adamantylammonium | 35015-52-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: adamantylammonium
• 英文别名: adamantan-1-ylamine; protonated form；1-adamantane-ammonium cation；Adamantan-1-aminium；1-adamantylazanium
• CAS: 35015-52-2
• 化学式: C₁₀H₁₈N
• 分子量: 152.26
• InChiKey: DKNWSYNQZKUICI-UHFFFAOYSA-O

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  27.6
• 氢给体数：
  1
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  adamantylammonium 、 葫芦[7]脲 以 重水 为溶剂， 生成
  参考文献：
  名称：

  Detection of Isomeric Microscopic Host–Guest Complexes. A Time-Evolving Cucurbit[7]uril Complex

  摘要：

  The formation of inclusion complexes between the cucurbit[7]uril host and a cationic guest containing ferrocenylmethyl and adamantyl residues connected to an ammonium nitrogen initially leads to an similar to 1:1 mixture of two isomeric microscopic complexes, which evolves as a function of time toward the thermodynamically stable mixture, dominated by the adamantyl-included complex.

  DOI：

  10.1021/ja404797y

文献信息

• Stimuli-responsive supramolecular dye inclusion complex constructed by self-assembly of inverted cucurbit[7]uril and thioflavin T
  作者：Hui Zhao、Wen-Jie Chen、Hao Chen、Ji-Fu Sun、Zhong-Zheng Gao

  DOI：10.1080/10610278.2022.2109471

  日期：2021.9.2

  the basis of host–guest recognition. The obtained results revealed that THT exhibited obvious iQ[7]-induced fluorescence enhancement in this inclusion complex system, and the N-dimethyl and benzene ring moiety of the guest THT were located inside the cavity of iQ[7], whereas the other section of THT remained outside the portal. And THT@iQ[7] was highly stimuli-responsive to competing guests. These results

  摘要 在主客体识别的基础上，成功构建了倒葫芦[7]脲（iQ[7]）和硫黄素T（THT）之间的新型1:1超分子染料包合物。结果表明，THT在该包合物体系中表现出明显的iQ[7]诱导的荧光增强，客体THT的N-二甲基和苯环部分位于iQ[7]的空腔内，而另一部分位于iQ[7]的空腔内。的 THT 留在门户之外。并且 THT@iQ[7] 对竞争的客人具有高度的刺激反应。这些结果为分子识别领域的应用提供了可能。
• 2-Hydroxychalcone−β-Cyclodextrin Conjugate with pH-Modulated Photoresponsive Binding Properties
  作者：Micael Paulino、Ignacio Pérez-Juste、María Magdalena Cid、José P. Da Silva、M. Manuela A. Pereira、Nuno Basílio

  DOI：10.1021/acs.joc.2c01875

  日期：2022.11.4

  Stimuli-responsive supramolecular receptors are important building blocks for the construction of self-assembled functional materials. We report the design and synthesis of a pH- and light-responsive 2-hydroxychalcone−β-cyclodextrin conjugate (1-Ct) and its characterization by spectroscopic and computational methods. 1-Ct follows the typical reaction network of trans-chalcone-flavylium photoswitches

  刺激响应超分子受体是构建自组装功能材料的重要组成部分。我们报告了 pH 和光响应性 2-羟基查尔酮-β-环糊精共轭物 ( 1-Ct ) 的设计和合成及其通过光谱和计算方法的表征。1-Ct遵循反式-查尔酮-flavylium 光开关的典型反应网络。在光照射下，1-Ct可以在中性 pH 条件下光化学转化为顺式- 查耳酮/半缩酮形式 ( 1-Cc / 1-B ) 或黄酮阳离子 ( 1-AH +) 在酸性 pH 值下。这种刺激反应性 β-环糊精宿主1-Ct被发现比1-AH +（K intra = 3）形成更强的分子内自包合物（K intra = 14 ）并且弱于1-Cc / 1-B（整体K intra = 179），允许通过 pH 和光刺激的组合来控制它们的稳定性和结合特性。