1,2,3,4-tetrabromonaphthalene | 31400-66-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,2,3,4-tetrabromonaphthalene
• 英文别名: 1,2,3,4-Tetrabrom-naphthalin
• CAS: 31400-66-5
• 化学式: C₁₀H₄Br₄
• 分子量: 443.758
• InChiKey: VZQGIXBRWYLDST-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  在 氢溴酸 、 溶剂黄146 作用下， 生成 1,2,3,4-tetrabromonaphthalene
  参考文献：
  名称：

  芳烃化学。第二十八部分。由四卤代邻氨基苯甲酸产生的四卤代联苯胺的一些其他环加成反应

  摘要：

  可以从相应的四卤代邻氨基苯甲酸高效地生成四溴和四碘联苯胺，并在与芳族底物的溶液中进行环加成反应。竞争数据已与四氯和四氟苯并ne的竞争数据进行了比较。在亚硝酸3-甲基丁基酯的存在下，某些取代的四溴苯并-barrelenes被转化为萘衍生物。

  DOI：

  10.1039/j39710000567

文献信息

• Access to polysubstituted naphthalenes and anthracenes via a retro-Diels–Alder reaction
  作者：Esra Turan Akin、Musa Erdogan、Arif Dastan、Nurullah Saracoglu

  DOI：10.1016/j.tet.2017.07.058

  日期：2017.9

  Naphthalene and anthracene nuclei are present in several natural and synthetic compounds. Due to their unique physical and chemical properties, access to functionalized naphthalenes and anthracenes has attracted the attention of both synthetic and medicinal chemists over the decades. In this study, successive Diels–Alder/retro-Diels–Alder reactions of dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate with

  萘和蒽核存在于几种天然和合成化合物中。由于其独特的物理和化学性质，几十年来，获得官能化的萘和蒽已引起合成化学和药物化学家的关注。在这项研究中，报道了在一个罐中1,2,4,5-四嗪-3,6-二羧酸二甲酯与各种双环烯烃的连续狄尔斯-阿尔德/逆狄尔斯-阿尔德反应，生成萘和蒽衍生物。使用抗与顺式为烯烃伙伴启用的三萘有效地合成从benzobarrelene的环三聚衍生-cyclotrimers。
• [EN] QUANTITATIVE INTRAMOLECULAR FISSION IN OLIGOACENES, MATERIALS, AND METHODS OF USE THEREOF<br/>[FR] FRAGMENTATION INTRAMOLÉCULAIRE QUANTITATIVE DANS DES OLIGOACÈNES, MATÉRIAUX, ET LEURS PROCÉDÉS D'UTILISATION
  申请人：UNIV COLUMBIA

  公开号：WO2016100754A1

  公开（公告）日：2016-06-23

  The present invention provides soluble, stable singlet fission (SF) compounds, compositions, materials, methods of their use, and methods for their preparation that provide efficient intramolecular singlet fission (iSF) and multiple excitons. The SF compound may be a dimer, an oligomer, or a polymer of polyoligoacenes, where for example, the compound achieves a triplet yield reaching about 200% per absorbed photon. In this system, SF does not depend on intermolecular inter-actions. Instead, SF is an intrinsic property of the molecule and therefore occurs independent of intermolecular interactions. Singlet fission has the potential to significantly improve the photocurrent in single junction solar cells and thus raise the Shockley-Queisser power conversion efficiency limit from about 33% to about 46% or greater. Quantitative SF yield at room temperature has only been observed in crystalline solids or aggregates of higher acenes.

  本发明提供可溶性、稳定的单重子裂变（SF）化合物、组合物、材料、其使用方法以及制备方法，其提供高效的分子内单重子裂变（iSF）和多重激子。SF化合物可以是多聚体、寡聚体或聚合物的聚合物，例如，该化合物可实现每吸收光子的三重态产率达到约200%。在这个系统中，SF不依赖于分子间相互作用。相反，SF是分子的固有性质，因此独立于分子间相互作用而发生。单重子裂变有潜力显着提高单结太阳能电池的光电流，并将从约33%提高到约46%或更高的肖克利-克瓦塞尔功率转换效率极限。在室温下只有在晶体固体或更高的芳香烃聚集体中观察到定量的SF产率。
• Quantitative intramolecular fission in oligoacenes, materials, and methods of use thereof
  申请人：THE TRUSTEES OF COLUMBIA UNIVERSITY IN THE CITY OF NEW YORK

  公开号：US10752730B2

  公开（公告）日：2020-08-25

  The present invention provides soluble, stable singlet fission (SF) compounds, compositions, materials, methods of their use, and methods for their preparation that provide efficient intramolecular singlet fission (iSF) and multiple excitons. The SF compound may be a dimer, an oligomer, or a polymer of polyoligoacenes, where for example, the compound achieves a triplet yield reaching about 200% per absorbed photon. In this system, SF does not depend on intermolecular inter-actions. Instead, SF is an intrinsic property of the molecule and therefore occurs independent of intermolecular interactions. Singlet fission has the potential to significantly improve the photocurrent in single junction solar cells and thus raise the Shockley-Queisser power conversion efficiency limit from about 33% to about 46% or greater. Quantitative SF yield at room temperature has only been observed in crystalline solids or aggregates of higher acenes.

  本发明提供了可溶性、稳定的单子裂变（SF）化合物、组合物、材料、使用方法及其制备方法，这些化合物、组合物、材料、使用方法及其制备方法可提供高效的分子内单子裂变（iSF）和多重激子。SF 化合物可以是二聚体、低聚物或多元二十八烯的聚合物，例如，该化合物每吸收一个光子的三重子产率可达到约 200%。在这种体系中，SF 并不依赖于分子间的相互作用。相反，SF 是分子的固有特性，因此其发生与分子间的相互作用无关。单裂变有可能显著提高单结太阳能电池的光电流，从而将肖克利-奎塞尔功率转换效率极限从约 33% 提高到约 46% 或更高。室温下的定量 SF 产率只在高碳烯的结晶固体或聚合体中观察到过。
• 11. Reactions of 3-nitro-1-naphthylamine, including anil formation, bromination, and the preparation of 1 : 2 : 3 : 4-tetrabromonaphthalene
  作者：Herbert H. Hodgson、David E. Hathway

  DOI：10.1039/jr9440000021

  日期：——
• METHOD OF CALIBRATING MASS-TO-CHARGE RATIO MEASUREMENTS OBTAINED FROM A MASS SPECTROMETER CONNECTED IN FLUID COMMUNICATION WITH AN ANALYSIS SYSTEM DELIVERING A TEMPORALLY CHANGING SAMPLE
  申请人：TOFWERK AG

  公开号：US20160211125A1

  公开（公告）日：2016-07-21

  A method of calibrating mass-to-charge ratio measurements obtained from a mass spectrometer connected in fluid communication with a chromatographic system comprises the steps of acquiring a multiplicity of mass spectra of an analyte during an analytical run, analyzing at least some of the multiplicity of mass spectra during the analytical run for generating result data relating to a decision on introduction of a calibrant material into the mass spectrometer; and introducing the calibrant material into the mass spectrometer during the analytical run, based on the result data. An arrangement for mass analysis that is suitable for carrying out the method comprises a chromatographic system ( 10 ), a mass spectrometer ( 20 ) connected downstream, in fluid communication to the chromatographic system ( 10 ), a data acquisition device ( 22 ) for acquiring mass spectra of an analyte fed to the mass spectrometer ( 20 ), a controllable injector ( 30, 31 ) to introduce calibrant material into the mass spectrometer, and a control unit ( 50 ) receiving information on the acquired mass spectra from the data acquisition device ( 22 ), the control unit ( 50 ) configured to dynamically control the injector ( 30, 31 ) based on the received information.