Aethyl-tert.-butyl-trithiocarbonat | 89975-80-4

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫基化合物
• 英文名称: Aethyl-tert.-butyl-trithiocarbonat
• 英文别名: Tert-butylsulfanyl(ethylsulfanyl)methanethione
• CAS: 89975-80-4
• 化学式: C₇H₁₄S₃
• 分子量: 194.386
• InChiKey: ZTJXOWJGECJGIQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  82.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  ethyl chlorodithioformate 、 叔丁基硫醇 在 sodium hydroxide 作用下， 以 苯 为溶剂， 生成 Aethyl-tert.-butyl-trithiocarbonat
  参考文献：
  名称：

  The Synthesis of Organic Trithiocarbonates¹

  摘要：

  DOI：

  10.1021/jo01068a097

文献信息

• Triethylamine-catalyzed one-pot synthesis of trithiocarbonates from carbon disulfide, thiols, and alkyl halides in water
  作者：Barahman Movassagh、Mohammad Soleiman-Beigi

  DOI：10.1007/s00706-008-0864-x

  日期：2008.8

  Symmetrical and unsymmetrical trithiocarbonates were prepared by a simple and efficient one-pot reaction of thiols, carbon disulfide, and alkyl halides in the presence of triethylamine in water at room temperature.

  对称和不对称的三硫代碳酸酯是通过在室温下在水中存在三乙胺的情况下，简单，高效地一锅反应硫醇，二硫化碳和烷基卤来制备的。
• NON-REACTIVE, HYDROPHILIC POLYMERS HAVING TERMINAL SILOXANES AND METHODS FOR MAKING AND USING THE SAME
  申请人：SCALES Charles

  公开号：US20110275734A1

  公开（公告）日：2011-11-10

  The present invention relates to compositions comprising at least one stable, near-monodisperse, non-reactive hydrophilic polymer comprising in said polymer's backbone, a hydrophilic segment having a degree of polymerization of about 10 to about 1000, and a linear silicone segment at least one terminal end of said non-reactive hydrophilic polymer, wherein said silicone segment comprises between about 6 and about 200 siloxy units, and said non-reactive hydrophilic polymer is associated, via the linear silicone block with a silicone hydrogel. The non-reactive hydrophilic polymers may be incorporated into the formulation from which the silicone hydrogel is made or may be contacted with the silicone hydrogel post formation.
• US9522980B2
  申请人：——

  公开号：US9522980B2

  公开（公告）日：2016-12-20
• US9726906B2
  申请人：——

  公开号：US9726906B2

  公开（公告）日：2017-08-08
• US9815979B2
  申请人：——

  公开号：US9815979B2

  公开（公告）日：2017-11-14