1.2-Diamino-dodecan | 4843-89-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1.2-Diamino-dodecan
• 英文别名: 1.2-diamino-dodecane；Dodecane-1,2-diamine
• CAS: 4843-89-4
• 化学式: C₁₂H₂₈N₂
• 分子量: 200.368
• InChiKey: OQGSHLFKXYVLRR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  14
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1.2-Diamino-dodecan 、 nickel dibromide 以 水 为溶剂， 生成 {Ni(C12H28N2)3}Br2
  参考文献：
  名称：

  Hein, F.; Schade, H., Zeitschrift fur Anorganische und Allgemeine Chemie

  摘要：

  DOI：
• 作为产物：
  描述：

  (+/-)-2-Amino-dodecansaeure-amid 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 生成 1.2-Diamino-dodecan
  参考文献：
  名称：

  Kempter,G.; Moser,G., Journal fur praktische Chemie (Leipzig 1954), 1966, vol. 34, p. 104 - 111

  摘要：

  DOI：

文献信息

• [EN] SIX-MEMBERED CYCLIC BISCARBONATES<br/>[FR] BICARBONATES CYCLIQUES À SIX CHAÎNONS
  申请人：UNIV BORDEAUX

  公开号：WO2015091499A1

  公开（公告）日：2015-06-25

  The present invention relates to six-membered cyclic biscarbonates of formula (I), wherein: - A is selected from the group consisting of -CH=CH- and -CH2CHR'-S-R-S-CHR''CH2-, wherein R is a linear or branched alkylene radical in C2-C6, optionally interrupted by one or more oxygen atoms, and wherein R' and R'', identical or different, are selected from the group consisting of hydrogen atom and linear alkyl radicals in C1-C10; and - A' and A'', identical or different, are linear or branched alkylene radicals in C1-C12, on the proviso that, when A is -CH2CH2-S-R-S-CH2CH2-, A' and A'' are in C2 -C12, and their use for the preparation of polymers, such as poly(hydroxyurethane)s.

  本发明涉及式(I)的六元环状双碳酸酯，其中：- A选自由-CH=CH-和-CH2CHR'-S-R-S-CHR''CH2-组成的组，其中R是C2-C6的直链或支链亚烷基，可选地被一个或多个氧原子中断，并且其中R'和R''相同或不同，选自由氢原子和C1-C10的直链烷基组成的组；以及- A'和A''，相同或不同，是C1-C12的直链或支链亚烷基，条件是，当A是-CH2CH2-S-R-S-CH2CH2-时，A'和A''是C2-C12，以及它们用于制备聚合物，如聚(羟基聚氨酯)。
• [EN] SULFONIUM SULFATES, THEIR PREPARATION AND USE<br/>[FR] SULFATES DE SULFONIUM, LEUR PRÉPARATION ET UTILISATION
  申请人：BASF SE

  公开号：WO2012113829A1

  公开（公告）日：2012-08-30

  The present invention relates to a heat-curable composition comprising (a) at least one compound which is capable of undergoing cationic polymerization; and (b) at least one sulfonium sulfate selected from compounds of the formulae Ia and Ib where Yn- is a monovalent or divalent anion selected from (1) where n, M, R1 to R10 are as defined in claim 1 and in the description. The present invention also relates to novel sulfonium sulfates of the formulae Ia and Ib, to a process for curing cationically polymerizable material and to the cured material obtained by said process.

  本发明涉及一种热固化组合物，包括（a）至少一种能够进行阳离子聚合的化合物；和（b）选择自式Ia和Ib的至少一种砜酸盐，其中Yn-是从（1）中选择的一价或二价阴离子，其中n、M、R1至R10如权利要求1和描述中所定义。本发明还涉及式Ia和Ib的新型砜酸盐，以及用于固化阳离子聚合材料的工艺和通过该工艺获得的固化材料。
• [EN] LIPOPOLYAMINES OF SPERMINE TYPE FOR CONSTRUCTION OF LIPOSOMAL TRANSFECTION SYSTEMS<br/>[FR] LIPOPOLYAMINES DE TYPE SPERMINE POUR LA CONSTRUCTION DE SYSTÈMES DE TRANSFECTION LIPOSOMALE
  申请人：USTAV ORGANICKE CHEMIE A BIOCHEMIE AV CR V V I

  公开号：WO2013104346A1

  公开（公告）日：2013-07-18

  The invention provides new lipopolyamines of spermine type of the general formula I, wherein X is C-N bond or aminopolyethyleneglycolcarboxamide linker or o-hydroxy- alkylcarboxamide linker or ω-hydroxyalkylcarboxamidopolyethyleneglycol- carboxamide linker, and wherein a hydrophobic domain Y is an acyl symmetrically branched in the position C(2) or cholesteryl. The invention further provides a method of preparation of said lipopolyamines and their use for construction of polycationic liposomal drug carriers.

  该发明提供了一种新的通式I的脂质聚胺类化合物，其中X是C-N键或氨基聚乙二醇羧酰胺连接物或o-羟基-烷基羧酰胺连接物或ω-羟基烷基羧酰胺聚乙二醇羧酰胺连接物，其中疏水区域Y是在位置C(2)处对称分支的酰基或胆固醇。该发明还提供了所述脂质聚胺的制备方法及其用于构建多阳离子脂质体药物载体的用途。
• [EN] [(2-ETHOXY-5-TRANS-1-PROPEN-1-YL)-PHENOXYL]-TERMINATED COMPOUNDS<br/>[FR] COMPOSÉS À TERMINAISON [(2-ÉTHOXY-5-TRANS-1-PROPÉN-1-YL)-PHÉNOXYLE]
  申请人：EVONIK TECHNOCHEMIE GMBH

  公开号：WO2017045931A1

  公开（公告）日：2017-03-23

  The present invention relates to compounds according to formula (I) and to heat-curable resin compositions based on polymaleimide resin systems comprising such compounds as co-monomers:, (I) wherein Dis an x-functional group; and x is an integer ≥ 2; with the proviso that the x-functional group D is not a polycarbonate with an average molar mass in the range of 15000 g/mol to 150000 g/mol. The present invention also relates to crosslinked resins obtainable by curing such compositions. Compounds of the present invention can be used amongst others in fields like structural adhesives, matrix resins for fiber prepregs, moulding compounds, as well as structural and/or electrical composites.

  本发明涉及按照式（I）的化合物以及基于聚马来酰亚胺树脂体系的热固性树脂组合物，其中这些化合物作为共聚单体：（I）其中D是一个x官能团；x是大于等于2的整数；但需注意x官能团D不是具有平均摩尔质量在15000克/摩尔至150000克/摩尔范围内的聚碳酸酯。本发明还涉及通过固化这些组合物获得的交联树脂。本发明的化合物可以在结构胶、纤维预浸料的基体树脂、成型复合材料以及结构和/或电气复合材料等领域中使用。
• [EN] THERMOSETTING RESIN COMPOSITIONS<br/>[FR] COMPOSITIONS DE RÉSINE THERMODURCISSABLE
  申请人：HEXCEL COMPOSITES LTD

  公开号：WO2017108946A1

  公开（公告）日：2017-06-29

  Meta and para alkenyl phenols are reacted with hydroxyl benzophenone to produce compounds of the genera formula or which are used as curatives for polymaleimide resins.

  甲基和对烯基酚与羟基苯甲酮反应，产生通式化合物，用作聚马来酰亚胺树脂的固化剂。