Tetracopper;2-[2-hydroxyethyl(2-oxidoethyl)amino]ethanolate | 253149-38-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Tetracopper;2-[2-hydroxyethyl(2-oxidoethyl)amino]ethanolate
• CAS: 253149-38-1
• 化学式: C₂₄H₅₂Cu₄N₄O₁₂
• 分子量: 842.88
• InChiKey: NHKHUMRZENEUPM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -12.0
• 重原子数：
  44
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  278
• 氢给体数：
  4
• 氢受体数：
  16

反应信息

• 作为产物：
  描述：

  copper(ll) sulfate pentahydrate 、 三乙醇胺 在 NH₄OH 、 KOH 作用下， 以 水 为溶剂， 以76%的产率得到Tetracopper;2-[2-hydroxyethyl(2-oxidoethyl)amino]ethanolate
  参考文献：
  名称：

  Triethanolamine complexes of copper

  摘要：

  simple benchtop synthesis of the deep blue tetrameric compound [Cu{N(CH2CH2O)(3)H}](4) prepared from CuSO4. 5H(2)O and triethanolamine is presented. The compound has been characterized in three different crystalline modifications which vary due to the presence of different lattice solvents that include THF, Et2O and H2O. The compound dissolves in water, alcohols and to a slight extent in dichloromethane and chloroform. It produces basic solutions (K-b = 1.2 (+/- 0.4) x 10(-7)) in water and a visible spectrum that varies as a function of pH. FAB mass spectral data indicate that the tetramer remains intact and incorporates additional copper ions in the mass spectrometer. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00274-1

文献信息

• Triethanolamine complexes of copper
  作者：Kenton H. Whitmire、J.Chris Hutchison、Anna Gardberg、Chris Edwards

  DOI：10.1016/s0020-1693(99)00274-1

  日期：1999.11

  simple benchtop synthesis of the deep blue tetrameric compound [CuN(CH2CH2O)(3)H}](4) prepared from CuSO4. 5H(2)O and triethanolamine is presented. The compound has been characterized in three different crystalline modifications which vary due to the presence of different lattice solvents that include THF, Et2O and H2O. The compound dissolves in water, alcohols and to a slight extent in dichloromethane and chloroform. It produces basic solutions (K-b = 1.2 (+/- 0.4) x 10(-7)) in water and a visible spectrum that varies as a function of pH. FAB mass spectral data indicate that the tetramer remains intact and incorporates additional copper ions in the mass spectrometer. (C) 1999 Elsevier Science S.A. All rights reserved.