2-(7-(4-nitrophenylethynyl)-9,9-dihexadecyl-fluoren-2-yl)-1,10-phenanthroline | 1380049-28-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 2-(7-(4-nitrophenylethynyl)-9,9-dihexadecyl-fluoren-2-yl)-1,10-phenanthroline
• 英文别名: 2-[9,9-Dihexadecyl-7-[2-(4-nitrophenyl)ethynyl]fluoren-2-yl]-1,10-phenanthroline；2-[9,9-dihexadecyl-7-[2-(4-nitrophenyl)ethynyl]fluoren-2-yl]-1,10-phenanthroline
• CAS: 1380049-28-4
• 化学式: C₆₅H₈₃N₃O₂
• 分子量: 938.393
• InChiKey: LHFCDJZSNPKTQF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  24.7
• 重原子数：
  70
• 可旋转键数：
  33
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.51
• 拓扑面积：
  71.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  potassium tetrachloroplatinate(II) 、 2-(7-(4-nitrophenylethynyl)-9,9-dihexadecyl-fluoren-2-yl)-1,10-phenanthroline 以 氯仿 、 溶剂黄146 为溶剂， 以44%的产率得到(2-(7-(4-notrephenylethynyl)-9,9-dihexadecyl-fluoren-2-yl)-1,10-phenanthroline)chloridoplatimun(II)
  参考文献：
  名称：

  Synthesis and photophysics of platinum(II) complexes bearing 2-(7-(4-R-phenylethynyl)-9,9-dihexadecyl-fluoren-2-yl)-1,10-phenanthroline ligand

  摘要：

  A series of platinum(II) complexes bearing 2-(7-(4-R-phenylethynyl)-9,9-dihexadecyl-fluoren-2-yl)-1,10-phenanthroline ligand were synthesized and characterized. Their photophysical properties were systematically investigated by UV-Vis absorption, emission, and transient absorption spectroscopy. All complexes exhibit (1)pi,pi* absorption bands below 410 nm and charge transfer transitions at 415-550 nm in CH2Cl2. They all emit at ca. 624 nm with vibronic structures. Both UV-Vis absorption and emission spectra show negative solvatochromic effect. All complexes exhibit broad and moderately strong triplet transient absorption from the near-UV to the near-IR spectral region. Reverse saturable absorption of these complexes in CH2Cl2 for ns laser pulses at 532 nm was demonstrated. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.03.033
• 作为产物：
  描述：

  2-碘芴 在 aluminum (III) chloride 、 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 四丁基碘化铵 、 三乙胺 、 三苯基膦 、 potassium hydroxide 、 sodium hydroxide 作用下， 以 乙醇 、 二氯甲烷 、 水 、 二甲基亚砜 为溶剂， 反应 60.0h， 生成 2-(7-(4-nitrophenylethynyl)-9,9-dihexadecyl-fluoren-2-yl)-1,10-phenanthroline
  参考文献：
  名称：

  Synthesis and photophysics of platinum(II) complexes bearing 2-(7-(4-R-phenylethynyl)-9,9-dihexadecyl-fluoren-2-yl)-1,10-phenanthroline ligand

  摘要：

  A series of platinum(II) complexes bearing 2-(7-(4-R-phenylethynyl)-9,9-dihexadecyl-fluoren-2-yl)-1,10-phenanthroline ligand were synthesized and characterized. Their photophysical properties were systematically investigated by UV-Vis absorption, emission, and transient absorption spectroscopy. All complexes exhibit (1)pi,pi* absorption bands below 410 nm and charge transfer transitions at 415-550 nm in CH2Cl2. They all emit at ca. 624 nm with vibronic structures. Both UV-Vis absorption and emission spectra show negative solvatochromic effect. All complexes exhibit broad and moderately strong triplet transient absorption from the near-UV to the near-IR spectral region. Reverse saturable absorption of these complexes in CH2Cl2 for ns laser pulses at 532 nm was demonstrated. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.03.033

文献信息

• Synthesis and photophysics of platinum(II) complexes bearing 2-(7-(4-R-phenylethynyl)-9,9-dihexadecyl-fluoren-2-yl)-1,10-phenanthroline ligand
  作者：Xu-Guang Liu、Wenfang Sun

  DOI：10.1016/j.ica.2012.03.033

  日期：2012.6

  A series of platinum(II) complexes bearing 2-(7-(4-R-phenylethynyl)-9,9-dihexadecyl-fluoren-2-yl)-1,10-phenanthroline ligand were synthesized and characterized. Their photophysical properties were systematically investigated by UV-Vis absorption, emission, and transient absorption spectroscopy. All complexes exhibit (1)pi,pi* absorption bands below 410 nm and charge transfer transitions at 415-550 nm in CH2Cl2. They all emit at ca. 624 nm with vibronic structures. Both UV-Vis absorption and emission spectra show negative solvatochromic effect. All complexes exhibit broad and moderately strong triplet transient absorption from the near-UV to the near-IR spectral region. Reverse saturable absorption of these complexes in CH2Cl2 for ns laser pulses at 532 nm was demonstrated. (C) 2012 Elsevier B. V. All rights reserved.