Hexa-2,4-diyne,1,6-bis(ethyl)(phenyl)amino- | 18158-85-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Hexa-2,4-diyne,1,6-bis(ethyl)(phenyl)amino-
• 英文别名: N,N'-diethyl-N,N'-diphenylhexa-2,4-diyne-1,6-diamine
• CAS: 18158-85-5
• 化学式: C₂₂H₂₄N₂
• 分子量: 316.446
• InChiKey: QNUSPDQIYREIJP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  24
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N-ethyl-N-(prop-2-yn-1-yl)aniline 在 吗啉 、 aluminum oxide 、 potassium fluoride 、 copper diacetate 作用下， 反应 3.0h， 以93%的产率得到Hexa-2,4-diyne,1,6-bis(ethyl)(phenyl)amino-
  参考文献：
  名称：

  Modified Glaser Reaction of Terminal Alkynes on KF/Alumina

  摘要：

  A variety of 1,3-diyne compounds are prepared in a solvent-free reaction on KF/alumina in the presence of catalytic amounts of Cu(OAc)(2)center dot H2O with up to 96% yields at room temperature.

  DOI：

  10.1007/s00706-005-0416-6

文献信息

• Polydiacetylenes exhibiting extended wavelength absorption maxima
  申请人：University of Massachusetts Lowell

  公开号：US06005058A1

  公开（公告）日：1999-12-21

  Polydiacetylenes prepared from 2,4-hexadiyne monomers substituted with at least one side chain component, exhibit an absorption maximum wavelength maximum greater than that exhibited by polydiacetylenes formed from 1,6-di-N-carbazolyl 2,4-hexadiyne. Preferably, the polydiacetylenes exhibit an absorption maximum that is in the range of visible light. Examples of suitable side chain components of the polydiacetylenes include cyanovinyl aromatic substituents and quinoid substituents. The polydiacetylenes exhibit useful third order nonlinear optical behavior for electromagnetic radiation in the visible and near-infrared electromagnetic wavelength range and can be formed by thermally-based synthesis methods.

  由至少一个侧链组分置换的2,4-己二炔单体制备的聚二炔烯，其吸收最大波长大于由1,6-二-N-咔唑基2,4-己二炔形成的聚二炔烯。最好，聚二炔烯的吸收最大值在可见光范围内。适合作为聚二炔烯的侧链组分的例子包括氰基乙烯芳香基取代物和醌基取代物。聚二炔烯对于可见光和近红外电磁波长范围的电磁辐射具有有用的三阶非线性光学行为，并且可以通过热合成方法形成。
• Zanina,A.S. et al., Journal of Organic Chemistry USSR (English Translation), 1972, vol. 8, p. 1556 - 1559
  作者：Zanina,A.S. et al.

  DOI：——

  日期：——
• Sharifi, Ali; Mirzaei, Mojtaba; Naimi-Jamal, Mohammad Reza, Journal of Chemical Research - Part S, 2002, # 12, p. 628 - 630
  作者：Sharifi, Ali、Mirzaei, Mojtaba、Naimi-Jamal, Mohammad Reza

  DOI：——

  日期：——
• US6005058A
  申请人：——

  公开号：US6005058A

  公开（公告）日：1999-12-21
• Modified Glaser Reaction of Terminal Alkynes on KF/Alumina
  作者：Ali Sharifi、Mojtaba Mirzaei、M. Reza Naimi-Jamal

  DOI：10.1007/s00706-005-0416-6

  日期：2006.2

  A variety of 1,3-diyne compounds are prepared in a solvent-free reaction on KF/alumina in the presence of catalytic amounts of Cu(OAc)(2)center dot H2O with up to 96% yields at room temperature.