6-乙基-1,3-苯并噻唑-2(3H)-硫酮 | 21224-17-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 中文名称: 6-乙基-1,3-苯并噻唑-2(3H)-硫酮
• 英文名称: 6-ethyl-3H-benzothiazole-2-thione
• 英文别名: 6-Ethyl-benzothiazolin-2-thion；6-ethyl-3H-1,3-benzothiazole-2-thione
• CAS: 21224-17-9
• 化学式: C₉H₉NS₂
• mdl: MFCD11107893
• 分子量: 195.309
• InChiKey: LEPCXHJXNAUYNN-UHFFFAOYSA-N

物化性质

• 沸点：
  331.6±35.0 °C(Predicted)
• 密度：
  1.33±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.222
• 拓扑面积：
  69.4
• 氢给体数：
  1
• 氢受体数：
  2

安全信息

• 海关编码：
  2934999090

反应信息

• 作为反应物：
  描述：

  6-乙基-1,3-苯并噻唑-2(3H)-硫酮 、 碘甲烷 生成 6-Ethyl-3-methyl-benzothiazolin-2-thion
  参考文献：
  名称：

  驱虫性季盐。3.苯并噻唑盐。

  摘要：

  DOI：

  10.1021/jm00301a008
• 作为产物：
  描述：

  1-(对乙基苯基)-2-硫脲 在 磺酰氯 作用下， 以 氯苯 为溶剂， 反应 2.0h， 生成 6-乙基-1,3-苯并噻唑-2(3H)-硫酮
  参考文献：
  名称：

  驱虫性季盐。3.苯并噻唑盐。

  摘要：

  DOI：

  10.1021/jm00301a008

文献信息

• Cleaner and greener synthesis of 3<i>H</i>-benzothiazole-2-thione and its derivatives
  作者：Nitin Srivastava、Ram Kishore

  DOI：10.1080/17415993.2020.1803321

  日期：2021.1.2

  A cleaner and greener method of synthesis of 3H-benzothiazole-2-thione is being reported in this communication. In this method, various o-iodoaniline derivatives are reacted with carbon disulfide in the presence of Cs2CO3 and tetramethyl ammonium bromide (TMAB) to give 3H-benzothiazole-2-thione and its derivatives in higher yields. GRAPHICAL ABSTRACT

  本通讯报道了一种更清洁、更环保的 3H-苯并噻唑-2-硫酮合成方法。在该方法中，各种邻碘苯胺衍生物在 Cs2CO3 和四甲基溴化铵 (TMAB) 的存在下与二硫化碳反应，以更高的收率得到 3H-苯并噻唑-2-硫酮及其衍生物。图形概要
• Verfahren zur Herstellung von 2-Merkaptobenzthiazolen
  申请人：HOECHST AKTIENGESELLSCHAFT

  公开号：EP0035219A1

  公开（公告）日：1981-09-09

  Herstellung von (ggf. substituiertem) 2-Mercaptobenzthiazol durch Umsetzung von entsprechenden 2-Halogenanilinen mit Alkali- oder Erdalkalixanthat bzw. mit CS2 in Gegenwart von Basen.

  在碱存在下，通过相应的 2-卤苯胺与碱金属或碱土金属黄原酸盐或 CS2 反应，制备（任选取代的）2-巯基苯并噻唑。
• Process for the stabilization of mercaptobenzothiazole in a lubricating oil composition
  申请人：EXXON RESEARCH AND ENGINEERING COMPANY

  公开号：EP0207737A2

  公开（公告）日：1987-01-07

  There is disclosed a process for the solubilization of a mercaptobenzothiazole amine salt with a solvent such as dihexyl phthalate which solubilized salt is in turn suitable for dissolution into a lubricating oil composition, such as an automatic transmission fluid, even at room temperature.

  本发明公开了一种用邻苯二甲酸二己酯等溶剂增溶巯基苯并噻唑胺盐的工艺，增溶后的盐即使在室温下也适合溶解到自动变速箱油等润滑油组合物中。
• Rubber composition for tire tread and pneumatic tire using the rubber composition
  申请人：BRIDGESTONE CORPORATION

  公开号：EP0818500A1

  公开（公告）日：1998-01-14

  The present invention provides a rubber composition for a tire tread which comprises 100 parts by weight of a rubber component comprising 50 parts by weight or more of SBR and the remaining amount of a synthetic rubber and/or natural rubber, 25 parts by weight or more of a softener, and 0.5 to 5.0 parts by weight of a vulcanization accelerator, such as bis(4-methylbenzothiazolyl-2)-disulfide, bis(5-methylbenzothiazolyl-2)-disulfide, mercapto-4-methylbenzothiazole, and mercapto-5-methylbenzothiazole, and a pneumatic tire produced by using this rubber composition. A tire having excellent controllability and ride quality throughout tire life can be provided.

  本发明提供了一种用于轮胎胎面的橡胶组合物，该组合物包括 100 份（按重量计）的橡胶组分，其中 50 份（按重量计）或更多的丁苯橡胶和剩余量的合成橡胶和/或天然橡胶，25 份（按重量计）或更多的软化剂，以及 0.5 至 5.0 重量份的硫化促进剂，如双(4-甲基苯并噻唑-2)-二硫化物、双(5-甲基苯并噻唑-2)-二硫化物、巯基-4-甲基苯并噻唑和巯基-5-甲基苯并噻唑，以及使用这种橡胶组合物生产的充气轮胎。这种轮胎在整个轮胎寿命期间都具有优异的可控性和行驶质量。
• Agricultural or industrial tire with reinforced rubber composition
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP1559587A2

  公开（公告）日：2005-08-03

  The present invention is directed a pneumatic agricultural or industrial tire (20) comprising a casing (21) and a rubber tread (32A, 32B, 34) disposed radially outwardly of the casing (21), the tread having an inner tread (34) and a plurality of tread lugs (50) projecting radially from the inner tread (34), said casing (21) having at least one component (22, 26, 28), said component comprising textile cord and a rubber composition in contact with the textile cord, the rubber composition comprising    100 parts by weight of at least one diene based elastomer, including from 75 to 15 parts by weight of polybutadiene and 25 to 85 parts by weight of at least one additional diene based elastomer selected from the group consisting of styrene-butadiene rubber, synthetic polyisoprene and natural polyisoprene;    0.1 to 8 parts by weight of at least one accelerator selected from benzothiazoles and dithiophosphates and exclusive of sulfenamides;    1 to 15 parts by weight of at least one resin selected from phenolformaldehyde resins, aliphatic cyclic hydrocarbon resins, and aromatic hydrocarbon resin;    10 to 150 parts by weight of a filler selected from the group consisting of carbon black, silica, and starch/plasticizer composite filler; and    0.3 to 3 parts by weight of sulfur;    wherein each lug has a width in a range of from 2 cm to 10 cm and length in a range of from 2 cm to 60 cm, and a height in a range of from 2 cm to 10 cm, and wherein the tread has a net-to-gross ratio in a range of from 15 to 40 percent as measured around the entire 360° circumference of a normally inflated and normally loaded tire contacting a flat hard surface.

  本发明涉及一种充气农业或工业轮胎（20），包括胎体（21）和从胎体（21）径向向外设置的橡胶胎面（32A、32B、34），胎面具有内胎面（34）和从内胎面（34）径向伸出的多个胎耳（50），所述胎体（21）具有至少一个部件（22、26、28），所述部件包括纺织帘线和与纺织帘线接触的橡胶组合物，所述橡胶组合物包括 100 份（按重量计）至少一种二烯基弹性体，包括 75 至 15 份（按重量计）聚丁二烯和 25 至 85 份（按重量计）至少另外一种二烯基弹性体，该弹性体选自由丁苯橡胶、合成聚异戊二烯和天然聚异戊二烯组成的组； 0.1 至 8 份（按重量计）至少一种促进剂，该促进剂选自苯并噻唑和二硫代磷酸 酯，但不包括亚氨基磺酸盐； 1 至 15 份（按重量计）至少一种树脂，选自苯酚甲醛树脂、脂肪族环状烃树脂和芳香族烃树脂； 10 至 150 份（按重量计）选自碳黑、二氧化硅和淀粉/增塑剂复合填料组的填料；以及 0.3 至 3 重量份的硫； 其中每个胎耳的宽度范围为 2 厘米至 10 厘米，长度范围为 2 厘米至 60 厘米，高度范围为 2 厘米至 10 厘米，并且胎面的净毛比范围为 15%至 40%，该范围是在正常充气和正常装载的轮胎接触平硬表面的整个 360° 圆周上测量的。