[7-(Dimethylamino)-10,10a-dihydrophenothiazin-3-ylidene]-dimethylazanium

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻嗪类
• 英文名称: [7-(Dimethylamino)-10,10a-dihydrophenothiazin-3-ylidene]-dimethylazanium
• 化学式: C₁₆H₂₀N₃S
• 分子量: 286.421
• InChiKey: XKBFTTQXFRJRLT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  43.6
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  亚甲基蓝阳离子 在 sodium tetrahydroborate 作用下， 以 水 为溶剂， 反应 2.0h， 生成 [7-(Dimethylamino)-10,10a-dihydrophenothiazin-3-ylidene]-dimethylazanium
  参考文献：
  名称：

  新型普鲁士蓝-类似物微立方组装体及其催化还原4-硝基苯酚的催化性能

  摘要：

  普鲁士蓝及其类似物（PBA）由于其优异的物理和化学性能，已经在锂离子电池（LIB），超级电容器，催化剂和水分解等领域进行了广泛的研究。为了增强其应用，已经制造了各种基于PBA多维数据集的新颖架构。在这项工作中，首次使用Co-Fe PBA立方体作为构造块，通过自组装过程，首次溶剂热合成了长度为1-2μm的一维（Co）-Fe PBA长方体。随时间变化的扫描电子显微镜（SEM）观察表明，PBA立方体经过结构分解成较小的立方体，然后沿一定的优先方向组装成长方体。令人着迷的是，该方法可以扩展到其他PBA多维数据集。退火后 获得的Co-Fe PBA长方体产物CoFe / NC-MCBs可用作氢化催化剂，可高效还原4-硝基苯酚（4-NP）。该方法为制备具有可调化学组成的新颖长方体结构提供了巨大的机会，这将促进PBA在不同方面的进一步应用。

  DOI：

  10.1039/c8nj04958k

文献信息

• Preparation for the Photodynamic Control of Micro-Organisms and Use Thereof
  申请人：Vizethum Freimut

  公开号：US20070254349A1

  公开（公告）日：2007-11-01

  The invention relates to a preparation for the photodynamic control of micro-organisms, said preparation being in a liquid or pasty form and containing a photosensitiser which comprises a dyestuff and produces singlet oxygen when irradiated by means of light. The micro-organisms can be marked by means of the dyestuff. The aim of the invention is to improve said preparation in order to enable an improved photodynamic control. To this end, the preparation contains an active ingredient for amplifying or weakening the oxidative action of the singulet oxygen by chemical manipulation of the dyestuff or the nanoenvironment thereof. In a particular form of embodiment, a rinsing solution is used before the irradiation.
• PREPARATION FOR PHOTODYNAMIC CONTROL OF MICROORGANISMS AND USE THEREOF
  申请人：Vizethum Freimut

  公开号：US20100291654A1

  公开（公告）日：2010-11-18

  The invention relates to a preparation for the photodynamic control of micro-organisms, said preparation being in a liquid or pasty form and containing a photosensitiser which comprises a dyestuff and produces singlet oxygen when irradiated by means of light. The micro-organisms can be marked by means of the dyestuff. The aim of the invention is to improve said preparation in order to enable an improved photodynamic control. To this end, the preparation contains an active ingredient for amplifying or weakening the oxidative action of the singulet oxygen by chemical manipulation of the dyestuff or the nanoenvironment thereof. In a particular form of embodiment, a rinsing solution is used before the irradiation.
• US9034622B2
  申请人：——

  公开号：US9034622B2

  公开（公告）日：2015-05-19