2-[N-[2-[bis[2-[1-(2-hydroxyphenyl)ethylideneamino]ethyl]amino]ethyl]-C-methylcarbonimidoyl]phenol | 116670-23-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-[N-[2-[bis[2-[1-(2-hydroxyphenyl)ethylideneamino]ethyl]amino]ethyl]-C-methylcarbonimidoyl]phenol
• CAS: 116670-23-6
• 化学式: C₃₀H₃₆N₄O₃
• 分子量: 500.641
• InChiKey: FJNZIXPANYVLKY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  37
• 可旋转键数：
  12
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  101
• 氢给体数：
  3
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  三(2-氨基乙基)胺 、 2'-羟基苯乙酮 以 甲醇 为溶剂， 反应 1.0h， 生成 2-[N-[2-[bis[2-[1-(2-hydroxyphenyl)ethylideneamino]ethyl]amino]ethyl]-C-methylcarbonimidoyl]phenol
  参考文献：
  名称：

  Preparation of TiO2 nanoparticles by using tripodal tetraamine ligands as complexing agent via two-step sol–gel method and their application in dye-sensitized solar cells

  摘要：

  The effect of different tripodal tetraamine ligands was investigated on the particle size, agglomeration level, optical and photovoltaic properties of TiO2 nanoparticle prepared via a two-step sol-gel method. The products were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), transmission electron spectroscopy (TEM), scanning electron microscopy (SEM), and UV-vis spectroscopy. The results showed that the symmetry of ligands has a crucial effect on the size and agglomeration level of the products. The optical and photovoltaic properties of the products were studied, as well. The reflectivity property of the samples due to different agglomeration sizes is shown to be very important factor in increasing conversion efficiency of DSSC. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.materresbull.2013.01.006
• 作为试剂：
  描述：

  titanium(IV) tetraethanolate 、 水 在 三乙醇胺 、 2-[N-[2-[bis[2-[1-(2-hydroxyphenyl)ethylideneamino]ethyl]amino]ethyl]-C-methylcarbonimidoyl]phenol 作用下， 以 neat (no solvent) 为溶剂， 反应 96.0h， 生成 titanium(IV) dioxide
  参考文献：
  名称：

  Preparation of TiO2 nanoparticles by using tripodal tetraamine ligands as complexing agent via two-step sol–gel method and their application in dye-sensitized solar cells

  摘要：

  The effect of different tripodal tetraamine ligands was investigated on the particle size, agglomeration level, optical and photovoltaic properties of TiO2 nanoparticle prepared via a two-step sol-gel method. The products were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), transmission electron spectroscopy (TEM), scanning electron microscopy (SEM), and UV-vis spectroscopy. The results showed that the symmetry of ligands has a crucial effect on the size and agglomeration level of the products. The optical and photovoltaic properties of the products were studied, as well. The reflectivity property of the samples due to different agglomeration sizes is shown to be very important factor in increasing conversion efficiency of DSSC. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.materresbull.2013.01.006

文献信息

• Preparation of TiO2 nanoparticles by using tripodal tetraamine ligands as complexing agent via two-step sol–gel method and their application in dye-sensitized solar cells
  作者：Noshin Mir、Masoud Salavati-Niasari

  DOI：10.1016/j.materresbull.2013.01.006

  日期：2013.4

  The effect of different tripodal tetraamine ligands was investigated on the particle size, agglomeration level, optical and photovoltaic properties of TiO2 nanoparticle prepared via a two-step sol-gel method. The products were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), transmission electron spectroscopy (TEM), scanning electron microscopy (SEM), and UV-vis spectroscopy. The results showed that the symmetry of ligands has a crucial effect on the size and agglomeration level of the products. The optical and photovoltaic properties of the products were studied, as well. The reflectivity property of the samples due to different agglomeration sizes is shown to be very important factor in increasing conversion efficiency of DSSC. (C) 2013 Elsevier Ltd. All rights reserved.