N,N,N',N'-tetrakis-(p-allylphenyl)-biphenyl-4,4'-diamine | 640756-41-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N,N',N'-tetrakis-(p-allylphenyl)-biphenyl-4,4'-diamine
• 英文别名: 4-prop-2-enyl-N-(4-prop-2-enylphenyl)-N-[4-[4-(4-prop-2-enyl-N-(4-prop-2-enylphenyl)anilino)phenyl]phenyl]aniline
• CAS: 640756-41-8
• 化学式: C₄₈H₄₄N₂
• 分子量: 648.891
• InChiKey: FALCCCNUJSHBTG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.3
• 重原子数：
  50
• 可旋转键数：
  15
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N,N,N',N'-tetrakis-(p-allylphenyl)-biphenyl-4,4'-diamine 在 dihydrogen hexachloroplatinate 、 三氯硅烷 作用下， 以 二氯甲烷 为溶剂， 反应 6.0h， 以98%的产率得到N,N,N',N'-tetrakis-[(p-trichlorosilylpropyl)-phenyl]-biphenyl-4,4'-diamine
  参考文献：
  名称：

  Organic light-emitting diodes and related hole transport compounds

  摘要：

  新的有机发光二极管及相关的空穴传输化合物和制备方法，使用硅氧烷自组装技术。

  公开号：

  US20050234256A1
• 作为产物：
  描述：

  4,4’-双[(4-溴苯基)苯氨基]联苯 在 正丁基锂 、 tetra-N-butylammonium tribromide 作用下， 以 乙醚 、 正己烷 、 氯仿 为溶剂， 反应 14.58h， 生成 N,N,N',N'-tetrakis-(p-allylphenyl)-biphenyl-4,4'-diamine
  参考文献：
  名称：

  Molecularly “Engineered” Anode Adsorbates for Probing OLED Interfacial Structure−Charge Injection/Luminance Relationships:  Large, Structure-Dependent Effects

  摘要：

  Molecule-scale structure effects at organic light-emitting diodes (OLED) anode-organic transport layer interfaces are probed via a self-assembly approach. A series of ITO anode-linked silyltriarylamine molecules differing in aryl group and linker density are synthesized for this purpose and used to probe the relationship between nanoscale interfacial chemical structure, charge injection and electroluminescence properties. Dramatic variations in hole injection magnitude and OLED performance can be correlated with the molecular structures and electrochemically derived heterogeneous electron-transfer rates of such triarylamine fragments, placed precisely at the anode-hole transport layer interface. Very bright and efficient ( approximately 70 000 cd/m2 and approximately 2.5% forward external quantum efficiency) OLEDs have thereby been fabricated.

  DOI：

  10.1021/ja037174b

文献信息

• Organic light-emitting diodes and related hole transport compounds
  申请人：Marks J. Tobin

  公开号：US20050234256A1

  公开（公告）日：2005-10-20

  New organic light-emitting diodes and related hole transport compounds and methods for fabrication, using siloxane self-assembly techniques.

  新的有机发光二极管及相关的空穴传输化合物和制备方法，使用硅氧烷自组装技术。
• WHITE LIGHT EMISSION ORGANIC ELECTROLUMINESCENT ELEMENT, ILLUMINATING DEVICE AND DISPLAY
  申请人：Nakayama Yoriko

  公开号：US20110084601A1

  公开（公告）日：2011-04-14

  Disclosed is a coating type organic EL element having excellent chromaticity stability to driving current, excellent chromaticity stability during continuous driving and excellent color rendering property.
• US7750175B2
  申请人：——

  公开号：US7750175B2

  公开（公告）日：2010-07-06
• US8475938B2
  申请人：——

  公开号：US8475938B2

  公开（公告）日：2013-07-02
• Molecularly “Engineered” Anode Adsorbates for Probing OLED Interfacial Structure−Charge Injection/Luminance Relationships:  Large, Structure-Dependent Effects
  作者：Qinglan Huang、Guennadi Evmenenko、Pulak Dutta、Tobin J. Marks

  DOI：10.1021/ja037174b

  日期：2003.12.1

  Molecule-scale structure effects at organic light-emitting diodes (OLED) anode-organic transport layer interfaces are probed via a self-assembly approach. A series of ITO anode-linked silyltriarylamine molecules differing in aryl group and linker density are synthesized for this purpose and used to probe the relationship between nanoscale interfacial chemical structure, charge injection and electroluminescence properties. Dramatic variations in hole injection magnitude and OLED performance can be correlated with the molecular structures and electrochemically derived heterogeneous electron-transfer rates of such triarylamine fragments, placed precisely at the anode-hole transport layer interface. Very bright and efficient ( approximately 70 000 cd/m2 and approximately 2.5% forward external quantum efficiency) OLEDs have thereby been fabricated.