2H-Isoindole, 5,6-dimethyl-

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: 2H-Isoindole, 5,6-dimethyl-
• 英文别名: 5,6-dimethyl-2H-isoindole
• 化学式: C₁₀H₁₁N
• 分子量: 145.2
• InChiKey: JBLZKAYROPQUPD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  15.8
• 氢给体数：
  1
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2H-Isoindole, 5,6-dimethyl- 、 丁炔二酸二甲酯 以18%的产率得到
  参考文献：
  名称：

  KREHER R.; HERD K. J., HETEROCYCLES, SPEC. ISSUE, 1978, 11, 409-414

  摘要：

  DOI：

文献信息

• HETEROCYCLIC HYDRAZIDE COMPOUND AND PESTICIDAL USE OF THE SAME
  申请人：Jachmann Markus

  公开号：US20100137362A1

  公开（公告）日：2010-06-03

  A hydrazide compound represented by the formula (I), an N-oxide thereof or suitable salt thereof: has excellent pesticidal activity.

  一种由式(I)表示的腙酰肼类化合物，其N-氧化物或适当的盐：具有优异的杀虫活性。
• POLYMERS HAVING ISOINDOLE STRUCTURE AND PROCESS FOR THEIR PREPARATION
  申请人：SHOWA DENKO KABUSHIKI KAISHA

  公开号：EP0248915A1

  公开（公告）日：1987-12-16

  Polymers having an isoindole structure represented by general formula (1a) and/or (1b), (wherein R1, R2 and R3 each independently represents hydrogen or a hydrocarbyl group containing 1 to 5 carbon atoms, X represents an electrolyte anion, y represents a number of 0.01 to 1 showing the proportion of the anion per mol of the monomer, and n represents a number of 5 to 500 showing the degree of polymerization) show high electroconductivity by doping, and are highly stable in an oxidized state. The polymers are obtained by (1) electrochemically polymerizing an isoindole compound of general formula (lla) or (IIb), (wherein R1, R2 and R3 are the same as defined above) in solvent in the presence of an electrolyte or (2) conducting oxidative polymerization in a solvent with the aid of an oxidant.

  具有通式(1a)和/或(1b)代表的异吲哚结构的聚合物（其中 R1、R2 和 R3 各自独立地代表氢或含有 1 至 5 个碳原子的烃基；X 代表电解质阴离子；y 代表 0.01 至 1 的数字，表示每摩尔单体中阴离子的比例；n 代表 5 至 500 的数字，表示聚合度），通过掺杂显示出高导电性，并且在氧化状态下高度稳定。这些聚合物是通过以下方法获得的：(1) 在溶剂中，在电解质的存在下，使通式 (lla) 或 (IIb) 的异吲哚化合物（其中 R1、R2 和 R3 与上述定义相同）电化学聚合；或 (2) 在溶剂中，借助氧化剂进行氧化聚合。
• METHOD FOR PRODUCING POLYISOTHIANAPHTHENE ELECTROCONDUCTIVE POLYMER
  申请人：Showa Denko K.K.

  公开号：EP3564290A1

  公开（公告）日：2019-11-06

  The present invention relates to (i) a method of producing a conductive polymer, comprising polymerizing at least one of compounds (A1) represented by the formula (1) disclosed in the specification in the presence of a compound (B) having sulfo group; (ii) a method of producing a conductive polymer, comprising polymerizing at least one compound selected from a group consisting of at least one compound (A2) represented by the formula (2); and (iii) a method of producing a conductive polymer, comprising copolymerizing at least one compound (A1) and at least one compound selected from a group consisting of at least one compound (A2). The method of the present invention is a method for producing a one-liquid type conductive polymer in which it is possible to easily adjust the solvent affinity, the solubility, and other such aspects of performance according to the purpose.

  本发明涉及(i)生产导电聚合物的方法，包括在具有磺基的化合物(B)存在下聚合至少一种由说明书中公开的式(1)代表的化合物(A1)；(iii) 一种生产导电聚合物的方法，包括将至少一种化合物(A1)和至少一种选自至少 一种化合物(A2)的化合物共聚。本发明的方法是一种生产单液型导电聚合物的方法，在这种方法中，可以根据目的轻松调整溶剂亲和性、溶解性和其他性能方面。
• METHOD FOR MANUFACTURING SOLID ELECTROLYTIC CAPACITOR
  申请人：Showa Denko K.K.

  公开号：EP3564976A1

  公开（公告）日：2019-11-06

  The present invention relates to a method of producing a solid electrolytic capacitor, comprising a step of forming a dielectric film on the surface of the valve-acting metal having fine pores and a step of forming a solid electrolyte layer containing a conductive polymer on the dielectric film; wherein the solid electrolyte layer containing the conductive polymer is formed without using an oxidizing agent by: (i) a method of polymerizing at least one of the compounds (A1) represented by the formula (1) disclosed in the description in the presence of a compound (B) having sulfo group; (ii) a method of copolymerizing at least one compound (A2) represented by the formula (2); and (iii) a method of polymerizing at least one of the compounds (A1) represented by the formula (1) and at least one of the compounds (A2) represented by the formula (2). According to the present invention, it is possible to form a solid electrolyte film containing a conductive polymer on the dielectric film on the surface of valve-acting metal having fine pores by simple steps without employing a cumbersome polymerization step, film-formation step, or a purification step; and to provide a solid electrolytic capacitor having a low ESR, a high capacity achievement rate, and excellent low leakage current characteristics.

  本发明涉及一种生产固体电解电容器的方法，包括在具有细孔的阀动金属表面上形成电介质膜的步骤和在电介质膜上形成含有导电聚合物的固体电解质层的步骤；其中，含有导电聚合物的固体电解质层是在不使用氧化剂的情况下通过以下方法形成的： (i) 在具有磺基的化合物(B)存在下聚合至少一种由描述中公开的式(1)代表的化合物 (A1)的方法； (ii) 至少一种由式(2)表示的化合物(A2)的共聚合方法；和 (iii) 至少一种由式(1)代表的化合物(A1)和至少一种由式(2)代表的化合物(A2)聚合的方法。根据本发明，可以通过简单的步骤在具有细孔的阀动金属表面的电介质膜上形成含有导电聚合物的固体电解质膜，而无需采用繁琐的聚合步骤、成膜步骤或纯化步骤；并提供具有低 ESR、高容量实现率和优异的低漏电流特性的固体电解电容器。
• Method for manufacturing solid electrolytic capacitor
  申请人：SHOWA DENKO K.K.

  公开号：US11183340B2

  公开（公告）日：2021-11-23

  A method of producing a solid electrolytic capacitor, including a step of forming a dielectric film on the surface of a valve-acting metal having fine pores and a step of forming a solid electrolyte layer containing a conductive polymer on the dielectric film; wherein the solid electrolyte layer containing the conductive polymer is formed without using an oxidizing agent by: (i) a method of polymerizing at least one of the compounds (A1) represented by formula (1) disclosed herein in the presence of a compound (B) having a sulfo group; (ii) a method of copolymerizing at least one compound (A2) represented by formula (2) disclosed herein; and (iii) a method of polymerizing at least one of the compounds (A1) and (A2).

  一种生产固体电解电容器的方法，包括在具有细孔的阀动金属表面上形成电介质膜的步骤和在电介质膜上形成含有导电聚合物的固体电解质层的步骤；其中含有导电聚合物的固体电解质层是在不使用氧化剂的情况下通过以下方法形成的：(i)在具有磺基的化合物(B)存在下聚合本文所公开的至少一种由式(1)表示的化合物(A1)的方法；(ii)共聚本文所公开的至少一种由式(2)表示的化合物(A2)的方法；以及(iii)聚合化合物(A1)和(A2)中的至少一种的方法。