N¹,N¹,N²,N²-tetracyclohexylethane-1,2-diamine | 3261-33-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N¹,N¹,N²,N²-tetracyclohexylethane-1,2-diamine
• 英文别名: N,N,N',N'-Tetra-cyclohexyl-aethylendiamin；tetra-N-cyclohexyl-ethylenediamine；Tetra-N-cyclohexyl-aethylendiamin；N,N,N',N'-tetracyclohexyl-1,2-ethanediamine；N,N,N',N'-Tetracyclohexyl ethylene diamine；N,N,N',N'-tetracyclohexylethane-1,2-diamine
• CAS: 3261-33-4
• 化学式: C₂₆H₄₈N₂
• 分子量: 388.681
• InChiKey: LJVHUNUMQUEARE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  28
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N¹,N¹,N²,N²-tetracyclohexylethane-1,2-diamine 在 tris(bipyridine)ruthenium(II) dichloride hexahydrate 、 水 、 氧气 、 silica gel 、 caesium carbonate 作用下， 以 乙腈 为溶剂， 反应 60.0h， 以82%的产率得到N,N-二环己基甲酰胺
  参考文献：
  名称：

  可见光催化的CC键断裂：由1,2-邻位二胺制备 N，N-二烷基甲酰胺

  摘要：

  在非常温和的条件下，Ru（bpy）3 Cl 2光催化剂，45 W家用电灯泡和Cs 2 CO 3碱性添加剂的协同作用下，将一系列1,2-邻位二胺顺利转化为N，N-二烷基甲酰胺反应条件。该过程涉及可见光激活的C–C键的光催化裂解，这是战略性事件。

  DOI：

  10.1016/j.tet.2013.07.056
• 作为产物：
  描述：

  ethyleneglycol dibenzenesulfonate 、 二环己胺 生成 N¹,N¹,N²,N²-tetracyclohexylethane-1,2-diamine
  参考文献：
  名称：

  Preparation of N,N,N',N'-Tetrasubstituted Diamines

  摘要：

  DOI：

  10.1021/ja01151a521

文献信息

• RADIATION-CURABLE POLYMERIZABLE COMPOSITION, INK COMPOSITION, INKJET RECORDING METHOD, PRINTED MATERIAL, PLANOGRAPHIC PRINTING PLATE, AND METHOD FOR FORMING PLANOGRAPHIC PRINTING PLATE
  申请人：YOKOI Kazuhiro

  公开号：US20080187727A1

  公开（公告）日：2008-08-07

  The invention provides a radiation-curable polymerizable composition of the invention having (a) a hindered amine compound having no nucleophilic moiety in a molecule, (b) a photo-acid generating agent and (c) a cationic polymerizable monomer. The invention further provides an ink composition formed of the radiation-curable polymerizable composition, a method for ink jet recording having: ejecting the ink composition onto a recording medium by using an ink jet recording apparatus and irradiating the ejected ink composition so as to cure the ink composition, and a printed material obtained thereby. The invention further provides a method for forming a planographic printing plate having: ejecting the ink composition onto a hydrophilic recording medium by using an ink jet recording apparatus; and irradiating the ejected ink composition so as to cure the ink composition for forming a hydrophobic region, and a planographic printing plate obtained thereby.

  本发明提供了一种辐射可固化的聚合物组合物，其包含(a)一种分子中没有亲核基团的受阻胺化合物，(b)一种光酸发生剂和(c)一种阳离子聚合单体。本发明还提供了一种由辐射可固化的聚合物组合物形成的墨水组合物，以及一种喷墨记录方法，其包括：使用喷墨记录设备将墨水组合物喷射到记录介质上，并照射所喷射的墨水组合物以固化墨水组合物，以及通过该方法得到的印刷材料。本发明还提供了一种形成平面印刷版的方法，其包括：使用喷墨记录设备将墨水组合物喷射到亲水性记录介质上；并照射所喷射的墨水组合物以固化墨水组合物以形成疏水区域，以及通过该方法得到的平面印刷版。
• Radiation-curable polymerizable composition, ink composition, inkjet recording method, printed material, planographic printing plate, and method for forming planographic printing plate
  申请人：FUJIFILM Corporation

  公开号：EP1952982A1

  公开（公告）日：2008-08-06

  The invention provides a radiation-curable polymerizable composition of the invention having (a) a hindered amine compound having no nucleophilic moiety in a molecule, (b) a photo-acid generating agent and (c) a cationic polymerizable monomer. The invention further provides an ink composition formed of the radiation-curable polymerizable composition, a method for ink jet recording having: ejecting the ink composition onto a recording medium by using an ink jet recording apparatus and irradiating the ejected ink composition so as to cure the ink composition, and a printed material obtained thereby. The invention further provides a method for forming a planographic printing plate having: ejecting the ink composition onto a hydrophilic recording medium by using an ink jet recording apparatus; and irradiating the ejected ink composition so as to cure the ink composition for forming a hydrophobic region, and a planographic printing plate obtained thereby.

  本发明提供了一种本发明的辐射固化可聚合组合物，该组合物具有(a)分子中无亲核分子的受阻胺化合物，(b)光酸生成剂和(c)阳离子可聚合单体。本发明进一步提供了一种由辐射固化可聚合组合物形成的油墨组合物、一种喷墨记录方法，该方法包括：使用喷墨记录装置将油墨组合物喷射到记录介质上，并照射喷射出的油墨组合物以固化油墨组合物，以及由此获得的印刷材料。本发明进一步提供了一种平版印刷板的形成方法，该方法具有：使用喷墨记录装置将油墨组合物喷射到亲水性记录介质上；照射喷射出的油墨组合物以固化油墨组合物，从而形成疏水区域，以及由此获得的平版印刷板。
• Ink composition and inkjet recording method
  申请人：Fujifilm Corporation

  公开号：EP2169018A2

  公开（公告）日：2010-03-31

  An ink composition is provided that includes (A) a pigment other than titanium oxide, (B) a cationically polymerizable compound, and (C) a photo-acid generator, the pigment (A) having a content of 3.5 to 20 wt %, the cationically polymerizable compound (B) containing only an oxirane compound and/or an oxetane compound, the oxirane compound and/or the oxetane compound containing a low-viscosity compound having a viscosity at 25°C of no greater than 12 mPa·s, and the low-viscosity compound having a total content of 65 to 100 wt % relative to the total weight of the cationically polymerizable compound (B). There is also provided an ink composition that includes (A') titanium oxide, (B) a cationically polymerizable compound, and (C) a photo-acid generator, the titanium oxide (A') having a content of 35 to 45 wt %, the cationically polymerizable compound (B) containing an oxirane compound, oxetane compound, or vinyl ether compound having a viscosity at 25°C of no greater than 12 mPa·s, and the oxirane compound, oxetane compound, and vinyl ether compound having a viscosity at 25°C of no greater than 12 mPa·s having a total content of 65 to 100 wt % relative to the total weight of the cationically polymerizable compound (B). There is also provided an inkjet recording method that includes (a1) a step of discharging the ink composition above onto a recording medium and (b1) a step of curing the ink composition by irradiating the discharged ink composition with actinic radiation.

  提供了一种油墨组合物，其中包括 (A) 除氧化钛以外的颜料，(B) 阳离子可聚合化合物，和 (C) 光酸发生器，颜料 (A) 的含量为 3.5至20重量％，阳离子可聚合化合物(B)仅含有环氧乙烷化合物和/或氧杂环丁烷化合物，环氧乙烷化合物和/或氧杂环丁烷化合物含有低粘度化合物，其在25°C时的粘度不大于12 mPa-s，相对于阳离子可聚合化合物(B)的总重量，低粘度化合物的总含量为65至100重量％。还提供了一种油墨组合物，其中包括 (A')氧化钛、(B) 可阳离子聚合的化合物和 (C) 光酸发生器，氧化钛 (A') 的含量为 35 至 45 wt %，可阳离子聚合的化合物 (B) 含有环氧乙烷化合物、氧杂环丁烷化合物或乙烯基醚化合物，其含量为 35 至 45 wt %、或乙烯基醚化合物，其在 25°C 时的粘度不大于 12 mPa-s，且环氧乙烷化合物、氧杂环丁烷化合物和乙烯基醚化合物在 25°C 时的粘度不大于 12 mPa-s，其总含量相对于阳离子可聚合化合物 (B) 的总重量为 65 至 100 wt %。还提供了一种喷墨记录方法，包括(a1)将上述墨水组合物排放到记录介质上的步骤和(b1)通过用阳极辐射照射排放的墨水组合物来固化墨水组合物的步骤。
• INK COMPOSITION AND INKJET RECORDING METHOD
  申请人：ARAKI Kenjiro

  公开号：US20100080925A1

  公开（公告）日：2010-04-01

  An ink composition is provided that includes (A) a pigment other than titanium oxide, (B) a cationically polymerizable compound, and (C) a photo-acid generator, the pigment (A) having a content of 3.5 to 20 wt %, the cationically polymerizable compound (B) containing only an oxirane compound and/or an oxetane compound, the oxirane compound and/or the oxetane compound containing a low-viscosity compound having a viscosity at 25° C. of no greater than 12 mPa·s, and the low-viscosity compound having a total content of 65 to 100 wt % relative to the total weight of the cationically polymerizable compound (B). There is also provided an inkjet recording method that includes (a 1 ) a step of discharging the ink composition above onto a recording medium and (b 1 ) a step of curing the ink composition by irradiating the discharged ink composition with actinic radiation.
• US7900558B2
  申请人：——

  公开号：US7900558B2

  公开（公告）日：2011-03-08

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