6-甲氧基-1,2,3,4-四庚基萘 | 1003853-54-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 6-甲氧基-1,2,3,4-四庚基萘
• 英文名称: 6-methoxy-1,2,3,4-tetraheptylnaphthalene
• 英文别名: 1,2,3,4-Tetraheptyl-6-methoxynaphthalene
• CAS: 1003853-54-0
• 化学式: C₃₉H₆₆O
• 分子量: 550.952
• InChiKey: TXJNZBUBMLHOBP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.2
• 重原子数：
  40
• 可旋转键数：
  25
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.74
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  8-十六炔 、 4,4’,4’-三甲氧基苯基甲醇 在 dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer copper diacetate 作用下， 以 邻二甲苯 为溶剂， 以47%的产率得到6-甲氧基-1,2,3,4-四庚基萘
  参考文献：
  名称：

  Rhodium-Catalyzed Oxidative Coupling of Triarylmethanols with Internal Alkynes via Successive C−H and C−C Bond Cleavages

  摘要：

  [GRAPHICS]The rhodium-catalyzed oxidative coupling of triarylmethanols with internal alkynes effectively proceeds in a 1:2 manner via cleavage of C-H and C-C bonds to produce the corresponding naphthalene derivatives. Addition of trior tetraphenylcyclopentadiene as a ligand is crucial for the reaction to occur efficiently.

  DOI：

  10.1021/jo7022087

文献信息

• Rhodium-Catalyzed Oxidative Coupling of Triarylmethanols with Internal Alkynes via Successive C−H and C−C Bond Cleavages
  作者：Toshihiko Uto、Masaki Shimizu、Kenji Ueura、Hayato Tsurugi、Tetsuya Satoh、Masahiro Miura

  DOI：10.1021/jo7022087

  日期：2008.1.1

  [GRAPHICS]The rhodium-catalyzed oxidative coupling of triarylmethanols with internal alkynes effectively proceeds in a 1:2 manner via cleavage of C-H and C-C bonds to produce the corresponding naphthalene derivatives. Addition of trior tetraphenylcyclopentadiene as a ligand is crucial for the reaction to occur efficiently.