）日：2019-04-17

  The present invention discloses a composition comprising at least one or more stereoisomers of a compound represented by the following Formula (1), wherein, in a gas chromatogram obtained by analyzing the composition by gas chromatography, the ratio of the area of the maximum peak with respect to the total area of peaks derived from the stereoisomers is 90% or more. The present invention also discloses: a curable composition comprising the above described composition, and one selected from the group consisting of a thermal cationic polymerization initiator, an acid anhydride-based curing agent and a curing accelerator, and a photo-cationic polymerization initiator; as well as a cured product therefrom. The above described curable composition is useful in that it allows for the production of a cured product having a high heat resistance. (In the Formula (1), R1 to R18 are each independently selected from the group consisting of a hydrogen atom, an alkyl group and an alkoxy group.)

  本发明公开了一种包含至少一种或多种由下式(1)表示的化合物的立体异构体的组合物，其中，在通过气相色谱法分析该组合物得到的气相色谱图中，最大峰的面积与来自立体异构体的峰的总面积之比为90％或以上。本发明还公开了：一种可固化组合物，该组合物包含上述组合物，以及从热阳离子聚合引发剂、酸酐基固化剂和固化促进剂以及光阳离子聚合引发剂组成的组中选出的一种；以及由其制成的固化产品。上述固化组合物的作用在于可以生产出具有高耐热性的固化产品。 (在式（1）中，R1 至 R18 各自独立地选自由氢原子、烷基和烷氧基组成的组）。