1,6,9,14-tetraazatetradecane | 70862-14-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,6,9,14-tetraazatetradecane
• 英文别名: spermine；N~1~,N~1'~-(Ethane-1,2-diyl)di(butane-1,4-diamine)；N'-[2-(4-aminobutylamino)ethyl]butane-1,4-diamine
• CAS: 70862-14-5
• 化学式: C₁₀H₂₆N₄
• 分子量: 202.343
• InChiKey: UNTMDEHZQNHMOF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.1
• 重原子数：
  14
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  76.1
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,6,9,14-tetraazatetradecane 在 盐酸 作用下， 生成 1,6,9,14-tetraazatetradecane tetrahydrochloride
  参考文献：
  名称：

  CHEMOENZYMATIC SYNTHESES OF POLYAMINES AND TETRAAZAMACROCYCLES

  摘要：

  Syntheses of different open chain polyamines starting from enzymatically prepared bis(amidoesters) are described. Some of these polyamines are also used as precursors in the syntheses of tetraazamacrocycles. This methodology cart also be applied to the synthesis of chiral compounds.

  DOI：

  10.1081/scc-120003392
• 作为产物：
  描述：

  dimethyl 4,9-dioxo-5,8-diazadodecanedioate 在 硼烷四氢呋喃络合物 、 氨 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 7.0h， 生成 1,6,9,14-tetraazatetradecane
  参考文献：
  名称：

  CHEMOENZYMATIC SYNTHESES OF POLYAMINES AND TETRAAZAMACROCYCLES

  摘要：

  Syntheses of different open chain polyamines starting from enzymatically prepared bis(amidoesters) are described. Some of these polyamines are also used as precursors in the syntheses of tetraazamacrocycles. This methodology cart also be applied to the synthesis of chiral compounds.

  DOI：

  10.1081/scc-120003392

文献信息

• BASE RESIN FOR SOLDERING FLUX, SOLDERING FLUX AND SOLDER PASTE
  申请人：Arakawa Chemical Industries, Ltd.

  公开号：EP2851396A1

  公开（公告）日：2015-03-25

  The object of the present invention is to provide a soldering-flux-oriented novel base resin that enhances the fluidity of a soldering flux and both the visco-stability and adhesion of a solder paste, while improving the color tone and anti-crack property of the flux residue. The present invention is directed to a base resin for a soldering flux, the base resin comprising a rosin (A) containing at least 15 wt% of a pimarane-type resin acid (a-1), at least 1 wt% of a labdane-type resin acid (a-2), and at least 50 wt% of an abietane-type resin acid that has no conjugated double bond (a-3).

  本发明的目的是提供一种面向焊接助焊剂的新型基础树脂，它能提高焊接助焊剂的流动性以及焊膏的粘稳定性和粘附性，同时改善助焊剂残留物的色调和抗裂性能。 本发明涉及一种用于焊接助焊剂的基础树脂，该基础树脂包括松香（A），其中含有至少 15 wt%的皮马兰型树脂酸（a-1）、至少 1 wt%的拉布丹型树脂酸（a-2）和至少 50 wt%的无共轭双键的阿比坦型树脂酸（a-3）。
• MATERIAUX HYBRIDES ORGANIQUES-INORGANIQUES, MESOPOREUX, POUR SEPARER LES GAZ
  申请人：CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS)

  公开号：EP1370563B1

  公开（公告）日：2006-09-06
• Mesoporous organic-inorganic hybrid materials for separating gases
  申请人：——

  公开号：US20040122250A1

  公开（公告）日：2004-06-24

  The invention concerns a method for preparing organic-inorganic hybrid materials with controlled porosity and functionality, comprising hydrolysis and condensation polymerisation of at least a compound of formula (I): Z—R 1 —Si(OR)(OR′)(OR″), wherein: Z represents either an atom selected among chlorine, bromine or iodine atoms, or an amino or phosphino group; R, R′ and R″, independently of one another, represent an alkyl radical comprising on to four carbon atoms; R 1 represents a divalent radical derived from an aliphatic hydrocarbon chain comprising 1 to 30 carbon atoms, wherein are optionally interspersed one or several arylene; —O—, —S—, —O—C(═O), —N(R 6 )—C(═O)— or N(R 6 ), with at least an alkaline or alkaline-earth silicate of (II) in a mol ratio (I)/(II)=1/9 in the presence of at least a non-ionic surfactant in micellar concentration, to form a mesoporous silica represented by formula (III): Z—R 1 —SiO 1,5 9 SiO 2 , whereon is then anchored an equivalent of an organic compound, represented by (&Dgr;)N—H, comprising at least a —NH— group capable of reacting with the function Z, to form a functionalised mesoporous silica represented by formula (IV): (&Dgr;)N—R—SiO 1,5 9 SiO 2 , which is optionally complexed with a metallic carbon to form an organometallic complex (V). The invention also concerns the products of formulae (IV) and (V) and their use for separating gases.
• MESOPOROUS ORGANIC-INORGANIC HYBRID MATERIALS FOR SEPARATING GASES
  申请人：Corriu Robert

  公开号：US20080152561A1

  公开（公告）日：2008-06-26

  The invention concerns a method for preparing organic-inorganic hybrid materials with controlled porosity and functionality comprising hydrolysis and condensation polymerization of a compound of formula (I): Z-R 1 —Si(OR)(OR′)(OR″), with an alkaline or alkaline-earth silicate in a mol ratio of (I)/(silicate)=1:9, in the presence of a non-ionic surfactant, to form a mesoporous silica represented by Z-R 1 —SiO 1.5 9 SiO 2 , whereon is then anchored an organic compound, represented by (Δ)N—H, comprising a —NH— group capable of reacting with Z, to form a functionalized mesoporous silica represented by (Δ)N—R—SiO 1.5 9 SiO 2 , which is optionally complexed with a metallic cation to form an organometallic complex. The invention also concerns the use of these materials to separate gases.
• US7452845B2
  申请人：——

  公开号：US7452845B2

  公开（公告）日：2008-11-18