2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-1-(4-methylpiperazin-1-yl)heptan-1-one | 560092-29-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: 2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-1-(4-methylpiperazin-1-yl)heptan-1-one
• CAS: 560092-29-7
• 化学式: C₁₂H₁₁F₁₃N₂O
• 分子量: 446.211
• InChiKey: NALAEANMNNNTHF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  28
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  23.6
• 氢给体数：
  0
• 氢受体数：
  15

反应信息

• 作为反应物：
  描述：

  2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-1-(4-methylpiperazin-1-yl)heptan-1-one 、 碘甲烷 以 甲苯 为溶剂， 生成 1,1-dimethyl-4-(2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroenanthyl)piperazinium iodide
  参考文献：
  名称：

  Inhibitory activity of fluorine-containing quaternary ammonium salts comprising an N-methylpiperazinyl moiety

  摘要：

  New fluorine-containing quaternary ammonium salts comprising an N-methylpiperazinyl moiety, which exhibited a high inhibiting capacity against hydrochloric acid corrosion of low-carbon steel, were synthesized. The polarization-resistance method was applied to determine the uniform corrosion rate of steel-3 in relation to the structure and concentration of the fluorine-containing substituents in the salts. It was found that the structure of the fluorine-containing moiety of the quaternary ammonium salts does not significantly influence the corrosion processes.

  DOI：

  10.1134/s1070427213070082
• 作为产物：
  描述：

  N-甲基哌嗪 、 十三氟庚酸乙酯 以 甲苯 为溶剂， 反应 2.0h， 生成 2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-1-(4-methylpiperazin-1-yl)heptan-1-one
  参考文献：
  名称：

  Inhibitory activity of fluorine-containing quaternary ammonium salts comprising an N-methylpiperazinyl moiety

  摘要：

  New fluorine-containing quaternary ammonium salts comprising an N-methylpiperazinyl moiety, which exhibited a high inhibiting capacity against hydrochloric acid corrosion of low-carbon steel, were synthesized. The polarization-resistance method was applied to determine the uniform corrosion rate of steel-3 in relation to the structure and concentration of the fluorine-containing substituents in the salts. It was found that the structure of the fluorine-containing moiety of the quaternary ammonium salts does not significantly influence the corrosion processes.

  DOI：

  10.1134/s1070427213070082

文献信息

• Inhibitory activity of fluorine-containing quaternary ammonium salts comprising an N-methylpiperazinyl moiety
  作者：T. I. Gorbunova、D. N. Bazhin、A. Ya. Zapevalov、V. I. Saloutin

  DOI：10.1134/s1070427213070082

  日期：2013.7

  New fluorine-containing quaternary ammonium salts comprising an N-methylpiperazinyl moiety, which exhibited a high inhibiting capacity against hydrochloric acid corrosion of low-carbon steel, were synthesized. The polarization-resistance method was applied to determine the uniform corrosion rate of steel-3 in relation to the structure and concentration of the fluorine-containing substituents in the salts. It was found that the structure of the fluorine-containing moiety of the quaternary ammonium salts does not significantly influence the corrosion processes.