5-(phthalimidomethyl)bicyclo[2.2.1]hept-2-ene | 56384-98-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: 5-(phthalimidomethyl)bicyclo[2.2.1]hept-2-ene
• 英文别名: NBMPI；2-(2-Bicyclo[2.2.1]hept-5-enylmethyl)isoindole-1,3-dione
• CAS: 56384-98-6
• 化学式: C₁₆H₁₅NO₂
• 分子量: 253.301
• InChiKey: YTEHQZDHWWLTII-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  37.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  苯酐 、 5-降冰片烯-2-甲胺 以 氯仿 为溶剂， 反应 12.0h， 生成 5-(phthalimidomethyl)bicyclo[2.2.1]hept-2-ene
  参考文献：
  名称：

  Norbornene compounds with cross-linkable groups and their derivatives

  摘要：

  本发明提供了一种具有可交联基团的去环戊烯化合物及其衍生聚合物，其中所述可交联基团为烯烃或环氧基团。通过活性环开拆聚合方法制备了具有可交联侧链的去环戊烯聚合物及其嵌段共聚物以及改性衍生物。所得聚合物具有优异的溶解性和光学性能，具有窄分子量分布、良好控制的分子量、小的折射率和高透明度。它们还适用于制备具有高热稳定性和化学抗性的混合材料。

  公开号：

  US07132565B2

文献信息

• Self-Assembly Aggregation of Highly Stable Copolynorbornenes with Amphiphilic Architecture via Ring-Opening Metathesis Polymerization
  作者：Der-Jang Liaw、Tsang-Pin Chen、Ching-Cheng Huang

  DOI：10.1021/ma048015v

  日期：2005.4.1
• Norbornene monomers with an epoxy group and polymer material thereof
  申请人：Liaw Der-Jang

  公开号：US20090043059A1

  公开（公告）日：2009-02-12

  Norbornene monomers with epoxy groups and polymer materials thereof are disclosed. The Norbornene monomers with epoxy groups are prepared by Diels-Alder reaction. The Norbornene monomers with epoxy groups are highly active for ring-opening-metathesis polymerization (ROMP), and the molecular weight and PDI value of the obtained polymers are controllable.
• NORBORNENE COMPOUNDS WITH CROSS-LINKABLE GROUPS AND THEIR DERIVATIVES
  申请人：Liaw Der-Jang

  公开号：US20100087659A1

  公开（公告）日：2010-04-08

  The present invention provided a norbornene compound with cross-linkable groups and their derivative polymers, wherein said cross-linkable groups were olefin or epoxy groups. Norbornene polymers with cross-linkable side chain and their block copolymers as well as modified derivatives were prepared via living ring-open metathesis polymerization method. The resulting polymers with excellent solubility and optic properties had narrow molecular weight distribution, well-controlled molecular weight, small refraction index and high transparency. They were also suitable for preparing hybrid materials with high thermal stability and chemical resistance.
• MALEIMIDE CONTAINING CYCLOOLEFINIC POLYMERS AND APPLICATIONS THEREOF
  申请人：Promerus, LLC

  公开号：US20140087293A1

  公开（公告）日：2014-03-27

  Various cycloolefinic/maleic anhydride polymers containing maleimide pendant groups and compositions thereof useful for forming self-imageable films encompassing such copolymers are disclosed. Such polymers encompass norbornene-type repeating units containing maleimide groups and maleic anhydride-type repeating units where at least some of such maleic anhydride-type repeating units have been ring-opened. The films formed from such copolymer compositions provide self imageable, low-k, thermally stable layers for use in microelectronic and optoelectronic devices.
• US4080491A
  申请人：——

  公开号：US4080491A

  公开（公告）日：1978-03-21