N,N'-m-phenylenebisphthalimide | 19065-88-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: N,N'-m-phenylenebisphthalimide
• 英文别名: 1,3-Diphthalimidobenzol；m-Diphthalimidobenzol；N,N'-m-Phenylen-bis-phthalimid；1H-Isoindole-1,3(2H)-dione, 2,2'-(1,3-phenylene)bis-；2-[3-(1,3-dioxoisoindol-2-yl)phenyl]isoindole-1,3-dione
• CAS: 19065-88-4
• 化学式: C₂₂H₁₂N₂O₄
• 分子量: 368.348
• InChiKey: APQBHDJUOUDRGR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  28
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  苯酐 、 2,4,6-tris-phenylazo-m-phenylenediamine 生成 N,N'-m-phenylenebisphthalimide
  参考文献：
  名称：

  Crippa; Galimberti, Gazzetta Chimica Italiana, 1929, vol. 59, p. 828

  摘要：

  DOI：

文献信息

• Composition and associated method
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP1783147A1

  公开（公告）日：2007-05-09

  Provided is a fluorine substituted oligomeric or polymeric ester including the reaction product of a fluorine substituted acrylate or a fluorine substituted methacrylate; an unsaturated anhydride; and an alkyl acrylate or an alkyl methacrylate. Also provided is a method of making the composition.

  本发明提供了一种氟取代低聚物或聚合物酯，包括氟取代丙烯酸酯或氟取代甲基丙烯酸酯、不饱和酸酐和丙烯酸烷基酯或甲基丙烯酸烷基酯的反应产物。此外，还提供了一种制造该组合物的方法。
• Polyetherimides, methods of manufacture, and articles formed therefrom
  申请人：SABIC Innovative Plastics IP B.V.

  公开号：EP2644640A1

  公开（公告）日：2013-10-02

  Polyetherimide compositions are described wherein the polyetherimide composition comprises a polyetherimide comprising a reacted combination of alkali metal salts comprising an alkali metal salt of a dihydroxy aromatic compound and an alkali metal salt of a monohydroxy aromatic compound with a bis(halophthalimide), wherein the alkali metal salt of the monohydroxy aromatic compound is included in an amount of greater or equal to 5 mole percent based on the total moles of the alkali metal salts, and the polyetherimide has a weight average molecular weight less thaw 43,000 Daltons and a melt flow index of greater than 22 g/10 min when determined according to ASTM D1238, at 337°C/6.6 kg. The polyetherimide exhibits lower levels of chlorine and chlorine end groups, lower levels of bis(halophthalimide) and bis(phthalimide), and low plate-out during manufacturing.

  描述了聚醚酰亚胺组合物，其中聚醚酰亚胺组合物包含一种聚醚酰亚胺，该聚醚酰亚胺包含碱金属盐的反应组合，该碱金属盐包含二羟基芳香族化合物的碱金属盐和单羟基芳香族化合物的碱金属盐与双(卤代邻苯二甲酰亚胺)的反应组合、其中单羟基芳香族化合物的碱金属盐的含量大于或等于碱金属盐总摩尔数的 5 摩尔%，且聚醚酰亚胺的重量平均分子量小于 43,000 道尔顿，根据 ASTM D1238 测定，在 337℃/6，熔体流动指数大于 22 克/10 分钟。6 千克。聚醚酰亚胺的氯和氯端基含量较低，双（卤代邻苯二甲酰亚胺）和双（邻苯二甲酰亚胺）含量较低，生产过程中的脱板率较低。
• Polyetherimide miscible polymer blends for capacitor films
  申请人：SABIC GLOBAL TECHNOLOGIES, B.V.

  公开号：US10147541B2

  公开（公告）日：2018-12-04

  A uniaxially-stretched, high yield extruded capacitor film comprising a miscible polymer blend comprising a polyetherimide and a poly(carbonate-arylate ester), wherein the polyetherimide comprises units derived from polymerization of an aromatic dianhydride with a diamine comprising a m-phenylenediamine, a p-phenylenediamine, or combinations thereof, wherein the polyetherimide is endcapped with a substituted or unsubstituted aromatic primary monoamine, wherein the poly(carbonate-arylate ester) comprises repeating bisphenol carbonate units and repeating arylate ester units, wherein the repeating bisphenol carbonate units and the repeating arylate ester units are different from each other, and wherein the high yield extruded capacitor film comprises equal to or greater than about 90 wt. % of the miscible polymer blend entering an extruder used for manufacturing the capacitor film, based on the total weight of miscible polymer blend prior to entering the extruder.

  一种单轴拉伸的高产率挤出电容器薄膜，包括一种由聚醚酰亚胺和聚(碳酸酯-芳酸 酯)组成的混溶聚合物混合物，其中聚醚酰亚胺包括由芳香族二酐与二胺聚合而得的单 位，二胺包括间苯二胺、对苯二胺或它们的组合、其中聚醚酰亚胺用取代或未取代的芳香族伯胺单体封端，其中聚(碳酸酯-芳酸酯)包括重复的双酚碳酸酯单元和重复的芳酸酯单元，其中重复的双酚碳酸酯单元和重复的芳酸酯单元彼此不同，以及其中高产率挤出电容器薄膜包括等于或大于约 90 wt.%的混溶聚合物混合物进入用于制造电容器薄膜的挤出机，以进入挤出机前的混溶聚合物混合物总重量为基础。
• Thermoplastic polyimides, method for the manufacture thereof, and articles prepared therefrom
  申请人：SABIC Global Technologies B.V.

  公开号：US10640613B2

  公开（公告）日：2020-05-05

  A polymer composition including a polyetherimide comprising repeating units of formula (1) and formula (2) [Formula should be inserted here] wherein the repeating units of formula (1) are present in an amount of at least 10 mole %, preferably 20 to 100 mole %, Z is independently at each occurrence derived from a biphenol; Z′ is independently at each occurrence a group of formulas (3) to (13) as defined herein, preferably bisphenol A, 1,2-dihydroxybenzene, 1,1-bis(4-hydroxyphenyl)-1-phenyl-ethane, isophorone bisphenol (1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane), spirobiindane bisphenol, dimethylindanone bisphenol, 3,3′-dimethylbisphenol cyclohexane, or fluorenone bisphenol; and R is independently at each occurrence as a C6-20 aromatic hydrocarbon group or a halogenated derivative thereof, a straight or branched chain C2-20 alkylene group or a halogenated derivative thereof, a C3-8 cycloalkylene group or halogenated derivative thereof; wherein the polyetherimide has a Tg of greater than 200° C.

  一种聚合物组合物，包括由式(1)和式(2)[此处应插入式]重复单元组成的聚醚酰亚胺，其中式(1)重复单元的含量至少为10摩尔％，优选20至100摩尔％，Z在每次出现时均独立地衍生自双酚；Z′ 在每次出现时均独立地为本文定义的式 (3) 至 (13) 组，优选双酚 A、1,2-二羟基苯、1,1-双（4-羟基苯基）-1-苯基乙烷、异佛尔酮双酚（1,1-双（4-羟基苯基）-3,3,5-三甲基环己烷）、螺双茚酮双酚、二甲基茚酮双酚、3,3′-二甲基双酚环己烷或芴酮双酚；R独立地在每次出现时为C6-20芳烃基团或其卤代衍生物、直链或支链C2-20亚烷基或其卤代衍生物、C3-8环亚烷基或其卤代衍生物；其中聚醚酰亚胺的Tg大于200℃。
• Electron-acceptor properties of N, N?-arylenebisphthalimides
  作者：D. V. Pebalk、B. V. Kotov、A. N. Pravednikov

  DOI：10.1007/bf00957932

  日期：1983.2