(Z)-1,1,4,5-tetraphenylpenta-1,4-diene | 1246035-74-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: (Z)-1,1,4,5-tetraphenylpenta-1,4-diene
• 英文别名: [(1Z)-1,5,5-triphenylpenta-1,4-dien-2-yl]benzene
• CAS: 1246035-74-4
• 化学式: C₂₉H₂₄
• 分子量: 372.51
• InChiKey: PQMBSTZVHNKOLW-NFFVHWSESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.9
• 重原子数：
  29
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,1'-(1,1-丙二烯二基)二苯 、 二苯基乙炔 在 二氯二茂锆 、 乙基溴化镁 、 盐酸 、 水 作用下， 以 四氢呋喃 为溶剂， 生成 (Z)-1,1,4,5-tetraphenylpenta-1,4-diene
  参考文献：
  名称：

  Selective synthesis of α-methylenyl zirconacyclopentene via cross-coupling of alkyne and allene

  摘要：

  alpha-Methylenyl zirconacyclopentenes are synthesized regio- and stereoselectively via reductive intermolecular cross-coupling of alkynes and allenes promoted by zirconocene species 'Cp2Zr'. An interesting reductive intramolecular coupling of the alpha-methylenyl zirconacyclopentene has been observed in the presence of DMAD/CuCl, resulting in the generation of cyclobutene with an exocyclic double bond. Polysubstituted 1,4-dienes can be given with high selectivity and good yields. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.06.134

文献信息

• Selective synthesis of α-methylenyl zirconacyclopentene via cross-coupling of alkyne and allene
  作者：Weixin Zheng、Yangfeng Wu、Fenfen Zheng、Linfeng Hu、Ya Hong

  DOI：10.1016/j.tetlet.2010.06.134

  日期：2010.9

  alpha-Methylenyl zirconacyclopentenes are synthesized regio- and stereoselectively via reductive intermolecular cross-coupling of alkynes and allenes promoted by zirconocene species 'Cp2Zr'. An interesting reductive intramolecular coupling of the alpha-methylenyl zirconacyclopentene has been observed in the presence of DMAD/CuCl, resulting in the generation of cyclobutene with an exocyclic double bond. Polysubstituted 1,4-dienes can be given with high selectivity and good yields. (C) 2010 Elsevier Ltd. All rights reserved.