Non-3-ynylamine | 86001-04-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Non-3-ynylamine
• 英文别名: Non-3-yn-1-amine
• CAS: 86001-04-9
• 化学式: C₉H₁₇N
• mdl: MFCD08449525
• 分子量: 139.241
• InChiKey: PYVSXRHDAKDYHO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.777
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Non-3-ynylamine 在 吡啶 、 碘 、 potassium carbonate 作用下， 以 二氯甲烷 、 乙腈 为溶剂， 反应 14.0h， 生成 3-iodo-2-n-pentyl-1-tosyl-4,5-dihydropyrrole
  参考文献：
  名称：

  Facile Preparation of 2-Aryl-3-iodopyrroles with N-Tosyl 4-Aryl-3-butyn-1-ylamines, I2, and tBuOK

  摘要：

  DOI：

  10.3987/com-21-14443
• 作为产物：
  描述：

  non-3-ynylimino(triphenyl)-λ5-phosphane 以91%的产率得到
  参考文献：
  名称：

  VAULTIER, H.;KNOUZI, N.;CARRIE, R., TETRAHEDRON LETT., 1983, 24, N 8, 763-764

  摘要：

  DOI：

文献信息

• Methods for Obtaining Optically Active Epoxides and Vicinal Diols From 2,2-Disubstituted Epoxides
  申请人：Botes Adriana Leonora

  公开号：US20080286832A1

  公开（公告）日：2008-11-20

  The invention provides yeast strains, and polypeptides encoded by genes of such yeast strains, that have enantiospecific 2,2-disubstituted epoxide hydrolase activity. The invention also features nucleic acid molecules encoding such polypeptides, vectors containing such nucleic acid molecules, and cells containing such vectors. Also embraced by the invention are methods for obtaining optically active 2,2-disubstituted vicinal diols and optically active 2,2-disubstituted epoxides.

  该发明提供了酵母菌株，以及这些酵母菌株基因编码的多肽，具有对映选择性的2,2-二取代环氧乙烷水解酶活性。该发明还涵盖编码这些多肽的核酸分子，包含这些核酸分子的载体以及含有这些载体的细胞。该发明还涵盖了获得光学活性2,2-二取代邻二醇和光学活性2,2-二取代环氧化物的方法。
• Reduction d'azides en amines primaires par une methode generale utilisant la reaction de staudinger
  作者：M. Vaultier、N. Knouzi、R. Carrié

  DOI：10.1016/s0040-4039(00)81520-8

  日期：1983.1

  A general chemoselective method for the reduction of azides into primary amines is described.

  描述了将叠氮化物还原成伯胺的一般化学选择方法。
• Methods For Obtaining Optically Active Epoxides And Vicinal Diols From Meso-Epoxides
  申请人：Botes Leonora Adriana

  公开号：US20070275448A1

  公开（公告）日：2007-11-29

  The invention provides yeast strains, and polypeptides encoded by genes of such yeast strains, that have enantiospecific meso-epoxide hydrolase activity. The invention also features nucleic acid molecules encoding such polypeptides, vectors containing such nucleic acid molecules, and cells containing such vectors. Also embraced by the invention are methods for obtaining optically active vicinal diols from meso-epoxides.

  本发明提供了酵母菌株和由这些酵母菌株的基因编码的多肽，具有对映特异性的中间体环氧水解酶活性。本发明还涵盖编码这种多肽的核酸分子，含有这种核酸分子的载体以及含有这种载体的细胞。本发明还涵盖了从中间体环氧化物中获得光学活性邻二醇的方法。
• Methods for Obtaining Optically Active Glycidyl Ethers and Optically Active Vicinal Diols from Racemic Substrates
  申请人：Botes Adriana Leonora

  公开号：US20080213833A1

  公开（公告）日：2008-09-04

  The invention provides yeast strains, and polypeptides encoded by genes of such yeast strains, that have enantiospecific glycidyl ether hydrolase activity. The invention also features nucleic acid molecules encoding such polypeptides, vectors containing such nucleic acid molecules, and cells containing such vectors. Also embraced by the invention are methods for obtaining optically active glycidyl ethers and associated optically active vicinal diols.

  本发明提供了具有对映选择性环氧丙烷醚水解酶活性的酵母菌株和由这些酵母菌株基因编码的多肽。本发明还涉及编码这种多肽的核酸分子、含有这种核酸分子的载体以及含有这种载体的细胞。本发明还包括用于获得光学活性环氧丙烷醚及相关光学活性邻二醇的方法。
• Methods for Obtaining Optically Active Epoxides and Diols from 2,3-Disubstituted and 2,3-Trisubstituted Epoxides
  申请人：Botes Adriana Leonora

  公开号：US20080199912A1

  公开（公告）日：2008-08-21

  The invention provides yeast strains, and polypeptides encoded by genes of such yeast strains, that have enantiospecific internal epoxide hydrolase activity. The invention also features nucleic acid molecules encoding such polypeptides, vectors containing such nucleic acid molecules, and cells containing such vectors. Also embraced by the invention are methods for obtaining optically active internal epoxides and corresponding optically active internal diols.

  本发明提供了具有对映选择性内部环氧水解酶活性的酵母菌株和由这些酵母菌株的基因编码的多肽。本发明还涵盖编码这种多肽的核酸分子，含有这种核酸分子的载体以及含有这种载体的细胞。本发明还包括获得光学活性内部环氧化物及其相应的光学活性内部二醇的方法。