1-Octylaziridine | 38914-83-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1-Octylaziridine
• CAS: 38914-83-9
• 化学式: C₁₀H₂₁N
• 分子量: 155.28
• InChiKey: ZPUJFEMAHSZIJA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  11
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• Process for the synthesis of N-substituted beta-amino nitriles through the ring opening of aziridines
  申请人：——

  公开号：US20040198999A1

  公开（公告）日：2004-10-07

  The present invention comprises the simultaneous ring opening and concomitant N-substitution of various N-tosyl aziridines with different aliphatic and aromatic nitrites in presence of catalytic amount of metal triflates to afford different N-substituted &bgr;-amino nitrites in excellent yields and selectivities.

  本发明包括在存在催化量的金属三氟甲烷的情况下，同时开环和伴随着不同脂肪族和芳香族亚磺酰基环丙胺与不同的亚磺酰基环丙胺进行N-取代，从而获得不同N-取代的β-氨基亚硝基化合物，产率和选择性均极高。
• [EN] PROCESS FOR THE SYNTHESIS OF N-SUBSTITUTED beta -AMINO NITRILES THROUGH THE RING OPENING OF AZIRIDINES<br/>[FR] PROCEDE DE SYNTHESE DE DOLLAR G(B)-AMINO NITRILES N SUBSTITUES A TRAVERS L'OUVERTURE DE CYCLE D'AZIRIDINES
  申请人：COUNCIL SCIENT IND RES

  公开号：WO2004050606A1

  公开（公告）日：2004-06-17

  The present invention comprises the simultaneous ring opening and concomitan N-substitution of various N-tosyl aziridines with different aliphatic and aromatic nitriles in presence of catalytic amount of metal triflates to afford different N-substituted β-amino nitriles in excellent yields and selectivities.

  该发明包括在存在金属三氟乙酸盐的催化剂量下，同时开环和共同N-取代不同脂肪族和芳香族腈的各种N-对甲苯磺酰基环丙烷，以获得不同N-取代的β-氨基腈，产率和选择性均非常高。
• Compositions containing thiocarbonates and acylated-nitrogen containing compounds
  申请人：The Lubrizol Corporation

  公开号：EP0825247A2

  公开（公告）日：1998-02-25

  This invention relates to a composition, comprising: (A) a compound represented by the formula wherein in Formula (A-I): R1, R2 and R3 are independently hydrogen or hydrocarbyl groups; X is O or S; n is zero, 1 or 2; and T is a hydrocarbyl group, a hetero group, a hydroxyhydrocarbyl group, or an activating group; with the proviso that when n is zero, T can be a metal, and when n is 2, each R2 and R3 can be the same or different; and (B) an acylated nitrogen-containing compound having a substituent of at least about 10 carbon atoms. In one embodiment, the inventive composition further comprises (C) a phosphorus compound. In one embodiment, the inventive composition further comprises (D) an organic sulfide. In one embodiment, the inventive composition further comprises (E) a heterocyclic compound. In one embodiment, the inventive composition further comprises (F) a thiocarbamate. In one embodiment, the invention relates to a process comprising mixing the foregoing components (A) and (B) with an oil of lubricating viscosity, and, optionally, one or more of the foregoing components (C), (D), (E) and/or (F). The inventive compositions are useful in formulating lubricating compositions and functional fluids characterized by enhanced antiwear properties.

  本发明涉及一种组合物，其中包括： (A) 由式（A-I）表示的化合物 式（A-I）中R1、R2和R3独立地是氢基或烃基；X是O或S；n是零、1或2；T是烃基、杂基、羟基烃基或活化基；但当n为零时，T可以是金属，当n为2时，每个R2和R3可以相同或不同；以及(B)具有至少约10个碳原子取代基的酰化含氮化合物。在一个实施方案中，本发明组合物还包括 (C) 磷化合物。在一个实施方案中，本发明组合物进一步包含 (D) 有机硫化物。在一个实施方案中，本发明组合物还包括 (E) 杂环化合物。在一个实施方案中，本发明组合物还包括 (F) 硫代氨基甲酸酯。在一个实施方案中，本发明涉及一种工艺，该工艺包括将上述成分（A）和（B）与具有润滑粘度的油，以及可选的一种或多种上述成分（C）、（D）、（E）和/或（F）混合。本发明的组合物适用于配制润滑组合物和功能性液体，其特点是抗磨损性能更强。
• Lubricants and functional fluids containing heterocyclic compounds
  申请人：The Lubrizol Corporation

  公开号：EP0825246A2

  公开（公告）日：1998-02-25

  This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and a minor amount of    (A) a compound represented by the formula wherein in Formula (A-I): X1, X2 and X3 are independently O or S, and X2 and X3 can be NR1 wherein R1 is hydrogen or hydrocarbyl; and G1, G2, G3 and G4 are independently R2, OR2 or R3OR2, wherein R2 is hydrogen or hydrocarbyl and R3 is hydrocarbylene or hydrocarbylidene. In one embodiment, the inventive composition further comprises (B) an acylated nitrogen-containing compound having a substituent of at least about 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a phosphorus compound. In one embodiment, the inventive composition further comprises (D) a thiocarbamate. In one embodiment, the inventive composition further comprises (E) a organic sulfide. In one embodiment, the invention relates to a process comprising mixing the foregoing component (A) with an oil of lubricating viscosity, and, optionally, one or more of the foregoing components (B), (C), (D) and/or (E).

  本发明涉及一种润滑组合物，其主要成分是具有润滑粘度的油，次要成分是 (A) 由以下式子表示的化合物 式（A-I）中X1、X2和X3独立地是O或S，X2和X3可以是NR1，其中R1是氢或烃基；以及G1、G2、G3和G4独立地是R2、OR2或R3OR2，其中R2是氢或烃基，R3是亚烃基或亚烃基。在一个实施方案中，本发明组合物进一步包含（B）具有至少约 10 个脂肪族碳原子取代基的酰化含氮化合物。在一个实施方案中，本发明组合物进一步包含（C）磷化合物。在一个实施方案中，本发明组合物进一步包含 (D) 硫代氨基甲酸酯。在一个实施方案中，本发明组合物还包括 (E) 有机硫化物。在一个实施方案中，本发明涉及一种工艺，该工艺包括将上述成分 (A) 与具有润滑粘度的油，以及可选的一种或多种上述成分 (B)、(C)、(D) 和/或 (E) 混合。
• US4014931A
  申请人：——

  公开号：US4014931A

  公开（公告）日：1977-03-29