| 1404575-45-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• CAS: 1404575-45-6
• 化学式: C₇H₁₈N₂O₂
• 分子量: 162.232
• InChiKey: FFDFMUZEOTYARU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.52
• 重原子数：
  11.0
• 可旋转键数：
  4.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  46.12
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  四甲基丙二胺 在 双氧水 作用下， 以 甲醇 、 水 为溶剂， 反应 3.0h， 以80%的产率得到
  参考文献：
  名称：

  Exploring the Self-Assembly of Polar Dimeric Capsules Using Molecular Rulers

  摘要：

  A homologous series of N,N,N,N-tetramethylalkyl-N,N-dioxides is used to probe the level of guest induced fit attainable in the assembly of a dimeric capsule based on tetraurea benzyl calix[4]pyrrole components. A sensible enhancement of the capsule's volume was observed in response to guest size for n = 2, 3, and 4. In turn, larger guests adopted folded conformations to adapt to the capsule's dimensions.

  DOI：

  10.1021/ol302724e

文献信息

• Exploring the Self-Assembly of Polar Dimeric Capsules Using Molecular Rulers
  作者：Mónica Espelt、Pablo Ballester

  DOI：10.1021/ol302724e

  日期：2012.11.16

  A homologous series of N,N,N,N-tetramethylalkyl-N,N-dioxides is used to probe the level of guest induced fit attainable in the assembly of a dimeric capsule based on tetraurea benzyl calix[4]pyrrole components. A sensible enhancement of the capsule's volume was observed in response to guest size for n = 2, 3, and 4. In turn, larger guests adopted folded conformations to adapt to the capsule's dimensions.