(2S,6R)-4-(2-hydroxyethyl)-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: (2S,6R)-4-(2-hydroxyethyl)-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione
• 化学式: C₁₁H₁₃NO₃
• 分子量: 207.23
• InChiKey: WUNGPAHZQWNPEL-WZENYGAOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.4
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  57.6
• 氢给体数：
  1
• 氢受体数：
  3

文献信息

• Copolymer formulation for directed self-assembly, methods of manufacture thereof and articles comprising the same
  申请人：Dow Global Technologies LLC

  公开号：US10351727B2

  公开（公告）日：2019-07-16

  Disclosed herein is a pattern forming method comprising disposing upon a substrate a composition comprising a block copolymer; where the block copolymer comprises a first polymer and a second polymer; where the first polymer and the second polymer of the block copolymer are different from each other and the block copolymer forms a phase separated structure; an additive polymer; where the additive polymer comprises a bottlebrush polymer; and where the bottlebrush polymer comprises a polymer that has a lower or a higher surface energy than the block copolymer; and a solvent; and annealing the composition to facilitate domain separation between the first polymer and the second polymer of the block copolymer to form a morphology of periodic domains formed from the first polymer and the second polymer; where a longitudinal axis of the periodic domains are parallel to the substrate.

  本文公开了一种图案形成方法，该方法包括在基底上放置一种组合物，该组合物包括嵌段共聚物；其中嵌段共聚物包括第一聚合物和第二聚合物；其中嵌段共聚物的第一聚合物和第二聚合物彼此不同，且嵌段共聚物形成相分离结构；添加剂聚合物；其中添加剂聚合物包括瓶丛聚合物；退火组合物，以促进嵌段共聚物的第一聚合物和第二聚合物之间的畴分离，从而形成由第一聚合物和第二聚合物形成的周期性畴的形态；周期性畴的纵轴平行于基底。
• Photonic structures from self assembly of brush block copolymers and polymer blends
  申请人：California Institute of Technology

  公开号：US10732321B2

  公开（公告）日：2020-08-04

  The invention provides a class of block copolymers having a plurality of chemically different blocks, at least a portion of which incorporating polymer side chain groups having a helical secondary structure. The invention also provides structures generated by self-assembly of polymer blends including at least one block copolymer component, such as a brush block polymer or wedge-type block polymer. The invention provides, for example, periodic nanostructures and microstructures generated by self-assembly of block copolymers and polymer blends comprising a mixture of at least one block copolymer component, such as a brush block copolymer, and at least a second component.

  本发明提供了一类具有多个化学性质不同嵌段的嵌段共聚物，其中至少有一部分嵌段共聚物含有具有螺旋状二级结构的聚合物侧链基团。本发明还提供了包括至少一种嵌段聚合物成分的聚合物混合物自组装产生的结构，例如刷状嵌段聚合物或楔形嵌段聚合物。例如，本发明提供了通过嵌段共聚物和聚合物混合物的自组装产生的周期性纳米结构和微结构，聚合物混合物包括至少一种嵌段共聚物组分（如刷型嵌段聚合物）和至少第二种组分的混合物。
• BRUSH BLOCK COPOLYMER INFRARED 1-D PHOTONIC CRYSTALS USING LINEAR POLYMER ADDITIVES
  申请人：CALIFORNIA INSTITUTE OF TECHNOLOGY

  公开号：US20160068669A1

  公开（公告）日：2016-03-10

  The present invention is directed to brush block copolymer compositions comprising first and second homopolymers or random copolymers whose presence provides access to photonic bandgaps in the infrared frequency range, their use in this capacity, and methods of making the same. The specific parameters associated with these compositions are described within the specification.
• COPOLYMER FORMULATION FOR DIRECTED SELF-ASSEMBLY, METHODS OF MANUFACTURE THEREOF AND ARTICLES COMPRISING THE SAME
  申请人：Dow Global Technologies LLC

  公开号：US20160251508A1

  公开（公告）日：2016-09-01

  Disclosed herein is a composition comprising a block copolymer; where the block copolymer comprises a first polymer and a second polymer; where the first polymer and the second polymer of the block copolymer are different from each other and the block copolymer forms a phase separated structure; an additive polymer; where the additive polymer comprises a bottle brush polymer; where the bottle brush polymer comprises a homopolymer that is the chemically and structurally the same as one of the polymers in the block copolymer or where the additive polymer comprises a graft copolymer that has a preferential interaction with one of the blocks of the block copolymers; and a solvent.
• Photonic Structures from Self Assembly of Brush Block Copolymers and Polymer Blends
  申请人：California Institute of Technology

  公开号：US20160356923A1

  公开（公告）日：2016-12-08

  The invention provides a class of block copolymers having a plurality of chemically different blocks, at least a portion of which incorporating polymer side chain groups having a helical secondary structure. The invention also provides structures generated by self-assembly of polymer blends including at least one block copolymer component, such as a brush block polymer or wedge-type block polymer. The invention provides, for example, periodic nanostructures and microstructures generated by self-assembly of block copolymers and polymer blends comprising a mixture of at least one block copolymer component, such as a brush block copolymer, and at least a second component.