thiozone | 12597-03-4

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 其他非金属有机物
• 英文名称: thiozone
• 英文别名: Trithiirane
• CAS: 12597-03-4
• 化学式: S₃
• 分子量: 96.198
• InChiKey: JSKOEFHOIIVIGK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  75.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  thiozone(1+) 、 氨 以 gas 为溶剂， 生成 thiozone
  参考文献：
  名称：

  Gas‐phase reactivity of sulphur ions with ammonia

  摘要：

  The gas-phase reactions of sulphur cluster ions, cations S+n (n=1,...,8) and anions S−n (n=2,...,6) with NH3 have been studied by means of a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. Relative and absolute reaction rate constants as well as reaction efficiencies have been determined. The S+4 cation has by the far highest reactivity with all other sulphur cations being significantly less reactive. Besides some fragmentation, no reactivity of the anions was found. Structural conclusions are made based on the present experiments, on previous extensive ab initio calculations, and on complementary experiments.

  DOI：

  10.1063/1.465499

文献信息

• Gas‐phase reactivity of sulphur ions with ammonia
  作者：Gereon Niedner‐Schatteburg、Thomas Schindler、Christian Berg、Dirk Wössner、Vladimir E. Bondybey

  DOI：10.1063/1.465499

  日期：1993.12.15

  The gas-phase reactions of sulphur cluster ions, cations S+n (n=1,...,8) and anions S−n (n=2,...,6) with NH3 have been studied by means of a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. Relative and absolute reaction rate constants as well as reaction efficiencies have been determined. The S+4 cation has by the far highest reactivity with all other sulphur cations being significantly less reactive. Besides some fragmentation, no reactivity of the anions was found. Structural conclusions are made based on the present experiments, on previous extensive ab initio calculations, and on complementary experiments.