tetradodecylthiuram disulfide | 31382-10-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tetradodecylthiuram disulfide
• 英文别名: didodecylcarbamothioylsulfanyl N,N-didodecylcarbamodithioate
• CAS: 31382-10-2
• 化学式: C₅₀H₁₀₀N₂S₄
• 分子量: 857.621
• InChiKey: CVMRCQCMDBHELO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  24
• 重原子数：
  56
• 可旋转键数：
  47
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.96
• 拓扑面积：
  121
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  双十二烷基胺 在 碘 、 sodium hydroxide 作用下， 以 水 、 甲苯 为溶剂， 生成 tetradodecylthiuram disulfide
  参考文献：
  名称：

  A composition of organic hetero compounds as an antioxidant and antiwear additive for mineral lubricating oils

  摘要：

  As a multifunctional additive exhibiting antioxidant and antiwear activity for mineral lubricating oil, a composition of ammonium dialkyldithiophosphate (ADTP) with tetraalkyl thiuram disulfide (TDS) has been proposed, which provides lower sulfated ash, phosphorus, and sulfur contents compared with the traditional additive zinc dialkyldithiophosphate used for the same functions. Ammonium dialkyldithiophosphates bearing various alkyl radicals have been synthesized using structurally different amines. The antioxidant efficiency of ADTP samples has been shown by monitoring the formation and degradation of hydroperoxides in a hexadecane medium as a model of mineral oil. The tribological parameters of these compounds have been determined under boundary lubrication conditions.

  DOI：

  10.1134/s0965544113040142

文献信息

• Thermoplastic elastomer
  申请人：SHOWA DENKO KABUSHIKI KAISHA

  公开号：EP0376213A2

  公开（公告）日：1990-07-04

  A thermoplastic elastomer with well-balanced physical properties is prepared by treating a rubber/resin composition comprised of (a) 45 - 90 wt. parts of a rubbery component and (b) l0 - 55 wt. parts of a polyolefin resin, with a curing agent. The rubbery component (a) is comprised of 5 - l00 wt.% of an ethylene-propylene copolymer rubber having an ethylene content of 60 - 78 mole%, a crystallinity of 4 to 20%, a maximum peak temperature of melting of at least l00°C, an MFI of less than 0.01 at 230°C, an HLMFI/MFI of at least 35, an Mw/Mn of at least 4, and a tensile strength at break of at least l00 kg/cm², and 95 - 0% by weight of an ethylene-propylene-nonconjugated diene copolymer. The rubbery component in the cured product has a gel content more than 80 wt.% and less than 97 wt.% as determined by immersion in cyclohexane at 23°C for 48 hours.

  通过用固化剂处理由(a) 45 - 90 重量份的橡胶成分和(b) l0 - 55 重量份的聚烯烃树脂组成的橡胶/树脂组合物，制备具有良好平衡物理性能的热塑性弹性体。橡胶组分 (a) 由 5 - l00 重量份的乙烯-丙烯共聚橡胶组成，乙烯含量为 60 - 78 摩尔%，结晶度为 4 - 20%，熔融最高温度至少为 l00°C，在 230°C 时 MFI 小于 0.01，HLMFI/MFI 至少为 35，Mw/Mn 至少为 4，断裂拉伸强度至少为 l00 kg/cm²，乙烯-丙烯-非共轭二烯共聚物的重量百分比为 95 - 0%。根据在 23°C 环己烷中浸泡 48 小时的测定，固化产品中橡胶成分的凝胶含量大于 80%，小于 97%。
• Acrylic rubber composition
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0811659A2

  公开（公告）日：1997-12-10

  A crosslinkable acrylic rubber composition exhibiting superior balance between the storage stability and cure rate, and having only minimal risk of corroding metals or being contaminated by metals. The cured products made from the composition have excellent tensile strength, permanent compression set, and water resistance. The composition which comprises (1) a halogen-containing acrylic rubber, (2) a triazine thiol compound, (3) a dithiocarbamine acid derivative or a thiuram sulfide compound, or both, (4) a hydrotalcite compound or an organotin compound, or both, (5) an aromatic carboxylic acid compound or an acid anhydride thereof, or both, (6) a white filler with a pH of 2-10, and (7) a silane coupling agent.

  一种可交联丙烯酸橡胶组合物，在贮存稳定性和固化速度之间表现出极佳的平衡，而且腐蚀金属或被金属污染的风险极低。由该组合物制成的固化产品具有优异的拉伸强度、永久压缩永久变形和防水性能。该组合物包括：(1) 含卤素丙烯酸橡胶；(2) 三嗪硫醇化合物；(3) 二硫代氨基甲酸衍生物或硫化秋兰姆化合物，或两者兼有；(4) 滑石粉化合物或有机锡化合物，或两者兼有；(5) 芳香族羧酸化合物或其酸酐，或两者兼有；(6) pH 值为 2-10 的白色填料；以及 (7) 硅烷偶联剂。
• RUBBER COMPOSITION AND TIRE USING THE SAME
  申请人：Bridgestone Corporation

  公开号：EP2103650A1

  公开（公告）日：2009-09-23

  This invention relates to a rubber composition capable of using in a tread rubber of a tire to improve both an initial gripping performance and a running stability of the tire as compared with those of conventional tires, and more particularly to a rubber composition formed by compounding an indene-containing C9-based resin having a softening point of 130°C-190°C and an indene content of 30-80 mass% into a rubber component.

  本发明涉及一种橡胶组合物，可用于轮胎的胎面橡胶，与传统轮胎相比，可提高轮胎的初始抓地性能和行驶稳定性，特别是涉及一种橡胶组合物，该橡胶组合物是将软化点为 130°C-190°C、茚含量为 30-80 质量%的含茚 C9 树脂与橡胶成分复合而成。
• RUBBER COMPOSITION AND PNEUMATIC TIRE
  申请人：Bridgestone Corporation

  公开号：EP2423253A1

  公开（公告）日：2012-02-29

  Provided are a rubber composition including: a rubber component formed of a diene-based rubber; and a filler, in which when an actual density determined by JIS K6268 method A is represented by dc, and a density and a mass fraction of a component i determined by constituent analysis are represented by di and φ i, respectively, dc·Σ(φi/di)≤0.980 satisfies a specific relationship, and hence the rubber composition reduces the weight of a tire without reducing the durability of the tire such as abrasion resistance and achieves a high level of balance between the weight reduction and a reduction in the rolling resistance of the tire, and a pneumatic tire using the composition.

  本发明提供了一种橡胶组合物，包括：由二烯基橡胶形成的橡胶成分；以及填料，其中当通过 JIS K6268 方法 A 确定的实际密度用 dc 表示，而通过成分分析确定的成分 i 的密度和质量分数分别用 di 和 φ i 表示时，dc-Σ(φi/di)≤0.980 满足特定关系，因此该橡胶组合物可在不降低轮胎耐磨性等耐用性的情况下减轻轮胎重量，并在减轻重量和降低轮胎滚动阻力之间实现高度平衡，使用该组合物的充气轮胎也是如此。
• METHOD FOR MANUFACTURING RUBBER COMPOSITION
  申请人：Bridgestone Corporation

  公开号：EP2623547A1

  公开（公告）日：2013-08-07

  The present invention provides a method for producing a rubber composition containing a rubber component (A) of at least one selected from natural rubbers and synthetic dienic rubbers, an inorganic filler (B), a silane coupling agent (C) and an acidic compound (D), wherein the rubber composition is kneaded in multiple stages, and in the final stage of kneading, the acidic compound (D) is added, and the highest temperature of the rubber composition in the final stage of kneading is from 60 to 120°C. The production method enables production of a rubber composition having a low-heat-generation property while successfully preventing the coupling function activity of the silane coupling agent from lowering.

  本发明提供了一种橡胶组合物的生产方法，该橡胶组合物含有至少一种选自天然橡胶和合成二元橡胶的橡胶组分（A）、无机填料（B）、硅烷偶联剂（C）和酸性化合物（D），其中橡胶组合物经过多阶段捏合，在捏合的最后阶段加入酸性化合物（D），在捏合的最后阶段橡胶组合物的最高温度为 60 至 120°C。该生产方法既能生产出具有低发热特性的橡胶组合物，又能成功防止硅烷偶联剂的偶联功能活性降低。