4-cyano-4-[N-tert-butyl-N-(1-diethoxyphosphoryl-2,2-dimethylpropyl)aminoxy]pentanoic acid | 1034133-00-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机膦酸及其衍生物
• 英文名称: 4-cyano-4-[N-tert-butyl-N-(1-diethoxyphosphoryl-2,2-dimethylpropyl)aminoxy]pentanoic acid
• 英文别名: 4-[Tert-butyl-(1-diethoxyphosphoryl-2,2-dimethylpropyl)amino]oxy-4-cyanopentanoic acid；4-[tert-butyl-(1-diethoxyphosphoryl-2,2-dimethylpropyl)amino]oxy-4-cyanopentanoic acid
• CAS: 1034133-00-0
• 化学式: C₁₉H₃₇N₂O₆P
• 分子量: 420.486
• InChiKey: UZIGFVRQEXSTDJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  28
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  109
• 氢给体数：
  1
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  4,4'-偶氮双(4-氰基戊酸) 、 N-(2-methyl-2-propyl)-N-(1-diethylphosphono-2,2-dimethylpropyl)aminoxyl 以 乙醇 、 水 为溶剂， 反应 4.0h， 以70%的产率得到4-cyano-4-[N-tert-butyl-N-(1-diethoxyphosphoryl-2,2-dimethylpropyl)aminoxy]pentanoic acid
  参考文献：
  名称：

  Synthesis of Highly Labile SG1-Based Alkoxyamines under Photochemical Conditions

  摘要：

  Highly labile SG1-based alkoxyamines were synthesized using the photodecomposition of both azo compounds and dithiocarbamates. The former method was a straightforward procedure to obtain the alkoxyamines, but a high [azo]/[nitroxide] ratio is needed. The latter method required only a stoichiometric amount of dithiocarbamate and allowed the recovery of the disulfide after irradiation. This enabled combination of the two methods in a process where only 0.75 equiv of azo compound is needed and where sulfurous compounds acted only as intermediates.

  DOI：

  10.1021/jo800422a

文献信息

• METHOD FOR PRODUCING POLYMER NANOCOMPOSITE, AND FLAME-RETARDANT POLYMER NANOCOMPOSITE FORMED BY THE PRODUCTION METHOD
  申请人：Takahara Atsushi

  公开号：US20110213111A1

  公开（公告）日：2011-09-01

  A method for producing a polymer nanocomposite, includes: after expanding an interlayer space of a layered inorganic compound using an organic onium salt, immobilizing a radical polymerization initiator having a group represented by formula (1) on an interlayer surface of the layered inorganic compound via a covalent bond; and carrying out surface-initiated radical polymerization in a monomer from the immobilized radical polymerization initiator. Preferably, in the radical polymerization initiator having the group represented by the general formula (1), at least one of X1 to X3 in the formula is a chlorine atom, or R1 in the formula is a C1-25 alkylene group or a C2-25 alkenylene group optionally interrupted by an oxygen atom or an ester group and optionally substituted by a phenyl group: R1 represents a C1-25 alkylene group, a C2-25 alkenylene group, a C5-8 cycloalkylene group, or a C6-12 arylene group.
• US8742044B2
  申请人：——

  公开号：US8742044B2

  公开（公告）日：2014-06-03